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Allylacetic acid

Description References
Allylacetic acid
Allylacetic acid structure
CAS No.
591-80-0
Chemical Name:
Allylacetic acid
Synonyms
4 PA;FEMA 2843;PENT-4-ENOATE;4-Pentensαure;AUYLACETICACID;Anulacetic acid;4-PENTENOIC ACID;4-PENTYNOIC ACID;ALLYLACETIC ACID;FEMA NUMBER 2843
CBNumber:
CB6264516
Molecular Formula:
C5H8O2
Formula Weight:
100.12
MOL File:
591-80-0.mol

Allylacetic acid Properties

Melting point:
54-57 °C(lit.)
Boiling point:
83-84 °C12 mm Hg(lit.)
Density 
0.981 g/mL at 25 °C(lit.)
vapor density 
>1 (vs air)
refractive index 
n20/D 1.428(lit.)
FEMA 
2843 | 4-PENTENOIC ACID
Flash point:
193 °F
storage temp. 
2-8°C
form 
Liquid
pka
pK1:4.677 (25°C)
Specific Gravity
0.981
color 
Clear colorless to light yellow
explosive limit
1.58%(V)
Water Solubility 
Soluble in alcohol, Slightly soluble in water
JECFA Number
314
BRN 
1633696
CAS DataBase Reference
591-80-0(CAS DataBase Reference)
NIST Chemistry Reference
4-Pentenoic acid(591-80-0)
EPA Substance Registry System
4-Pentenoic acid(591-80-0)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H314-H227-H318
Precautionary statements  P280-P305+P351+P338-P310-P210e-P260h-P303+P361+P353-P405-P501a
Hazard Codes  C,T
Risk Statements  34-22
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
RTECS  SC4751000
8-10-23
TSCA  T
HazardClass  8
PackingGroup  III
HS Code  29161980

Allylacetic acid price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 245925 4-Pentenoic acid 97% 591-80-0 25g $77 2018-11-13 Buy
Sigma-Aldrich 245925 4-Pentenoic acid 97% 591-80-0 5g $26.5 2018-11-13 Buy
TCI Chemical P0645 4-Pentenoic Acid >98.0%(GC)(T) 591-80-0 25mL $77 2018-11-22 Buy
TCI Chemical P0645 4-Pentenoic Acid >98.0%(GC)(T) 591-80-0 100mL $232 2018-11-22 Buy
Alfa Aesar A13991 4-Pentenoic acid, 98% 591-80-0 10g $31 2018-11-13 Buy

Allylacetic acid Chemical Properties,Uses,Production

Description

Allylacetic acid (allyl acetate) is a derivative of acetate. It is the acetate ester of allyl alcohol. It is useful industrial intermediate. It is the precursor of some special polymer such as drying oils. It can also be used as a useful allylating reagent for catalyzing the allylation of aldehydes, and also allylation of aryl bromides in the palladium-catalyzed cross-coupling reaction. It has also demonstrated that it is a potential fumigant against grain beetle pests; study has shown that doses of 50–150 mg litre?1 with 24–120-h exposures are necessary to achieve 100% mortality of all life stages against grain beetle pests. Study has also shown that ally acetate is an effective oxidants during the Palladium— Iminophosphine-Catalyzed Homocoupling of Alkynylstannanes and Other Organostannanes

References

Denmark, S. E., and S. T. Nguyen. "Catalytic, nucleophilic allylation of aldehydes with allyl acetate. " Organic Letters 11.3 (2009):781-4.
Yokoyama, Y., et al. "ChemInform Abstract: Palladium- Catalyzed Cross-Coupling Reaction: Direct Allylation of Aryl Bromides with Allyl Acetate."Chemischer Informationsdienst 26.52 (1986):6457-6460.
Rajendran, Dr Somiahnadar, and N. Muralidharan. "Effectiveness of allyl acetate as a fumigant against five stored grain beetle pests." Pest Management Science 61.1(2005):97-101.
Shirakawa, Eiji, et al. "Palladium—Iminophosphine-Catalyzed Homocoupling of Alkynylstannanes and Other Organostannanes Using Allyl Acetate or Air as an Oxidant." Journal of Organometallic Chemistry670.1(2003):132-136.

Chemical Properties

clear colorless to light yellow liquid

Chemical Properties

4-Pentenoic acid has a sour, caramellic flavor with sweet aftertaste. It has an acrid flavor and odor at high levels.

Uses

Sulfonation yields the corresponding γ-lactone.1

Definition

ChEBI: A pentenoic acid having the double bond at position 4.

Preparation

By decarboxylation via heating allylmalonic acid; from the corresponding ethyl ester prepared by boiling ethyl 4-chloron- valerate in quinoline.

Allylacetic acid Preparation Products And Raw materials

Raw materials

Preparation Products


Allylacetic acid Suppliers

Global( 181)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19918 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21714 58
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30002 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23980 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28236 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 8921 58
hdzhl biotechnology co., ltd
86-13032617415
sales@luchibiology.com CHINA 1173 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35440 58
Tianjin Danjun International Trade Co., Ltd. 15822601686
- shashasong@163.com CHINA 297 58

View Lastest Price from Allylacetic acid manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-04-03 4-Pentenoic Acid Allylacetic acid in stock Factory
591-80-0
US $1.00 / KG 1KG TOP 3 Factory in China Top 3 largest production capacity Factory Chemwill Asia Co.,Ltd.
2019-08-07 Allylacetic acid
591-80-0
US $1.00 / KG 1KG 98% 100KG career henan chemical co

Allylacetic acid Spectrum


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