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(1R)-(-)-CAMPHORQUINONE

CAS No.
10334-26-6
Chemical Name:
(1R)-(-)-CAMPHORQUINONE
Synonyms
3-Ketocamphor;D-CAMPHORQUINONE;2,3-BORNANEDIONE;D-CAMPHOROQUINONE;D-2,3-BORNANEDIONE;(-)-CAMPHORQUINONE;(-)-2,3-BORNANEDIONE;D-(-)-CAMPHORQUINONE;R-(-)-CAMPHORQUINONE;(1R)-2,3-BORNANEDIONE
CBNumber:
CB6242990
Molecular Formula:
C10H14O2
Molecular Weight:
166.22
MDL Number:
MFCD00082863
MOL File:
10334-26-6.mol
MSDS File:
SDS
Last updated:2023-11-02 15:05:42

(1R)-(-)-CAMPHORQUINONE Properties

Melting point 200-203 °C(lit.)
Boiling point 254.44°C (rough estimate)
alpha -101° (20/D)(c=2, C6H5CH3)
Density 1.0060 (rough estimate)
refractive index 1.5200 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility almost transparency in Methanol
form powder to crystal
color Light yellow to Yellow
optical activity [α]20/D 101°, c = 2 in toluene
BRN 2327696
CAS DataBase Reference 10334-26-6(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Danger
Hazard statements  H302-H334
Precautionary statements  P301+P312+P330
Hazard Codes  Xn
Risk Statements  22-43
Safety Statements  36/37
WGK Germany  3
HS Code  2914.29.5000
NFPA 704
1
0 0

(1R)-(-)-CAMPHORQUINONE price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 276286 (1R)-(?)-Camphorquinone 99% 10334-26-6 5g $225 2024-03-01 Buy
TCI Chemical C1482 (1R)-(-)-Camphorquinone >98.0%(GC) 10334-26-6 1g $47 2024-03-01 Buy
TCI Chemical C1482 (1R)-(-)-Camphorquinone >98.0%(GC) 10334-26-6 5g $185 2024-03-01 Buy
Alfa Aesar B24092 (1R)-(-)-Camphorquinone, 98% 10334-26-6 5g $0 2021-12-16 Buy
TRC C175010 (1R)-(-)Camphorquinone 10334-26-6 1g $140 2021-12-16 Buy
Product number Packaging Price Buy
276286 5g $225 Buy
C1482 1g $47 Buy
C1482 5g $185 Buy
B24092 5g $0 Buy
C175010 1g $140 Buy

(1R)-(-)-CAMPHORQUINONE Chemical Properties,Uses,Production

Uses

(1R)-(-)Camphorquinone are used as visible light photoinitiator for biomedical applications such as in dental surgery.

Uses

(1R)-(-)Camphorquinone are used as visible light photoinitiator for biomedical applications such as in dental surgery.

Uses

(1R)-(-)-Camphorquinone may be used as an analytical standard for the determination of the analyte in dental resin composite restorations in the oral environment in contact with food and beverages, and biological samples by analytical techniques.

Uses

(1R)-(?)-Camphorquinone can be used as a chiral starting material for the preparation of:

  • α-Hydroxycamphors by selective reduction of keto groups using various vegetables.
  • Camphor-1,2-diamine platinum(II) complexes for DNA interaction studies.
  • Camphoric anhydride by unsensitized photo-oxidation in the presence of oxygen and polar solvents.
  • Camphorquinone-based chiral homoallylic amine, which is reacted with aldehydes to produce homoallylic primary amines via imine formation followed by 2-azonia-Cope rearrangement.

Definition

ChEBI: (1R)-bornane-2,3-dione is a bornane-2,3-dione. It is an enantiomer of a (1S)-bornane-2,3-dione.

General Description

Camphorquinone, a 1,2-diketone, is a photoinitiator that finds wide use in the curing of resin composites. It functions by initiating the chain polymerization by free radical generation; typically with the aid of co-initiator amines.

Purification Methods

It can be purified by steam distillation, recrystallisation (yellow prisms) from EtOH, *C6H6 or Et2O/pet ether and it can be sublimed in a vacuum. The (±)-quinone forms needles from EtOH, m 197-198o, 203o. [Buxtorf & Flatt Helv Chim Acta 13 1026 1930, Asahena et al. Chem Ber 67 1432 1934, Beiltein 7 I 325.]

(1R)-(-)-CAMPHORQUINONE Preparation Products And Raw materials

Raw materials

Preparation Products

(1R)-(-)-CAMPHORQUINONE Suppliers

Global( 105)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12453 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 29321 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259 cherry@crovellbio.com China 18457 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 57511 58
Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32360 55
zhenJiang HuiRui chem-tech Co;Ltd 15951285981 huiruisales@163.com China 420 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62

View Lastest Price from (1R)-(-)-CAMPHORQUINONE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1R)-(-)-CAMPHORQUINONE pictures 2023-11-02 (1R)-(-)-CAMPHORQUINONE
10334-26-6
US $20.00-1.00 / kg 1kg 0.99 5 tons Hebei Yanxi Chemical Co., Ltd.
(1R)-(-)-CAMPHORQUINONE pictures 2023-10-19 (1R)-(-)-CAMPHORQUINONE
10334-26-6
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
(1R)-(-)-CAMPHORQUINONE pictures 2023-09-06 (1R)-(-)-CAMPHORQUINONE
10334-26-6
US $0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
CAMPHORQUINONE, -R-(-)- (-)-CAMPHORQUINONE D-2,3-BORNANEDIONE D-CAMPHOROQUINONE D-(-)-CAMPHORQUINONE D-CAMPHORQUINONE (-)-2,3-BORNANEDIONE 2,3-BORNANEDIONE (1R)-(-)-CAMPHORQUINONE (1R)-(-)-2,3-BORNANEDIONE (1R)-2,3-BORNANEDIONE D-(-)-Camphorquinone,98% Bicyclo2.2.1heptane-2,3-dione, 1,7,7-trimethyl-, (1R,4S)- R-(-)-CAMPHORQUINONE 3-Ketocamphor (1R)-(-)-2,3-Bornanedione, 2,3-Bornanedione (1R)-(-)-2,3-camphanedione (1R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione (1R,4S)-1β,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione (1R,4α)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione (1R)-(-)-CAMPHORQUINONE FOR SYNTHESIS (1R)-1,7,7-triMethylbicyclo[2.2.1]heptane-2,3-dione (1R)-(-)-Camphorquinone 99% (1R)-(-)-Camphorquinone (1R)-bornane-2,3-dione (1R)-(-)-Camphorquinone> (1R)-(-)-CAMPHORQUINONE ISO 9001:2015 REACH (1S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione 10334-26-6 Asymmetric Synthesis Ketones Organic Building Blocks Chiral Building Blocks Bicyclic Monoterpenes Terpenes Anthraquinones, Hydroquinones and Quinones Bicyclic Monoterpenes Biochemistry Terpenes