1,2-Dimethylimidazole
- CAS No.
- 1739-84-0
- Chemical Name:
- 1,2-Dimethylimidazole
- Synonyms
- DiMethyliMidazole;1,2-dimethyl-1h-imidazole;1,2-dimethyl-1h-imidazol;1,2-Dimethylimidazol;39-41℃;1,2-DimethyL;Lupragen DMI;LUPRAGEN(R) DMI;AKOS BBS-00004287;dimethylglyoxaline
- CBNumber:
- CB6196161
- Molecular Formula:
- C5H8N2
- Molecular Weight:
- 96.13
- MDL Number:
- MFCD00005294
- MOL File:
- 1739-84-0.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 1,2-Dimethylimidazole 98% | 136131 | 5g | $29.09 |
| 1,2-Dimethylimidazole 98% | 136131 | 100g | $48.4 |
| 1,2-Dimethylimidazole for synthesis | 8.03245 | 100mL | $55.6 |
| 1,2-Dimethylimidazole for synthesis | 8.03245 | 500mL | $215 |
| 1,2-Dimethylimidazole >98.0%(GC) | D1562 | 25g | $42 |
| More product size | |||
| Melting point | 37-39 °C (lit.) |
|---|---|
| Boiling point | 204 °C (lit.) |
| Density | 1.084 g/mL at 25 °C (lit.) |
| vapor pressure | 1 mm Hg ( 20 °C) |
| refractive index | 1.5000 (estimate) |
| Flash point | 198 °F |
| storage temp. | Store below +30°C. |
| pka | 7.76±0.25(Predicted) |
| form | Low Melting Mass |
| color | Colorless to yellow |
| Specific Gravity | 1.084 |
| PH | 12.6 (500g/l, H2O, 20℃) |
| Odor | Amine-like odor |
| Water Solubility | Soluble in water. |
| BRN | 108457 |
| InChI | 1S/C5H8N2/c1-5-6-3-4-7(5)2/h3-4H,1-2H3 |
| InChIKey | GIWQSPITLQVMSG-UHFFFAOYSA-N |
| SMILES | Cc1nccn1C |
| LogP | 0.11 at 25℃ |
| CAS DataBase Reference | 1739-84-0(CAS DataBase Reference) |
| EWG's Food Scores | 1-2 |
| FDA UNII | Q41BC3GRJB |
| NIST Chemistry Reference | 1H-Imidazole, 1,2-dimethyl-(1739-84-0) |
| EPA Substance Registry System | 1H-Imidazole, 1,2-dimethyl- (1739-84-0) |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H315-H318 | |||||||||
| Precautionary statements | P280-P305+P351+P338 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-38-41 | |||||||||
| Safety Statements | 24-26-2 | |||||||||
| RIDADR | UN 3263 8/PG 2 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | NI4838854 | |||||||||
| Autoignition Temperature | 896 °F | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29332990 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Dam. 1 Skin Irrit. 2 |
|||||||||
| Toxicity | LD50 orally in Rabbit: 1300 mg/kg | |||||||||
| Limited Quantities | 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
1,2-Dimethylimidazole price More Price(34)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 136131 | 1,2-Dimethylimidazole 98% | 1739-84-0 | 5g | $29.09 | 2025-07-31 | Buy |
| Sigma-Aldrich | 136131 | 1,2-Dimethylimidazole 98% | 1739-84-0 | 100g | $48.4 | 2025-07-31 | Buy |
| Sigma-Aldrich | 8.03245 | 1,2-Dimethylimidazole for synthesis | 1739-84-0 | 100mL | $55.6 | 2025-07-31 | Buy |
| Sigma-Aldrich | 8.03245 | 1,2-Dimethylimidazole for synthesis | 1739-84-0 | 500mL | $215 | 2023-01-07 | Buy |
| TCI Chemical | D1562 | 1,2-Dimethylimidazole >98.0%(GC) | 1739-84-0 | 25g | $42 | 2025-07-31 | Buy |
1,2-Dimethylimidazole Chemical Properties,Uses,Production
Chemical Properties
colorless to yellow low melting mass
Uses
1,2-Dimethylimidazole is used in the synthesis of 1,2-dimethyl-3-n-butylimidazoliumchloride and 1,2-dimethyl-3-n-propylimidazolium chloride. It also can be used in the synthesis of 1-(2-methoxyethyl)-2,3-dimethylimidazolium chloride and hexafluorophosphate salts.
Uses
1,2-Dimethylimidazole was used in the synthesis of 1,2-dimethyl-3-n-butylimidazoliumchloride and 1,2-dimethyl-3-n-propylimidazolium chloride. It was also used in the synthesis of 1-(2-methoxyethyl)-2,3-dimethylimidazolium chloride and hexafluorophosphate salts.
Definition
ChEBI: 1,2-dimethylimidazole is a member of imidazoles.
