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Copper(II) phthalocyanine

Copper(II) phthalocyanine structure

CAS No.: 147-14-8

Chemical Name:: Copper(II) phthalocyanine

Synonyms: CUPC;PIGMENT BLUE 15;PHTHALOCYANINE BLUE;COPPER PHTHALOCYANINE;CI 74160;COPPER(II) PHTHALOCYANINE;cyanine blue;C.I. Pigment Blue 15:1;C.I. Pigment Blue 15:3;Monastral blue

CBNumber:: CB6255035

Molecular Formula:: C32H16CuN8

Molecular Weight:: 576.07

MDL Number:: MFCD00010719

MOL File:: 147-14-8.mol

MSDS File:: SDS

Modify Date:2022-12-21 16:56:50

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Copper(II) phthalocyanine Properties

Melting point	600°C (dec.)
Density	1.62[at 20℃]
storage temp.	Inert atmosphere,Room Temperature
Colour Index	74160
form	Fine Crystalline Powder
color	Dark blue
Water Solubility	<0.1 g/100 mL at 20 ºC
λmax	602nm(CHCl3)(lit.)
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
Merck	14,2520
BRN	4121848
Exposure limits	ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey	XCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP	-1 at 23℃
FDA 21 CFR	74.3045; 178.3297
Indirect Additives used in Food Contact Substances	PHTHALOCYANINE BLUE
EWG's Food Scores	1-4
FDA UNII	3VEX9T7UT5
NIST Chemistry Reference	Copper phthalocyanine(147-14-8)
EPA Substance Registry System	C.I. Pigment Blue 15 (147-14-8)
Absorption	λmax 678 nm (DMF)

SAFETY

Risk and Safety Statements

Safety Statements

22-24/25

WGK Germany

RTECS

GL8510000

TSCA

Yes

HS Code

32041300

Toxicity

LD50 intraperitoneal in rat: > 3gm/kg

NFPA 704

	0
0		0

Copper(II) phthalocyanine price More Price(34)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	252980	Copper(II) phthalocyanine β-form, Dye content 90 %	147-14-8	5g	$32.9	2023-01-07	Buy
Sigma-Aldrich	252980	Copper(II) phthalocyanine β-form, Dye content 90 %	147-14-8	25g	$56.5	2023-01-07	Buy
TCI Chemical	P0655	Pigment Blue 15	147-14-8	25g	$30	2023-01-07	Buy
TCI Chemical	P1005	Copper(II) Phthalocyanine (α-form) >90.0%(T)	147-14-8	25g	$20	2023-01-07	Buy
Alfa Aesar	043650	Copper(II) phthalocyanine	147-14-8	10g	$31.5	2023-01-06	Buy

Product number	Packaging	Price	Buy
252980	5g	$32.9	Buy
252980	25g	$56.5	Buy
P0655	25g	$30	Buy
P1005	25g	$20	Buy
043650	10g	$31.5	Buy

Copper(II) phthalocyanine Chemical Properties,Uses,Production

Description

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.

Chemical Properties

dark blue fine crystalline powder

Uses

Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.

Application

Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic–organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.

General Description

Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10^-4 cm²/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.

Flammability and Explosibility

Notclassified

Properties and Applications

TEST ITEMS	SPECIFICATION
APPEARANCE	BLUE POWDER
SHADE	REDDISH
HEAT RESISTANCE	300 °C min
LIGHT FASTNESS	7-8
ACID RESISTANCE	5
ALKALI RESISTANCE	5
FASTNESS TO BLEEDING	5
OIL ABSORPTION	40-45%
SPECIFIC SURFACE	29 m ² /g
DENSITY	1.60 g/cm ³
RESIDUE ON 80 MESH	5.0% max
WATER SOLUBLE	1.0% max
VOLATITE 105 °C	1.0% max
TINTING STRENGTH	100-105 %

Purification Methods

Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

Copper(II) phthalocyanine Preparation Products And Raw materials

Raw materials

Xylene FUMING SULFURIC ACID Copper(II) chloride dihydrate Ammonium molybdate tetrahydrate Potassium iodide

Calcium chloride Chlorine Ammonium molybdate Urea Ammonium chloride

Copper(II) chloride dihydrate Copper(I) chloride Phthalic anhydride Hydrochloric acid Sodium hydroxide

1,2,4-Trichlorobenzene Sulfuric acid Zinc stearate

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Preparation Products

4923 Spirit Light Fast Ball-pen Blue GR Reactive Turquoise Blue Kn-G Various color alkyd primer Various color amino baking enamel A04-9 POLYSULFONE

