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1,5-Diazabicyclo[4.3.0]non-5-ene

1,5-Diazabicyclo[4.3.0]non-5-ene structure

CAS No.: 3001-72-7

Chemical Name:: 1,5-Diazabicyclo[4.3.0]non-5-ene

Synonyms: DBN;1,5-Diazabicyclo[4.3.0]non-5-ene,DBN;Diazabicyclononene;1,5-Diazabicyclonon-5-ene;1,5-DIAZABICYCLO[4.3.0]-5-NONENE;2,3,4,6,7,8-Hexahydropyrrolo[1,2-a]pyrimidine;1,5-DiazabicycL;o[4.3.0]non-5-ene;L-CYSTEINE HCL MONO/ANHY;Diazabicyclononene (DBN)

CBNumber:: CB6322458

Molecular Formula:: C7H12N2

Molecular Weight:: 124.18

MDL Number:: MFCD00005554

MOL File:: 3001-72-7.mol

MSDS File:: SDS

Last updated:2024-03-28 16:55:20

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1,5-Diazabicyclo[4.3.0]non-5-ene Properties

Boiling point	95-98 °C7.5 mm Hg(lit.)
Density	1.005 g/mL at 25 °C(lit.)
refractive index	n20/D 1.519(lit.)
Flash point	202 °F
storage temp.	Store below +30°C.
solubility	soluble in Chloroform, Methanol
form	Liquid
pka	13.42±0.20(Predicted)
color	Clear colorless to yellow
Water Solubility	soluble
Sensitive	Air Sensitive
BRN	2417
InChIKey	SGUVLZREKBPKCE-UHFFFAOYSA-N
CAS DataBase Reference	3001-72-7(CAS DataBase Reference)
FDA UNII	978M4OL12Q
NIST Chemistry Reference	1,5-diazabicyclo[4.3.0]non-5-ene(3001-72-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05

Signal word

Danger

Hazard statements

H314

Precautionary statements

P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363

Hazard Codes

Risk Statements

Safety Statements

26-36/37/39-45

RIDADR

UN 3267 8/PG 2

WGK Germany

1-3-8-10

Hazard Note

Corrosive/Air Sensitive

HazardClass

PackingGroup

HS Code

29335995

NFPA 704

	1
3		1

1,5-Diazabicyclo[4.3.0]non-5-ene price More Price(45)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	8.03603	1,5-Diazabicyclo[4.3.0]non-5-ene for synthesis	3001-72-7	25mL	$74.1	2024-03-01	Buy
Sigma-Aldrich	8.03603	1,5-Diazabicyclo[4.3.0]non-5-ene for synthesis	3001-72-7	100mL	$255	2024-03-01	Buy
Sigma-Aldrich	136581	1,5-Diazabicyclo[4.3.0]non-5-ene 98%	3001-72-7	5g	$36.4	2024-03-01	Buy
Sigma-Aldrich	136581	1,5-Diazabicyclo[4.3.0]non-5-ene 98%	3001-72-7	25g	$92.8	2024-03-01	Buy
TCI Chemical	D1313	1,5-Diazabicyclo[4.3.0]-5-nonene >98.0%(GC)	3001-72-7	10mL	$18	2024-03-01	Buy

Product number	Packaging	Price	Buy
8.03603	25mL	$74.1	Buy
8.03603	100mL	$255	Buy
136581	5g	$36.4	Buy
136581	25g	$92.8	Buy
D1313	10mL	$18	Buy

1,5-Diazabicyclo[4.3.0]non-5-ene Chemical Properties,Uses,Production

Description

1,5-Diazabicyclo [4.3.0]non-5-ene is a amidine base used in organic synthesis. It is employed for dehydrohalogenation reactions as well as base-catalyzed rearrangements. It can also be used as the nucleophilic catalyst for the Friedel-Crafts acylation of pyrroles and indoles2. Further, it is used as a resin curing agent and polyurethane catalyst.

Reference

Taylor, James E., et al. "Friedel−Crafts Acylation of Pyrroles and Indoles using 1,5-Diazabicyclo[4.3.0]non-5-ene (DBN) as a Nucleophilic Catalyst." Cheminform 42.13(2015):5740.

Chemical Properties

clear colorless to yellowish liquid

Uses

1,5-Diazabicyclo[4.3.0]non-5-ene (DBN) is an amidine base commonly used in the base-mediated eliminations, condensations, esterifications, isomerizations, carboxylations and carbonylations.
It is used in the preparation of supertetrahedral chalcogenide clusters and single crystals of polymer-chalcogenide composites.
It also acts as a catalyst for the regioselective Friedel-Crafts C-acylation of pyrroles.

Uses

1,5-Diazabicyclo[4.3.0]non-5-ene is employed for dehydrohalogenation reactions and base-catalyzed rearrangements in organic synthesis. It is an amidine base used in organic synthesis. Further, it is used as a resin curing agent and polyurethane catalyst.

Definition

ChEBI: 1,5-diazabicyclo[4.3.0]-non-5-ene is a pyrrolopyrimidine.

