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Chemical Name:
PNT;4NT;nci9579;4-Nitrotol;NCI-C60537;'LGC' (2401);nitrotoluenos;4-Nitrotoluol;p-Nitrotoluol;4-nitrobenzene
Molecular Formula:
Formula Weight:
MOL File:

4-Nitrotoluene Properties

Melting point:
52-54 °C(lit.)
Boiling point:
238 °C(lit.)
1.392 g/mL at 25 °C(lit.)
vapor density 
4.7 (vs air)
vapor pressure 
5 mm Hg ( 85 °C)
refractive index 
Flash point:
223 °F
storage temp. 
Crystalline Solid
explosive limit
Water Solubility 
0.35 g/L (20 ºC)
Stability May be shock sensitive. Incompatible with sulfuric acid, strong bases, reducing agents, strong oxidizing agents.
CAS DataBase Reference
99-99-0(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-methyl-4-nitro-(99-99-0)
EPA Substance Registry System
Benzene, 1-methyl-4-nitro-(99-99-0)
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N,F,Xn
Risk Statements  23/24/25-33-51/53-36/37/38-11-36-20/21/22
Safety Statements  28-37-45-61-28A-27-16-36/37-26
RIDADR  UN 3446 6.1/PG 2
WGK Germany  2
RTECS  XT3325000
HazardClass  6.1
PackingGroup  II
HS Code  29042000
Hazardous Substances Data 99-99-0(Hazardous Substances Data)
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P311 Call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P403+P235 Store in a well-ventilated place. Keep cool.

4-Nitrotoluene price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 31568 4-Nitrotoluene analytical standard 99-99-0 250mg $26.2 2017-11-08 Buy
Sigma-Aldrich 47242 4-Nitrotoluene solution 99-99-0 1EA $29.2 2017-11-08 Buy
TCI Chemical N0276 4-Nitrotoluene >99.0%(GC) 99-99-0 25g $14 2017-12-01 Buy
TCI Chemical N0276 4-Nitrotoluene >99.0%(GC) 99-99-0 500g $32 2017-12-01 Buy
Alfa Aesar A14398 4-Nitrotoluene, 99% 99-99-0 100g $0 2017-11-08 Buy

4-Nitrotoluene Chemical Properties,Uses,Production

Chemical Properties

light yellow crystals


manufacture of dyes, toluidines, nitrobenzoic acids, agricultural and rubber chemicals.

General Description

A yellow liquid with a weak aromatic odor. Toxic. Insoluble in water. Combustible but may take some effort to ignite. Produces toxic oxides of nitrogen when burned. In a spill, immediate steps should be taken to limit its spread to the environment. Can easily penetrate the soil and contaminate groundwater or nearby streams. Used to make other chemicals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Nitrotoluene may react violently with sodium, tetranitromethane, strong oxidizing agents , sulfuric acid and other acids.

Health Hazard

INHALATION, INGESTION, OR SKIN: Headache, flushed face, dizziness, dyspnea (difficult breathing), cyanosis, nausea, vomiting, muscular weakness, rapid pulse and respiration, irritability, and convulsions.

Fire Hazard

Special Hazards of Combustion Products: Yields toxic oxides of nitrogen when burning.

Purification Methods

Dry it in air, then dry it in a vacuum desiccator over H2SO4. [Wright & Grilliom J Am Chem Soc 108 2340 1986, Beilstein 5 IV 848.]

4-Nitrotoluene Preparation Products And Raw materials

Raw materials

Preparation Products

4-Nitrotoluene Suppliers

Global( 171)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Hebei Guanlang Biotechnology Co., Ltd.
+86-0311-66562153 whatsapp +8615203118427
+86-0311-66562153 CHINA 418 50
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 CHINA 1374 55
Mainchem Co., Ltd.
+86-0592-6210733 CHINA 32765 55
Dalian Pinmai Biotechnology Co., Ltd
+86-13230167943 CHINA 310 58
Hebei Atun Trading Co.Ltd
0311-86786001 CHINA 323 58
Dalian Idery Biotechnology Co., Ltd. 0411-62696576/0411-66160116/15141125520
0411-66160116 China 67 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933; China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) China 40399 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 China 30308 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 China 22909 81

View Lastest Price from 4-Nitrotoluene manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-07-27 4-Nitrotoluene
US $100.00 / G 10G 99% 500kg/month -
2018-08-13 4-Nitrotoluene
US $10.00 / KG 1KG 99% 100 MT per month -

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