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Copper(II) phthalocyanine

CAS No.
147-14-8
Chemical Name:
Copper(II) phthalocyanine
Synonyms
CUPC;PIGMENT BLUE 15;PHTHALOCYANINE BLUE;COPPER PHTHALOCYANINE;CI 74160;COPPER(II) PHTHALOCYANINE;cyanine blue;C.I. Pigment Blue 15:1;C.I. Pigment Blue 15:3;Monastral blue
CBNumber:
CB6255035
Molecular Formula:
C32H16CuN8
Molecular Weight:
576.07
MDL Number:
MFCD00010719
MOL File:
147-14-8.mol
MSDS File:
SDS
Last updated:2023-12-18 16:59:08

Copper(II) phthalocyanine Properties

Melting point 600°C (dec.)
Density 1.62[at 20℃]
storage temp. Inert atmosphere,Room Temperature
solubility insoluble in H2O, ethanol; soluble in concHSO 4
Colour Index 74160
form Fine Crystalline Powder
color Dark blue
Odor odorless
Water Solubility <0.1 g/100 mL at 20 ºC
λmax 602nm(CHCl3)(lit.)
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
Merck 14,2520
BRN 4121848
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey XCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP -1 at 23℃
FDA 21 CFR 74.3045; 178.3297
Indirect Additives used in Food Contact Substances PHTHALOCYANINE BLUE
EWG's Food Scores 1-4
FDA UNII 3VEX9T7UT5
NIST Chemistry Reference Copper phthalocyanine(147-14-8)
EPA Substance Registry System C.I. Pigment Blue 15 (147-14-8)
Absorption λmax 678 nm (DMF)

SAFETY

Risk and Safety Statements

Safety Statements  22-24/25
WGK Germany  -
RTECS  GL8510000
TSCA  Yes
HS Code  32041300
Toxicity LD50 intraperitoneal in rat: > 3gm/kg
NFPA 704
0
0 0

Copper(II) phthalocyanine price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 252980 Copper(II) phthalocyanine β-form, Dye content 90 % 147-14-8 5g $34.5 2024-03-01 Buy
Sigma-Aldrich 252980 Copper(II) phthalocyanine β-form, Dye content 90 % 147-14-8 25g $59.3 2024-03-01 Buy
TCI Chemical P0655 Pigment Blue 15 147-14-8 25g $64 2024-03-01 Buy
TCI Chemical P1005 Copper(II) Phthalocyanine (α-form) >90.0%(T) 147-14-8 25g $21 2024-03-01 Buy
Alfa Aesar 043650 Copper(II) phthalocyanine 147-14-8 10g $36 2024-03-01 Buy
Product number Packaging Price Buy
252980 5g $34.5 Buy
252980 25g $59.3 Buy
P0655 25g $64 Buy
P1005 25g $21 Buy
043650 10g $36 Buy

Copper(II) phthalocyanine Chemical Properties,Uses,Production

Description

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.

Chemical Properties

dark blue fine crystalline powder

Uses

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.

Application

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic&ndash;organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.

General Description

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10-4 cm2/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.

Flammability and Explosibility

Not classified

Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

BLUE POWDER

SHADE

REDDISH

HEAT RESISTANCE

300 °C min

LIGHT FASTNESS

7-8

ACID RESISTANCE

5

ALKALI RESISTANCE

5

FASTNESS TO BLEEDING

5

OIL ABSORPTION

40-45%

SPECIFIC SURFACE

29 m 2 /g

DENSITY

1.60 g/cm 3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBLE

1.0% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

100-105 %

Purification Methods

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

Global( 430)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Hebei Dongdu Import and Export Co. LTD
+86-15333296769 +86-15333296769 manager@cndongdu.com China 71 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21703 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29919 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Winchem industrial co limited
+86-0086-574-83851061 +86-13003762012 lucyhu@win-chemical.com China 300 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47464 58

View Lastest Price from Copper(II) phthalocyanine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
 CuPC pictures 2024-03-19 CuPC
147-14-8
US $0.00 / g 1g 99.5% 100kgs Zhejiang Free Trade Zone Violet Trade Co., Ltd.
phthalocyanine blue pictures 2023-12-20 phthalocyanine blue
147-14-8
US $5.00 / kg 1kg 99% 5000ton Hebei Dongdu Import and Export Co. LTD
Copper(II) phthalocyanine pictures 2023-09-07 Copper(II) phthalocyanine
147-14-8
US $10.00 / KG 1KG 99% 5tons Hebei Guanlang Biotechnology Co., Ltd.
  •  CuPC pictures
  • CuPC
    147-14-8
  • US $0.00 / g
  • 99.5%
  • Zhejiang Free Trade Zone Violet Trade Co., Ltd.
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