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4-METHOXYPHENYL ISOCYANIDE

4-METHOXYPHENYL ISOCYANIDE structure

CAS No.: 10349-38-9

Chemical Name:: 4-METHOXYPHENYL ISOCYANIDE

Synonyms: 1-ISOCYANO-4-METHOXYBENZENE;HANSA ISN-0053;Anisyl isonitrile;4-Isocyanoanisole;p-Anisyl isonitrile;p-Anisyl isocyanide;p-Anisoleisonitrile;P-ANISOYL ISONITRILE;p-Methoxyphenyl isocyanide;4-METHOXYPHENYL ISOCYANIDE

CBNumber:: CB6251123

Molecular Formula:: C8H7NO

Molecular Weight:: 133.15

MDL Number:: MFCD02664592

MOL File:: 10349-38-9.mol

MSDS File:: SDS

Last updated:2022-12-30 16:20:48

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4-METHOXYPHENYL ISOCYANIDE Properties

Melting point	29-33 °C (lit.)
Boiling point	113 °C
Flash point	224 °F
storage temp.	-20°C

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS06
Signal word	Danger
Hazard statements	H301-H311-H315-H319-H331-H335
Precautionary statements	P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P330-P332+P313-P337+P313-P361-P403+P233-P405-P501
Risk Statements	20/21/22-36/37/38
Safety Statements	26-36/37/39
RIDADR	UN 3335
WGK Germany	3
HazardClass	IRRITANT
HS Code	2929900090

4-METHOXYPHENYL ISOCYANIDE price More Price(13)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	594458	4-Methoxyphenyl isocyanide 97%	10349-38-9	1g	$103	2024-03-01	Buy
TRC	M350173	4-Methoxyphenyl isocyanide	10349-38-9	100mg	$45	2021-12-16	Buy
Apolloscientific	OR906675	4-Methoxyphenyl isocyanide	10349-38-9	5g	$466	2021-12-16	Buy
American Custom Chemicals Corporation	CHM0026045	4-METHOXYPHENYL ISOCYANIDE 95.00%	10349-38-9	0.5G	$726	2021-12-16	Buy
American Custom Chemicals Corporation	CHM0026045	4-METHOXYPHENYL ISOCYANIDE 95.00%	10349-38-9	1G	$808.5	2021-12-16	Buy

Product number	Packaging	Price	Buy
594458	1g	$103	Buy
M350173	100mg	$45	Buy
OR906675	5g	$466	Buy
CHM0026045	0.5G	$726	Buy
CHM0026045	1G	$808.5	Buy

4-METHOXYPHENYL ISOCYANIDE Chemical Properties,Uses,Production

Uses

4-Methoxyphenyl isocyanide can be used to synthesize N-(isoquinolin-1-yl)-formamides via reaction with 2-alkynylbenzaldoximes in the presence of silver trifluoromethanesulfonate and bismuth triflate.

Preparation

To an ice-cooled flask containing a solution of 10.5 gm (0.065 mole) of p-methoxyformanilide in 37.1 gm (0.47 mole) of pyridine and 13.0 ml (0.16 mole) of chloroform is added dropwise at 0°C 6.12 gm (0.040 mole) of phosphorus oxychloride. The solution is stirred for 1? hr at room temperature and then added to 55 ml of ice-water. The water layer is extracted with two 10-ml portions of chloroform; the combined chloroform layer is dried and distilled under reduced pressure, to afford 3.5 gm (40%), b.p. 767C (1.0 mm Hg), IR 2137 c m " 1 (R—NC).
Preparation of p-Methoxyphenyl Isonitrile

Synthesis Reference(s)

Journal of Medicinal Chemistry, 38, p. 2955, 1995 DOI: 10.1021/jm00015a018

4-METHOXYPHENYL ISOCYANIDE synthesis

Synthesis of 4-METHOXYPHENYL ISOCYANIDE from p-Anisidine and POTASSIUM BROMODIFLUOROACETATE

4-METHOXYPHENYL ISOCYANIDE Preparation Products And Raw materials

Raw materials

Sodium chlorodifluoroacetate N-(4-METHOXYPHENYL)FORMAMIDE POTASSIUM BROMODIFLUOROACETATE Propionaldehyde p-Anisidine

Chloroform

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Preparation Products

4-METHOXYPHENYL ISOTHIOCYANATE Benzophenone 4-Methoxyphenyl isocyanate

4-METHOXYPHENYL ISOCYANIDE Suppliers

Global( 51)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49390	58
Career Henan Chemica Co	+86-0371-86658258 15093356674;	laboratory@coreychem.com	China	30255	58
Aromsyn Co., Ltd.	+86-0571-85585865 +8613336024896	CB@aromsyn.com	China	19185	58
LEAPCHEM CO., LTD.	+86-852-30606658	market18@leapchem.com	China	43348	58
Aladdin Scientific	+1-833-552-7181	sales@aladdinsci.com	United States	57511	58
Meryer (Shanghai) Chemical Technology Co., Ltd.	4006608290; 18621169109	market03@meryer.com	China	40241	62
Wuhan Chemwish Technology Co., Ltd	86-027-67849912	sales@chemwish.com	China	35906	56
Shanghai Hanhong Scientific Co.,Ltd.	021-54306202 13764082696;	info@hanhongsci.com	China	42982	64
Syntechem Co.,Ltd		info@syntechem.com	China	12990	57
Bide Pharmatech Ltd.	400-1647117 15221909166	product02@bidepharm.com	China	41438	60

Supplier	Advantage
CONIER CHEM AND PHARMA LIMITED	58
Career Henan Chemica Co	58
Aromsyn Co., Ltd.	58
LEAPCHEM CO., LTD.	58
Aladdin Scientific	58
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Wuhan Chemwish Technology Co., Ltd	56
Shanghai Hanhong Scientific Co.,Ltd.	64
Syntechem Co.,Ltd	57
Bide Pharmatech Ltd.	60

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4-METHOXYPHENYL ISOCYANIDE Benzene, 1-isocyano-4-methoxy- (9CI) p-Anisoleisonitrile Anisyl isonitrile p-Anisyl isocyanide p-Anisyl isonitrile 4-Methoxyphenyl isocyanide 97% P-ANISOYL ISONITRILE HANSA ISN-0053 p-Methoxyphenyl isocyanide benzene, 1-isocyano-4-methoxy- 4-Isocyanoanisole 1-ISOCYANO-4-METHOXYBENZENE 10349-38-9 H3COC6H4NC Building Blocks Organic Building Blocks Isocyanides Nitrogen Compounds ISONITRITE Isocyanides Nitrogen Compounds Organic Building Blocks