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Benzotrichloride

Benzotrichloride
Benzotrichloride structure
CAS No.
98-07-7
Chemical Name:
Benzotrichloride
Synonyms
ai3-02583;BenzotrichL;alpha.alpha.al;benzotricloruro;Triclorotoluene;benzotrichlorid;PHENYLCHLOROFORM;BENZOTRICHLORIDE;benzenylchloride;BENZYLTRICHLORIDE
CBNumber:
CB6339243
Molecular Formula:
C7H5Cl3
Formula Weight:
195.47
MOL File:
98-07-7.mol

Benzotrichloride Properties

Melting point:
−7.5-−7 °C(lit.)
Boiling point:
219-223 °C760 mm Hg(lit.)
Density 
1.38 g/mL at 25 °C(lit.)
vapor density 
6.77 (vs air)
vapor pressure 
0.2 mm Hg ( 20 °C)
refractive index 
n20/D 1.557(lit.)
Flash point:
207 °F
storage temp. 
room temp
solubility 
alcohol: soluble
form 
Liquid
color 
Clear yellow
Odor
penetrating odor
Water Solubility 
HYDROLYSIS
Sensitive 
Moisture Sensitive
Merck 
14,1109
BRN 
508152
Stability:
Stable, but moisture sensitive. Incompatible with strong oxidizing agents, moisture.
InChIKey
XEMRAKSQROQPBR-UHFFFAOYSA-N
CAS DataBase Reference
98-07-7(CAS DataBase Reference)
EWG's Food Scores
3-5
FDA UNII
U62VHG99AM
NIST Chemistry Reference
Benzene, (trichloromethyl)-(98-07-7)
Proposition 65 List
Benzotrichloride
EPA Substance Registry System
Benzotrichloride (98-07-7)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H314-H330-H302-H315-H318-H331-H335-H350
Precautionary statements  P201-P261-P280-P305+P351+P338-P311-P303+P361+P353-P304+P340-P320-P405-P501a
Hazard Codes  T
Risk Statements  45-22-23-37/38-41
Safety Statements  53-45
RIDADR  UN 2226 8/PG 2
WGK Germany  3
RTECS  XT9275000
Autoignition Temperature 411 °F
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29039990
Toxicity LD50 orally in rats: 6.0 g/kg (Smyth)
NFPA 704
1
4 0

Benzotrichloride price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 36911 α,α,α-Trichlorotoluene analytical standard 98-07-7 250mg-r $70.6 2018-11-13 Buy
Sigma-Aldrich 147893 α,α,α-Trichlorotoluene 98% 98-07-7 500g $103 2019-12-02 Buy
TCI Chemical T0399 Benzotrichloride >99.0%(GC) 98-07-7 25g $16 2020-06-24 Buy
TCI Chemical T0399 Benzotrichloride >99.0%(GC) 98-07-7 500g $36 2020-06-24 Buy
Alfa Aesar A15652 Benzotrichloride, 98% 98-07-7 500g $147 2020-06-24 Buy

Benzotrichloride Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Chemical Properties

Benzotrichloride is a combustible, colorless to yellow-brown, oily liquid that fumes on contact with air. It has a penetrating odor.

Uses

α,α,α-Trichlorotoluene was used in determination of chlorinated toluenes in effluents of wastewater treatment plants and textile industries by closed loop stripping analysis.

Uses

In dye chemistry. In organic syntheses (source of benzenyl group).

General Description

A clear colorless to yellowish colored liquid with a penetrating odor. Denser than water and vapors are heavier than air. May be toxic by inhalation or ingestion. Burns skin, eyes, and mucous membranes. Insoluble in water. Used to make dyes and other chemicals.

Air & Water Reactions

Hydrolyzes in the presence of moisture. The reaction is rather slow due to low solubility in water.

Reactivity Profile

Benzotrichloride hydrolyzes in the presence of moisture. Benzotrichloride reacts with water, lime, ammonia, strong alkalis, organic amines, chlorates and acids.

Hazard

Highly toxic by inhalation, fumes highly irritant. Eye, skin, and upper respiratory tract irri- tant. Probable carcinogen.

Health Hazard

Toxic by inhalation; fumes are highly irritating to skin and mucous membranes. May cause death or permanent injury after very short exposure to small quantities. A suspected carcinogen.

Fire Hazard

Benzotrichloride may react violently with water. Fire may produce irritating or poisonous gases. Flammable/poisonous gases may accumulate in tanks and hopper cars. Materials may ignite combustibles (wood, paper, oil, etc.). Produces toxic and corrosive fumes when Benzotrichloride reacts with water or steam. Similar to hydrochloric acid; material will react with water or steam to produce toxic and corrosive fumes. Hydrolyzes in presence of water forming benzoic and hydrochloric acids.

Potential Exposure

Benzotrichloride is used as a chemical and dye intermediate; extensively used in the dye industry for the production of Malachite green, Rosamine, Quinoline red, and Alizarin yellow A. It can also be used to produce ethyl benzoate. Commercial grades may contain hydrochloric acid, benzylidene chloride, or benzyl chloride.

Carcinogenicity

Benzotrichloride is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Shipping

UN2226 Benzotrichloride, Hazard class: 8; Labels: 8—Corrosive material.

Incompatibilities

Benzotrichloride decomposes on heating, on contact with acids and/or water, producing toxic and corrosive hydrogen chloride and benzoic acid. Reacts violently with strong oxidizers, iron and other metals, alkali and earth alkali metals; bases and organic substances, and may cause fire and explosions. On contact with air it emits toxic and corrosive hydrogen chloride. Attacks many metals in presence of water. Attacks many plastics.

Waste Disposal

Incineration with flammable solvent added in incinerator with afterburner and alkaline scrubber.

Benzotrichloride Preparation Products And Raw materials

Raw materials

Preparation Products


Benzotrichloride Suppliers

Global( 198)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86(0)13336195806 +86-571-85586718
+86-571-85864795 sales@capotchem.com China 19929 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21838 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22625 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 2680 55
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23977 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28231 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 10154 58
QUALITY CONTROL CHEMICALS INC.
(323) 306-3136
(626) 453-0409 orders@qcchemical.com United States 8406 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6371 58
Shandong chuangyingchemical Co., Ltd.
18853181302
sale@chuangyingchem.com CHINA 5917 58

View Lastest Price from Benzotrichloride manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2020-01-08 Benzotrichloride
98-07-7
US $0.10 / KG 1KG 99.0% 1000 tons Shaanxi Dideu Medichem Co. Ltd
2019-12-30 Benzotrichloride
98-07-7
US $1.00 / KG 1KG 95-99% 1ton Career Henan Chemical Co

Benzotrichloride Spectrum


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