ChemicalBook >> CAS DataBase List >>2,2,6,6-Tetramethylpiperidinooxy
2,2,6,6-Tetramethylpiperidinooxy
- CAS No.
- 2564-83-2
- Chemical Name:
- 2,2,6,6-Tetramethylpiperidinooxy
- Synonyms
- TEMPO;TEPO;2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY;2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL;2,2,6,6-Tetramethylpiperidin-1-oxyl;(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl;2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL;Tanane;Tanan;TEMPO,98%
- CBNumber:
- CB6309451
- Molecular Formula:
- C9H18NO*
- Molecular Weight:
- 156.25
- MDL Number:
- MFCD00009599
- MOL File:
- 2564-83-2.mol
- MSDS File:
- SDS
Last updated:2024-01-18 17:03:10
| Melting point | 36-38 °C(lit.) |
|---|---|
| Boiling point | 193°C |
| Density | 1 g/cm3 |
| vapor pressure | 0.4 hPa (20 °C) |
| refractive index | 1.4350 (estimate) |
| Flash point | 154 °F |
| storage temp. | Store below +30°C. |
| solubility | 9.7g/l |
| form | Powder |
| color | Yellow to green |
| PH | 8.3 (9g/l, H2O, 20℃) |
| Water Solubility | Soluble in all organic solvents. Insoluble in water. |
| Merck | 14,9140 |
| BRN | 1422418 |
| Stability | Stable. Incompatible with strong acids, strong oxidizing agents. Refrigerate. |
| InChIKey | RVWUHFFPEOKYLB-UHFFFAOYSA-N |
| CAS DataBase Reference | 2564-83-2(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | VQN7359ICQ |
| NIST Chemistry Reference | 1-Piperidinyloxy, 2,2,6,6-tetramethyl-(2564-83-2) |
| EPA Substance Registry System | 1-Piperidinyloxy, 2,2,6,6-tetramethyl- (2564-83-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314-H412 | |||||||||
| Precautionary statements | P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 34-36/37/38 | |||||||||
| Safety Statements | 26-36/37/39-45-24/25 | |||||||||
| RIDADR | UN 3263 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | TN8991900 | |||||||||
| Autoignition Temperature | 275 °C | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29333999 | |||||||||
| NFPA 704 |
|
2,2,6,6-Tetramethylpiperidinooxy price More Price(48)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 214000 | TEMPO 98% | 2564-83-2 | 1g | $28.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 214000 | TEMPO 98% | 2564-83-2 | 5g | $64.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.14681 | 2,2,6,6-Tetramethylpiperidine-1-oxyl (free radical) for synthesis | 2564-83-2 | 5G | $108 | 2022-05-15 | Buy |
| Sigma-Aldrich | 8.14681 | 2,2,6,6-Tetramethylpiperidine-1-oxyl (free radical) for synthesis | 2564-83-2 | 25g | $201 | 2022-05-15 | Buy |
| TCI Chemical | T1560 | 2,2,6,6-Tetramethylpiperidine 1-Oxyl Free Radical >98.0%(GC)(T) | 2564-83-2 | 5g | $45 | 2024-03-01 | Buy |
2,2,6,6-Tetramethylpiperidinooxy Chemical Properties,Uses,Production
Description
2,2,6,6-Tetramethylpiperidine is a product that is used for the most diverse purposes because of its strong basicity, for example, as a light stabilizer for polyolefins, as a cocatalyst in olefin polymerizations (Ziegler catalysts), as a building block for the synthesis of pharmaceuticals and crop protection products, as a cocatalyst in the synthesis of dichloroacetyl chloride. The 4-unsubstituted 2.2.6,6-tetramethylpiperidine is generally prepared from the corresponding 4-oxo compound. It is known that triacetonamine can be converted by hydrazine to the hydrazone, which is then cleaved in the presence of alkali into 2,26,6-tetramethylpiperidine and nitrogen.
