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Methyl 4-methylbenzoate

CAS No.
99-75-2
Chemical Name:
Methyl 4-methylbenzoate
Synonyms
MPT;NSC-24761;Methyl-p-toluat;Methylp-tolulate;p-Methyl toluate;METHYL P-TOLUATE;METHYL 4-TOLUATE;RARECHEM AL BF 0113;METHYL PARA TOLUATE;Methylp-toluate,99%
CBNumber:
CB6224862
Molecular Formula:
C9H10O2
Molecular Weight:
150.17
MDL Number:
MFCD00008441
MOL File:
99-75-2.mol
MSDS File:
SDS
Last updated:2023-11-28 16:31:44

Methyl 4-methylbenzoate Properties

Melting point 32-35 °C (lit.)
Boiling point 103-104 °C/15 mmHg (lit.)
Density 1.06
vapor density 4.7 (vs air)
vapor pressure 1 mm Hg ( 39 °C)
refractive index 1.5002 (estimate)
Flash point 90 °C
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
form Solid
color White to Off-White
Odor at 100.00 %. sweet anisic floral ylang
Odor Type anisic
explosive limit 1-9.5%(V)
Water Solubility <0.1 g/100 mL at 22 ºC
BRN 1100609
Dielectric constant 4.3(33℃)
Stability Unstable in Solution
LogP 2.7 at 25℃
CAS DataBase Reference 99-75-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 964JP0ZZRG
NIST Chemistry Reference Benzoic acid, 4-methyl-, methyl ester(99-75-2)
EPA Substance Registry System Methyl-p-toluate (99-75-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H303-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26-36
WGK Germany  2
RTECS  XU2150000
Autoignition Temperature 932 °F
TSCA  Yes
HS Code  29163900
Toxicity LD50 oral in rat: 3300mg/kg
NFPA 704
2
2 0

Methyl 4-methylbenzoate price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 259667 Methyl p-toluate ≥99% 99-75-2 250g $89 2024-03-01 Buy
TCI Chemical T0297 Methyl p-Toluate >98.0%(GC) 99-75-2 25g $16 2024-03-01 Buy
TCI Chemical T0297 Methyl p-Toluate >98.0%(GC) 99-75-2 500g $117 2024-03-01 Buy
Alfa Aesar B23111 Methyl p-toluate, 99% 99-75-2 100g $31.65 2024-03-01 Buy
Alfa Aesar B23111 Methyl p-toluate, 99% 99-75-2 500g $96.65 2024-03-01 Buy
Product number Packaging Price Buy
259667 250g $89 Buy
T0297 25g $16 Buy
T0297 500g $117 Buy
B23111 100g $31.65 Buy
B23111 500g $96.65 Buy

Methyl 4-methylbenzoate Chemical Properties,Uses,Production

Chemical Properties

white low melting crystalline solid and/or

Uses

Organic synthesis.

Uses

Methyl p-toluate has been employesd as catalyst to investigate the effect of internal/external donor pair in high-yield catalysts for propylene polymerization.

Synthesis Reference(s)

The Journal of Organic Chemistry, 54, p. 1144, 1989 DOI: 10.1021/jo00266a028
Synthetic Communications, 20, p. 3273, 1990

General Description

Opaque colorless to white shiny crystalline solid. Intense unpleasant odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Methyl 4-methylbenzoate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Fire Hazard

Methyl 4-methylbenzoate is combustible.

67-56-1
104-87-0
99-75-2
106-44-5
Synthesis of Methyl 4-methylbenzoate from Methanol and p-Tolualdehyde
Global( 304)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12453 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
airuikechemical co., ltd.
+undefined86-15315557071 sales02@airuikechemical.com China 994 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2931 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58

View Lastest Price from Methyl 4-methylbenzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 4-methylbenzoate pictures 2024-04-11 Methyl 4-methylbenzoate
99-75-2
US $0.00-0.00 / Kg 1Kg 99.99% 2000 tons airuikechemical co., ltd.
Methyl 4-methylbenzoate pictures 2023-08-18 Methyl 4-methylbenzoate
99-75-2
US $10.00 / KG 1KG 99% 5000000kg Hebei Mojin Biotechnology Co., Ltd
Methyl 4-methylbenzoate pictures 2023-08-08 Methyl 4-methylbenzoate
99-75-2
US $0.00-0.00 / kg 1kg 99% 50tons Hebei Yanxi Chemical Co., Ltd.
P-TOLUIC ACID METHYL ESTER P-TOLULYL ACID METHYL ESTER RARECHEM AL BF 0113 Benzoicacid,4-methyl-,methylester Methyl ester of 4-methylbenzoic acid Methylp-tolulate MPT p-Carbomethoxytoluene p-Toluylic acid, methyl ester Methyl 4-methylbenzo p-Methyl toluate Methyl p-toluate, 99% 100GR 4-Methylbenzoic Acid Methyl Ester Methyl 4-Methylbenzoate p-Toluic Acid Methyl Ester p-(Methoxycarbonyl)toluene 4-(Methoxycarbonyl)toluene, Methyl p-toluate Methyl 4-methylbenzoate 99% Methyl p-Toluate, 98.0%(GC) Cladribine Impurity G (Methyl 4-methylbenzoate) Methyl 4-methylbenzoate for synthesis 4-METHYL METHYLBENZOATE 4-METHYLBENZOIC ACID METHYL ESTER METHYL P-TOLUATE METHYL P-METHYLBENZOATE METHYL PARA TOLUATE 4-Toluic acid methylester METHYL 4-METHYLBENZOATE, 99+% Benzoic acid, 4-methyl-, methyl ester (9CI) Methylp-toluate,99% Methyl-p-toluat P-TOLUIC ACID METHYL ESTER ( METHYL-4-METHYL BENZ P-TOLUIC ACID METHYL ESTER / METHYL P-TOLUATE 4-(Methoxycarbonyl)toluene 4-methyl-benzoicacimethylester METHYL 4-TOLUATE METHYL 4-METHYLBENZOATE Methyl 4-Toluate (Methyl 4-Methylbenzoate) METHYL METHYLBENZOATE 4-Methylbenzoic acid methyl NSC-24761 p-Methylbenzoic acid methyl ester Methyl p-Toluate > Cladribine Impurity G Methyl 4-methylbenzoate USP/EP/BP Celecoxib Methyl P-toluate Methyl 4-methylbenzoate/ Methyl P-toluate Methyl 4-methylbenzoate 99-75-2 Cladribine Impurity 7 p-TOLUIC ACID METHYL ESTER Extra Pure Methyl p-toluate, 97.5% Cladribine Impurity 7(Cladribine EP Impurity G) Cladribine EP Impurity G Celecoxib Impurity 38 Methyl 4-Methyl Benzoate (Para Toluic Acid Methyl Ester) Cladribine EP Impurity G(Celecoxib Impurity 2) Celecoxib USP Impurity B 99-75-2 CH3C6H4CO2CH3 C8 to C9