Purification Methods

Distil DBN from BaO. It forms a hydroiodide on addition of 47% HI; dry it and dissolve it in MeCN, evaporate and repeat; recrystallise from EtOH, dry at 25o/1mm for 5hours, then at 80o/0.03mm for 12hours and store and dispense it in a dry box, m 154-156o [Jaeger et al. J Am Chem Soc 101 717 1979]. The methiodide is recrystallised from CHCl3/Et2O, m 248-250o, and hydrogen fumarate has m 159-160o and is crystallised from iso-PrOH [Rokach et al. J Med Chem 22 237 1979, Oediger et al. Chem Ber 99 2012 1966, Reppe et al. Justus Liebigs Ann Chem 596 210 1955]. [Beilstein 23/5 V 239.]

1,5-Diazabicyclo[4.3.0]non-5-ene Preparation Products And Raw materials

Raw materials

Sodium azide 3-Chloro-1-propanol 2-Pyrrolidinone Anisole Tosyl chloride

1,2-Dichloroethane Oxalyl chloride

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Preparation Products

5-Dibenzosuberenone

1,5-Diazabicyclo[4.3.0]non-5-ene Suppliers

Global( 273)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7786	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10248	58
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2967	58

Supplier	Advantage
Hebei Yanxi Chemical Co., Ltd.	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Shenzhen Nexconn Pharmatechs Ltd	58
Jinan Finer Chemical Co., Ltd	58

View Lastest Price from 1,5-Diazabicyclo[4.3.0]non-5-ene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-25	1,5-Diazabicyclo[4.3.0]non-5-ene 3001-72-7	US $0.00 / KG	1KG	≥98%	100mt/year	Jinan Finer Chemical Co., Ltd
2024-03-29	1,5-Diazabicyclo[4.3.0]non-5-ene 3001-72-7	US $6.00-0.20 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-09-08	2,3,4,6,7,8-hexahydropyrrolo[1,2-a]pyrimidine 3001-72-7	US $40.00-40.00 / kg	1kg	0.99	10 tons	Hebei Yanxi Chemical Co., Ltd.

1,5-Diazabicyclo[4.3.0]non-5-ene
3001-72-7
US $0.00 / KG
≥98%
Jinan Finer Chemical Co., Ltd

1,5-Diazabicyclo[4.3.0]non-5-ene
3001-72-7
US $6.00-0.20 / KG
99%
Henan Fengda Chemical Co., Ltd

2,3,4,6,7,8-hexahydropyrrolo[1,2-a]pyrimidine
3001-72-7
US $40.00-40.00 / kg
0.99
Hebei Yanxi Chemical Co., Ltd.

1,5-Diazabicyclo[4.3.0]non-5-ene Spectrum

1,5-Diazabicyclo[4.3.0]non-5-ene(3001-72-7)MS 1,5-Diazabicyclo[4.3.0]non-5-ene(3001-72-7)¹HNMR 1,5-Diazabicyclo[4.3.0]non-5-ene(3001-72-7)¹³CNMR 1,5-Diazabicyclo[4.3.0]non-5-ene(3001-72-7)IR1 1,5-Diazabicyclo[4.3.0]non-5-ene(3001-72-7)Raman

3001-72-7(1,5-Diazabicyclo[4.3.0]non-5-ene)Related Search:

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N-Ethyl-1,3-propanediamine N-PROPYL-1,3-PROPANEDIAMINE N,N'-Diethyl-1,3-propanediamine BUTYRAMIDINE 1,3-Diaminopropane

N-PROPYLETHYLIDENEAMINE 1,4,5,6-TETRAHYDROPYRIMIDINE 1,5-Diazabicyclo[4.3.0]non-5-ene

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1,5-DIAZABICYCLO[4.3.0]NON-5-ENE FOR SYN 1,5-Diazabicyclo[4.3.0]non-5-ene purum, >=98.0% (GC) DBN 1,5-Diazabicyclo[4.3.0]non-5-ene 2H,3H,4H,6H,7H,8H-Pyrrolo[1,2-a]pyrimidine 1,5-Diazabicyclo[4.3.0]non-5-ene≥ 99%(GC) Pyrrolo[1,2-a]pyrimidine, 2,3,4,6,7,8-hexahydro- PYRROLIDINO[1,2:A]1,4,5,6-TETRAHYDRO-PYRIMIDINE 1,5-DIAZABICYCLO[4.3.0]NON-5-ENE 1,5-DIAZABICYCLO (4,3,0) NONENE-5 1,5-diazobicyclo[4.3.0]non-5-ene 1,5-Diazabicyclo[4.3.0]non-5-ene 97% 1,5-Diazabicyclo[4.3.0]nonane-5-ene 1,5-Diazabicyclo[4.3.0]non-5-ene,98% 1,5-Diazabicyclo[4.3.0]non-5-ene ,96% L-CYSTEINE HCL MONO/ANHY 1,5-Diazabicyclo4.3.0ünon-5-ene, 97% Diazabicyclononene (DBN) 1,5-DiazabicycL o[4.3.0]non-5-ene 1,5-Diazabicyclo[4.3.0]-5-nonene > 1,5-Diazobicyclo[4.3.0]non-5-en 1,5-Diazabicyclo[4,3,] non-5-ene 2,3,4,6,7,8-Hexahydropyrrolo[1,2-a]pyrimidine（DBN） 1,5-Diazabicyclo[4.3.0]non-5-ene,DBN 2,3,4,6,7,8-Hexahydropyrrolo[1,2-a]pyrimidine DBN 1,5-Diazabicyclonon-5-ene Diazabicyclononene 1,5-DIAZABICYCLO[4.3.0]-5-NONENE 3001-72-7 C7H12N2 Synthetic Reagents Organic Bases