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ChemicalBook >> CAS DataBase List >>(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Structure
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP structure
CAS No.
856407-37-9
Chemical Name:
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
Synonyms
(R)-SITCP;17ef]phosphocin, min. 97% (R)-SITCP;(R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane;(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd;(R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane;(R)-SITCP,(R)-dimethylene-[7,7′-(1,1′-spiro indan)]-phenylphospholane;(11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin;4H-Diindeno[7,1-cd:1',7'-ef]phosphocin, 5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)-;4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI);(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
CBNumber:
CB62526469
Molecular Formula:
C25H23P
Molecular Weight:
354.42
MDL Number:
MFCD17018763
MOL File:
856407-37-9.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Properties

Melting point 148-149°C
alpha +6° (c 0.5, CH2Cl2)
Boiling point 505.6±50.0 °C(Predicted)
form solid
color white
Sensitive air sensitive

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-5184 (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1,7-ef]phosphocin, min. 97% (R)-SITCP 856407-37-9 25mg $108 2024-03-01 Buy
Strem Chemicals 15-5184 (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1,7-ef]phosphocin, min. 97% (R)-SITCP 856407-37-9 100mg $320 2024-03-01 Buy
AK Scientific 2467AQ (R)-SITCP 856407-37-9 50mg $809.6 2021-12-16 Buy
ChemScene CS-0037625 (R)-SITCP ≥97.0% 856407-37-9 25mg $110 2021-12-16 Buy
ChemScene CS-0037625 (R)-SITCP ≥97.0% 856407-37-9 50mg $210 2021-12-16 Buy
Product number Packaging Price Buy
15-5184 25mg $108 Buy
15-5184 100mg $320 Buy
2467AQ 50mg $809.6 Buy
CS-0037625 25mg $110 Buy
CS-0037625 50mg $210 Buy

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Chemical Properties,Uses,Production

Reaction

  1. Phosphine-catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
  2. Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylative [4+2] cyclization.
  3. Catalytic, enantioselective carbon-oxygen bond formation – phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
  4. Use of a new spirophosphine to achieve catalytic, enantioselective [4+1] annulations of amines with allenes to generate dihydropyrroles.
Reactions of 856407-37-9_1
Reactions of 856407-37-9_2

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Preparation Products And Raw materials

Raw materials

Preparation Products

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Suppliers

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Shanghai Arbor Chemical Co., Ltd. 		58
Labnetwork lnc. 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
BeiJing Hwrk Chemicals Limted 55
Daicel Chiral Technologies (China)CO.,LTD 65
T&W GROUP 58
Chengdu HuaXia Chemical Reagent Co. Ltd 58
Shanghai Chiral bio-compound co., Ltd. 58
LaaJoo 58
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI) (R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane (11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin (R)-SITCP (R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd 17ef]phosphocin, min. 97% (R)-SITCP 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin, 5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (R)-SITCP,(R)-dimethylene-[7,7′-(1,1′-spiro indan)]-phenylphospholane 856407-37-9 C25H23P Chiral Phosphine Chiral Spiro Ligand