General Description
1,2-Dimethylimidazole reacts with copper(II) tetraacetate to yield cis-bis(acetato)bis(1,2-dimethylimidazole) copper(II) complex. It undergoes Menschutkin reaction with benzyl bromide to yield 3-benzyl-1,2-dimethylimidazolium bromide and kinetics of reaction was studied in various ionic liquids and molecular organic solvents.
Flammability and Explosibility
Not classified
Synthesis
131543-46-9
75-07-0
74-89-5
616-47-7
1739-84-0
693-98-1
A high-pressure microreactor equipped with three micro-mixers was used for the synthesis. It was operated as follows: an aqueous methylamine solution (0.33 mol/L) was fed from tank 1 via pump 1 at a flow rate of 0.68 mL/min; an aqueous acetaldehyde solution (0.33 mol/L) was fed from tank 3 via pump 3A at a flow rate of 63 mL/min while nearby water (0.33 mol/L) flowed at a flow rate of 1.13 mL/min; an aqueous glyoxal solution ( 0.33 mol/L) was fed from tank 4 via pump 4 at a flow rate of 0.56 mL/min. The reaction pressure was set to 30 MPa and the final flow rate was 8.0 mL/min. The temperature of the first micro-mixer and the 2.4 m reaction tube was controlled at 25 °C by the thermostat chamber 1 , under which the mixing and reaction of methylamine with acetaldehyde was carried out. Subsequently, in the second micro-mixer, the reaction mixture was mixed with ammonia and kept at 25 °C in the constant temperature chamber 2, and the reaction was fully mixed and reacted in the 0.1 m reaction tube. Next, glyoxal was added to the reaction system and fully reacted in a 0 m reaction tube. Subsequently, the temperature of the reaction zone was raised to 70 °C and the reaction was continued in a 25 μm reaction tube. Finally, the reaction mixture was cooled to 5 °C by a heat exchanger, depressurized to atmospheric pressure by a pressure reducing valve, and the aqueous solution obtained under cooling in ice water (0 °C to 4 °C) was collected. The residence time of the reaction part was 37 seconds throughout the reaction. For analysis, the product was diluted 10-fold with ice water, if necessary, and analyzed immediately using a gas chromatograph. The reaction tube was made of stainless steel (SUS316) with an inner diameter of 0.5 mm. the yield of the product 1,2-dimethylimidazole was 85.1%. The quantitative analysis was performed on an Agilent gas chromatograph (GC 6890, hydrogen flame ionization detector) with an HP-INNOWAX column (inner diameter 0.32 mm, film thickness 0.25 μm, length 30 m) manufactured by J & W Co. The yield of each product (1,2-dimethylimidazole, 1-methylimidazole, 2-methylimidazole, and imidazole) was determined by preparing standard curves for each product. The yield of each product was calculated based on the concentration obtained by conversion of the standard curve as follows: 1,2-dimethylimidazole 85.1%, 1-methylimidazole 6.27%, 2-methylimidazole 6.59%, and imidazole 2.06%.
Purification Methods
Crystallise the imidazole from *benzene, dry and store it at 0-4o. The picrate crystallises from H2O or EtOH with m 181o. [Balaban & Pymann J Chem Soc 125 1570 1924, Gorun et al. J Am Chem Soc 109 4244 1987, Beilstein 23 H 66, 23 II 56, 23 III/IV 594.]
References
[1] Patent: JP2016/222615, 2016, A. Location in patent: Paragraph 0051-0052
1,2-Dimethylimidazole Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shandong DYCK Biotech Co.,LTD | +86-15376072011 | sales3@dyckbiotech.com | China | 3 | 58 |
| Hebei Longbang Technology Co., LTD | +86-18633929156 | admin@hblongbang.com | China | 972 | 58 |
| Hebei Chuanghai Biotechnology Co., Ltd | +8615350571055 | Sibel@chuanghaibio.com | China | 8753 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5242 | 58 |
| Firsky International Trade (Wuhan) Co., Ltd | +8615387054039 | admin@firsky-cn.com | China | 427 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20129 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3692 | 58 |
| HebeiShuoshengImportandExportco.,Ltd | +86-18532138899 | L18532138899@163.com | China | 939 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 13620 | 58 |
View Lastest Price from 1,2-Dimethylimidazole manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-01-05 | 1,2-Dimethylimidazole
1739-84-0
|
US $10.00 / KG | 1KG | 99% | 5tons | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2025-09-25 | 1,2-Dimethylimidazole
1739-84-0
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2025-07-29 | 1,2-Dimethylimidazole
1739-84-0
|
US $6.00 / kg | 1kg | 99% | 2000KG/Month | HebeiShuoshengImportandExportco.,Ltd |
-
- 1,2-Dimethylimidazole
1739-84-0
- US $10.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- 1,2-Dimethylimidazole
1739-84-0
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 1,2-Dimethylimidazole
1739-84-0
- US $6.00 / kg
- 99%
- HebeiShuoshengImportandExportco.,Ltd
