ChemicalBook >> CAS DataBase List >>4-Bromomethylbenzoic acid

4-Bromomethylbenzoic acid

CAS No.
6232-88-8
Chemical Name:
4-Bromomethylbenzoic acid
Synonyms
4-(BROMOMETHYL)BENZOIC ACID;ALPHA-BROMO-P-TOLUIC ACID;4-Bromomethylbenzoic;ALPHA-BROMO-P-TOLUYLIC ACID;AKOS BBS-00006715;Eprosartan USP RC D;RARECHEM AL BO 0068;A-BROMO-P-TOLUIC ACID;á-Bromo-p-toluic acid;à-bromo-p-toluic acid
CBNumber:
CB6317157
Molecular Formula:
C8H7BrO2
Molecular Weight:
215.04
MDL Number:
MFCD00002567
MOL File:
6232-88-8.mol
MSDS File:
SDS
Last updated:2023-07-27 17:50:07

4-Bromomethylbenzoic acid Properties

Melting point 224-229 °C(lit.)
Boiling point 252.95°C (rough estimate)
Density 1.5313 (rough estimate)
refractive index 1.5500 (estimate)
storage temp. Store below +30°C.
form Crystalline Powder
pka 4.10±0.10(Predicted)
color White to beige
Water Solubility Soluble in water.
BRN 1862870
InChIKey CQQSQBRPAJSTFB-UHFFFAOYSA-N
CAS DataBase Reference 6232-88-8(CAS DataBase Reference)
EPA Substance Registry System Benzoic acid, 4-(bromomethyl)- (6232-88-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS05
Signal word  Warning
Hazard statements  H318-H314-H315-H319-H335
Precautionary statements  P309-P310-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501-P305+P351+P338
Hazard Codes  Xi,C
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  3261
WGK Germany  3
19-21
Hazard Note  Irritant
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29163900
NFPA 704
1
2 0

4-Bromomethylbenzoic acid price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 159549 4-(Bromomethyl)benzoic acid 97% 6232-88-8 5g $51.1 2024-03-01 Buy
Sigma-Aldrich 1238251 Eprosartan Related Compound D United States Pharmacopeia (USP) Reference Standard 6232-88-8 15mg $511 2024-03-01 Buy
TCI Chemical B0845 4-(Bromomethyl)benzoic Acid >97.0%(GC)(T) 6232-88-8 5g $24 2024-03-01 Buy
TCI Chemical B0845 4-(Bromomethyl)benzoic Acid >97.0%(GC)(T) 6232-88-8 25g $66 2024-03-01 Buy
Alfa Aesar L03371 4-(Bromomethyl)benzoic acid, 97% 6232-88-8 5g $38.65 2024-03-01 Buy
Product number Packaging Price Buy
159549 5g $51.1 Buy
1238251 15mg $511 Buy
B0845 5g $24 Buy
B0845 25g $66 Buy
L03371 5g $38.65 Buy

4-Bromomethylbenzoic acid Chemical Properties,Uses,Production

Chemical Properties

white to beige crystalline powder

Uses

4-(Bromomethyl)benzoic acid was used in the chemical modification of 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (temoporfin), second generation photosensitizer. It was also used in the synthesis of 4-(5-arylidene-2,4-dioxothiazolidin-3-yl) methylbenzoic acids.

Uses

4-(Bromomethyl)benzoic acid acts as an intermediate in the synthesis of eprosartan, which is used as an antihypertensive agent. Further, it is used in the preparation of 5,10,15,20-tetra(m-hydroxyphenyl)chlorin (temoporfin), which is a second generation photosensitizer. In addition to this, it is used in the preparation of 4-(5-arylidene-2,4-dioxothiazolidin-3-yl) methylbenzoic acids.

Uses

4-(Bromomethyl)benzoic Acid is an intermediate in the synthesis of Eprosartan (E590100), a prototype of the imidazoleacrylic acid angiotensin II receptor antagonists used as an antihypertensive agent.

Purification Methods

Crystallise the acid from pKEst Me2CO. [Beilstein 9 IV 1745.]

99-94-5
6232-88-8
Synthesis of 4-Bromomethylbenzoic acid from p-Toluic acid
Global( 382)Suppliers
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Hebei Mojin Biotechnology Co., Ltd
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View Lastest Price from 4-Bromomethylbenzoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Bromomethylbenzoic acid pictures 2023-07-28 4-Bromomethylbenzoic acid
6232-88-8
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
4-Bromomethylbenzoic acid pictures 2023-04-14 4-Bromomethylbenzoic acid
6232-88-8
US $10.00 / KG 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
α-Bromo-p-toluic acid pictures 2022-08-20 α-Bromo-p-toluic acid
6232-88-8
US $100.00 / kg 1kg 99% 100 tons Hebei Duling International Trade Co. LTD
AKOS BBS-00006715 A-BROMO-P-TOLUIC ACID alpha-BroMo-p-toluic acid, 97% 50GR Eprosartan USP RC D Eprosartan related coMpound D 4-(BroMoMethyl)benzoic Acid, 95+% p-Toluic acid, .alpha.-bromo- p-Toluic acid, alpha-bromo- 4-(Bromomethyl)benzoic acid≥ 98% (HPLC) á-Bromo-p-toluic acid 4-(bromomethyl)-benzoicaci 4-CARBOXYBENZYL BROMIDE P-(BROMOMETHYL)BENZOIC ACID P-CARBOXYBENZYL BROMIDE RARECHEM AL BO 0068 alpha-bromo-para-toluic acid alpha-bromotoluic acid Benzoic acid, 4-(bromomethyl)- à-bromo-p-toluic acid α-bromo-p-toluic acid alpha-Bromo-p-toluic acid,97% 4-(Bromomethyl)benzoic acid,α-Bromo-p-toluic acid alpha-BroMo-p-toluic acid, 97% 10GR Eprosartan Impurity 4(Eprosartan USP RC D) Eprosartan USP Related Compound D Benzoidacid,4-(bromomethyl)- Alpha-Bromo-P-Toluic Acid , 4-Bromomethylbenzoic Acid 4-(Bromomethyl)benzoic Acid > Eprosartan Related Compound D (4-(bromomethyl)benzoic acid) (1238251) ALPHA-BROMO-P-TOLUYLIC ACID ALPHA-BROMO-P-TOLUIC ACID 4-(BROMOMETHYL)BENZOIC ACID 4-Bromomethylbenzoic α-Bromo-p-toluic acid 6232-88-8 6232-88-6 62832-88-8 BrCH2C6H4CO2H C8H6BrO2 Organic Building Blocks Carboxylic Acids Carbonyl Compounds C8 Building Blocks Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Organic acids Acids and Derivatives Halides Aromatics