Chemical Properties
orange crystals or powder
Characteristics
2,2,6,6-Tetramethylpiperidinooxy(TEMPO) has the characteristics of high yield, good selectivity, good stability, and recyclable use.
Uses
TEMPO(2,2,6,6-Tetramethylpiperidinooxy) is a stable radical prepared through the oxidation of 2,2,6,6-tetramethylpiperidine. TEMPO has a wide range of applications including use as a free radical scavenger, a reagent in organic synthe sis and as a structural probe in electron spin resonance spectroscopy. TEMPO can also be used as a mediator in free radical polymerization.
Uses
In organic chemistry as a radical trap, 2,2,6,6-Tetramethylpiperidinooxy can be used as a catalyst and in polymerization mediation.
Uses
TEMPO can be used:
- As a catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.
- As a catalytic oxidant in the iodobenzene diacetae oxidation of nerol to neral.
- For trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene.
- In the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.
Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air
General Description
For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.
Purification Methods
Purify TEMPO by sublimation (33o, water aspirator) [Hay & Fincke J Am Chem Soc 109 8012 1987, Keana Chem Rev 78 37 1978].
2,2,6,6-Tetramethylpiperidinooxy Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Global( 631)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Nanjing Liskon Biological Technology Co., Ltd | 025-52110956 +8613814852963 | sales@liskonchem.com | China | 7 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7534 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9350 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
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View Lastest Price from 2,2,6,6-Tetramethylpiperidinooxy manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-23 | 2,2,6,6-Tetramethylpiperidinooxy
2564-83-2
|
US $12.00 / KG | 1KG | 99% | 200mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-01-18 | 2,2,6,6-Tetramethylpiperidinooxy
2564-83-2
|
US $6.00-0.60 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-08-04 | 2,2,6,6-Tetramethylpiperidinooxy
2564-83-2
|
US $10.00 / KG | 1KG | 99% | 5000000kg | Hebei Mojin Biotechnology Co., Ltd |
-
- 2,2,6,6-Tetramethylpiperidinooxy
2564-83-2
- US $12.00 / KG
- 99%
- Jinan Finer Chemical Co., Ltd
-
- 2,2,6,6-Tetramethylpiperidinooxy
2564-83-2
- US $6.00-0.60 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 2,2,6,6-Tetramethylpiperidinooxy
2564-83-2
- US $10.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
2564-83-2(2,2,6,6-Tetramethylpiperidinooxy)Related Search:
Haloperidol
Benzoyl peroxide
Triacetonediamine
2,2,6,6-Tetramethyl-4-piperidinol
1,2,2,6,6-Pentamethyl-4-piperidinol
2,2,6,6-Tetramethylpiperidine
Triacetonamine
4-Hydroxy-2,2,6,6-tetramethylpiperidinooxy radical,4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxy
Diphenoxylate
3,5-Dibromo-4-oxo-2,2,6,6-tetramethylpiperidin-1-yl