Alkyd enamel CI Pigment Blue 15:3 (74160) Direct Blue 199 Various color nitrocellulose exterior enamel Q04-2 Amino resin paint

Reactive Blue 231 Direct Blue 86 Chromium(III) oxide Reactive Blue 14 Ferro phthalocyanine green

Pigment Geen 7 Sulphur Green 14 ACID BLUE 249 REACTIVE BLUE 15

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Copper(II) phthalocyanine Suppliers

Global( 369)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan DaKen Chemical CO.,LTD.	+86-371-66670886	info@dakenchem.com	China	17713	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21975	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2990	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29922	58
Hubei Jusheng Technology Co.,Ltd.	86-18871470254	linda@hubeijusheng.com	CHINA	28185	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22973	58
Chongqing Chemdad Co., Ltd	86-13650506873	sales@chemdad.com	China	39915	58
Winchem industrial co limited	+86-0086-574-83851061 +86-13003762012	lucyhu@win-chemical.com	China	300	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	47427	58
Richest Group Ltd	18017061086	oled@richest-group.com	CHINA	5601	58

Supplier	Advantage
Henan DaKen Chemical CO.,LTD.	58
Henan Tianfu Chemical Co.,Ltd.	55
Hefei TNJ Chemical Industry Co.,Ltd.	55
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Hubei xin bonus chemical co. LTD	58
Chongqing Chemdad Co., Ltd	58
Winchem industrial co limited	58
CONIER CHEM AND PHARMA LIMITED	58
Richest Group Ltd	58

View Lastest Price from Copper(II) phthalocyanine manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-03-29	CuPC 147-14-8	US $0.00 / g	1g	99.5%	100kgs	Zhejiang Free Trade Zone Violet Trade Co., Ltd.
2022-12-12	PIGMENT BLUE 15:1 147-14-8	US $0.00 / kg	25kg	1	100mt	Winchem industrial co limited
2022-10-19	Copper(II) phthalocyanine 147-14-8	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.

CuPC
147-14-8
US $0.00 / g
99.5%
Zhejiang Free Trade Zone Violet Trade Co., Ltd.

PIGMENT BLUE 15:1
147-14-8
US $0.00 / kg
1
Winchem industrial co limited

Copper(II) phthalocyanine
147-14-8
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

Copper(II) phthalocyanine Spectrum

Copper(II) phthalocyanine(147-14-8)IR1 Copper(II) phthalocyanine(147-14-8)IR2 Copper(II) phthalocyanine(147-14-8)Raman Copper(II) phthalocyanine(147-14-8)ESR

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Copper, [29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-, (SP-4-1)- Copper, [phthalocyaninato(2-)]- phthalocyanine blueB15:0 Pigment Blue 15 (purified by sublimation) calcotonebluegp ceresbluebhr chromatexbluebn ciingrainblue2 cipigmentblue15 congoblueb-4 Copper phthalocyanine,CI 74160 Copper, [29H,31H-phthalocyaninato(2-)-N(29)-,N(30)-,N(31)-,N(32)-]-, (SP-4-1)- copper,(29h,31h-phthalocyaninato(2-)-n(sup29),n(sup30),n(sup31),n(sup32) Copper,[29H,31H-phthalocyaninato(2(-))-N²⁹,N³⁰,N³¹,N³²]-(SP-4-1)- copperphthalocyanin copperphthalocyanineblue cromophtalblue4g cyanbluebnc55-3745 cyanbluebnf55-3753 cyanbluegt55-3295 cyaninebluebb CyanineBlueBB,BF,GC,HB,LB cyaninebluec cyanpeacockblueg dainichicyanineblueb dainichicyaninebluefpg daltolitefastblueb duratintblue1001 fastogenblue5110 fastogenblueb fastoluxblue fenalacbluebdisp franconiabluea-4431 graphtolblue2gls graphtolbluebl helioblueb HelioFastBlueB,BB,BF,BRN,BT,GO,GOT,HB,HG heliofastbluebrn HeliogenBlue6480 heliogenblueb heliogenbluelbg HostapermBlueAFN,A3R indolenblue3g irgalitefastbrilliantbluebl isolfastblueb lbx5 Monastral blue B phthaloblue phthalocyanineblue15 pigmentblue15:4 PigmentphthalocyanineblueB PigmentphthalocyanineblueBN PigmentphthalocyanineblueBS PigmentphthalocyanineblueBX PigmentphthalocyanineblueFGX Copper(II) Phthalocyanine (alpha-form) Copper(II) Phthalocyanine (beta-form) Copper(II) phthalocyanine,CuPc, Phthalocyanine blue, Pigment Blue 15 Phthalocyanine Copper(II)