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5-Hydroxymethylfurfural

5-Hydroxymethylfurfural
5-Hydroxymethylfurfural structure
CAS No.
67-47-0
Chemical Name:
5-Hydroxymethylfurfural
Synonyms
HMF;5-HMF;-2-furaL;5-HydroxyMethy;5-(HydroxyMethyl)-;TIMTEC-BB SBB004259;Furfural Impurity 2;Hydroxymethyl Water;5-Oxymethylfurfurole;5-HydroMethylfurfural
CBNumber:
CB6266813
Molecular Formula:
C6H6O3
Formula Weight:
126.11
MOL File:
67-47-0.mol

5-Hydroxymethylfurfural Properties

Melting point:
28-34 °C (lit.) 28-34 °C (lit.)
Boiling point:
114-116 °C/1 mmHg (lit.)
Density 
1.243 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.562(lit.)
Flash point:
175 °F
storage temp. 
2-8°C
form 
Liquid or Crystalline Powder and/or Chunks
pka
12.82±0.10(Predicted)
color 
Light yellow to yellow
Water Solubility 
Soluble in water, alcohol, ethyl acetate, acetone, dimethylformamide, benzene, ether and chloroform.
Sensitive 
Air & Light Sensitive
Merck 
14,4832
BRN 
110889
Stability:
Light Sensitive, Very Hygroscopic
InChIKey
NOEGNKMFWQHSLB-UHFFFAOYSA-N
CAS DataBase Reference
67-47-0(CAS DataBase Reference)
EWG's Food Scores
1
NIST Chemistry Reference
2-Furancarboxaldehyde, 5-(hydroxymethyl)-(67-47-0)
EPA Substance Registry System
2-Furancarboxaldehyde, 5-(hydroxymethyl)- (67-47-0)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H227-H412-H303-H335-H315-H319
Precautionary statements  P210-P264-P273-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P403+P235-P501-P261-P280a-P304+P340-P405-P501a-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38-52/53
Safety Statements  26-36-24/25
WGK Germany  2
RTECS  LT7031100
8-10
TSCA  Yes
HS Code  29321900
Toxicity LD50 orally in Rabbit: 2500 mg/kg

5-Hydroxymethylfurfural price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20678 5-Hydroxymethyl-2-furancarbaldehyde for synthesis 67-47-0 100 mg $22.2 2021-03-22 Buy
Sigma-Aldrich 8.20678 5-Hydroxymethyl-2-furancarbaldehyde for synthesis 67-47-0 1 g $41.16 2021-03-22 Buy
Sigma-Aldrich W501808 5-(Hydroxymethyl)furfural ≥99%, FG 67-47-0 1 g $60 2021-03-22 Buy
Sigma-Aldrich H40807 5-Hydroxymethyl-2-furaldehyde 99% 67-47-0 1g $66.1 2021-03-22 Buy
Sigma-Aldrich 8.20678 5-Hydroxymethyl-2-furancarbaldehyde for synthesis 67-47-0 5 g $150.77 2021-03-22 Buy

5-Hydroxymethylfurfural Chemical Properties,Uses,Production

Chemical Properties

Beige Coloured Crystalline Solid

Uses

As an indicator for excess heat-treatment in sugar-containing food.

Uses

An antioxidant for grape and apple juice.

Definition

ChEBI: A member of the class of furans that is furan which is substituted at positions 2 and 5 by formyl and hydroxymethyl substituents, respectively. Virtually absent from fresh foods, it is naturally generated in sugar-containing foods during storage, and espec ally by drying or cooking. It is the causative component in honey that affects the presystemic metabolism and pharmacokinetics of GZ in-vivo.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 7259, 1994 DOI: 10.1021/jo00103a016

Safety Profile

Questionable carcinogen with experimental tumorigenic data.Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES

Metabolic pathway

When 5-hydroxymethyl-2-furaldehyde (HMF) is administered orally or intravenously to rats, HMF or its metabolites are rapidly eliminated in the urine with the recovery of 95 ? 100% after 24 h. HMF is completely converted to two metabolites which are identified as 5- hydroxymethyl-2-furoic acid and N-(5-hydroxymethyl-2- furoyl)glycine.

Purification Methods

Crystallise it from diethyl ether/pet ether. [Beilstein 18 III/IV 100, 18/1 V 130.]

5-Hydroxymethylfurfural Preparation Products And Raw materials

Raw materials

Preparation Products


5-Hydroxymethylfurfural Suppliers

Global( 489)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Zhejiang Sugar Energy Technology Co., Ltd
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View Lastest Price from 5-Hydroxymethylfurfural manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-10-20 5-hydroxymethylfurfural
67-47-0
US $10.00 / KG 1KG 99% 1000MT/Month Wuhan wingroup Pharmaceutical Co., Ltd
2021-09-19 5-Hydroxymethylfurfural
67-47-0
US $1.10 / g 1g 99.9% 100 Tons min Dideu Industries Group Limited
2021-09-14 5-Hydroxymethylfurfural
67-47-0
US $1208.00 / KG 1KG 99 10T Baoji Guokang Healthchem co.,ltd

5-Hydroxymethylfurfural Spectrum


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