4-Acetylamino-2,2,6,6-tetramethylpiperidin-N-oxyl,4-Acetamido-2,2,6,6-tetramethylpiperidinooxy,4-ACETYLAMINO-2,2,6,6-TETRAMETHYLPIPERIDIN-1-OXYL
4-OXO-2,2,6,6-TETRAMETHYLPIPERIDINOOXY, FREE RADICAL,4-OXO-2,2,6,6-TETRAMETHYLPIPERIDINOOXY,4-Oxo-2,2,6,6-tetramethylpiperidinooxy, 95%, free radical
4-Amino-TEMPO, free radical
4-BENZOYLOXY-TEMPO
[4-Methoxy-2,2,6,6-tetramethylpiperidinooxy]radical
1of4
TEMPO, FREE RADICAL
2,2,6,6-Tetramethyl-1-piperidyloxy
2,2,6,6-Tetramethylpiperidin-1-oxy
2,2',6,6'-Tetramethylpiperidin-1-oxyl
2,2,6,6-TETRAMETHYLPIPERIDINOOXY
2,2,6,6-TETRAMETHYLPIPERIDINOOXY, FREE RADICAL
2,2,6,6-TETRAMETHYL PIPERIDINOXY
2,2,6,6-TETRAMETHYLPIPERIDINOXY FREE RADICAL
2,2,6,6-TETRAMETHYL-4-PIPERIDINYLOXY
2,2,6,6-TETRAMETHYLPIPERIDIN-1-OXYL FREE RADICAL
2,2,6,6-TETRAMETHYL-1-PIPERIDINOOXY
2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY,FREE RADICAL
2,2,6,6-TETRAMETHYL-1-PIPERIDINYLOXY, RADICAL
TETRABUTYLAMMONIUM HYDROXIDE 1.0M SOLN&
2,2,6,6-Tetramethyl-1-Piperidinyloxy(Tempo)
2,2,6,6-Tetramethyl-1-piperidinyloxiTEMPO
2,2,6,6-Tetramethylpiperidine-1-oxyl(TEMPO,freeradical)
1-Piperidinyloxy, 2,2,6,6-tetramethyl-
2,2,6,6-TETRAMETHYLPIPERIDINOOXY (TEMPO)
2,2,6,6-TETRAMETHYLPIPERIDINYLOXY / TEMPO, FREE RADICAL
2,2,6,6-Tetramethylpiperidine-1-oxyl, free radical
TEMPO FREE RADICAL (2,2,6,6-TETRAMETHYLPIPERIDINOOXY)
2,2,6,6-tetramethylpiperidinyloxy,free radical
1-Oxy-2,2,6,6-tetramethylpiperidine, free radical
TEMPO, free radical, 98+%
TEMPO/2,2,6,6-TETRAMETHYLPIPERIDINOOXY
free radical, 2,2,6,6-Tetramethylpiperidine 1-oxyl
2,2,6,6-Tetramethylpiperidine-1-oxyl (free radical) for synthesis
1,1,5,5-Tetramethylpentamethylene nitroxide
1-Oxyl-2,2,6,6-tetramethylpiperidine
1-Piperidinyloxy radical, 2,2,6,6-tetramethyl-
2,2,6,6-Tetramethyl-1-oxylpiperidine
2,2,6,6-Tetramethyl-1-piperadoxyl
2,2,6,6-tetramethyl-1-piperidinylox
TEMPO, free radica
TEMPO,2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical, 2,2,6,6-Tetramethylpiperidine 1-oxyl, TEMPO
2,2,6,6-Tetramethylpiperidine 1-oxyl, free radical - solid melt
TEMPO Oxidation Agent
2,2,6,6-Tetramethylpiperidine 1-oxyl, free radical - free flowing milled solid
2,2,6,6-TetraMethylpiperidinooxy, 98% 5GR
2,2,6,6-Tetramethylpiperidine N-oxide
2,2,6,6-Tetramethylpiperidinooxy ,98%
(2,2,6,6-Tetramethylpiperidin-1-yloxy)radical
2,2,6,6-Tetramethyl-4-piperidone,free radical
2,2,6,6-tetramethylperidinooxy
Piperidinooxy, 2,2,6,6-tetramethyl-
tetramethylpiperidinenitroxide
2,2,6,6-TETRAMETHYLPIPERIDINE-1-N-OXYL
2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL, RADICAL
2,2,6,6-TETRAMETHYLPIPERIDINEOXIDE
2,2,6,6-tetramethyl-4-piperidine 1-oxy, radical
2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical, 2,2,6,6-Tetramethylpiperidine 1-oxyl, TEMPO
2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical, TEMPO
2,2,6,6-Tetramethylpiperidine nitroxide
2,2,6,6-Tetramethylpiperidine nitroxide radical
2,2,6,6-Tetramethylpiperidine N-oxide radical
2,2,6,6-Tetramethylpiperidine N-oxyl radical
2,2,6,6-tetramethyl-piperidinoox