ChemicalBook >> CAS DataBase List >>4-Bromomethyl-7-methoxycoumarin
4-Bromomethyl-7-methoxycoumarin
- CAS No.
- 35231-44-8
- Chemical Name:
- 4-Bromomethyl-7-methoxycoumarin
- Synonyms
- BMC;BR-MMC;BMC, Br-Mmc;-7-methoxy-2H-chromen-2-one;4-BROMOETHYL-7-METHOXYCOUMARIN;4-Bromomethyl-7-methoxycoumain;4-bromomethyl-7-hydroxycoumarin;7-Methoxy-4-bromomethylcoumarin;4-BROMOMETHYL-7-METHOXYCOUMARIN;4-BroMoMethyl-7-MethoxycouMarine
- CBNumber:
- CB6345309
- Molecular Formula:
- C11H9BrO3
- Molecular Weight:
- 269.09
- MDL Number:
- MFCD00006869
- MOL File:
- 35231-44-8.mol
Last updated:2023-05-25 18:01:15
Melting point | 213-215 °C (lit.) |
---|---|
Boiling point | 385.3±42.0 °C(Predicted) |
Density | 1.552±0.06 g/cm3(Predicted) |
storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
solubility | chloroform: soluble20mg/mL, clear, colorless to faintly yellow |
form | Powder and/or Chunks |
color | Off-white to light yellow or beige |
Water Solubility | insoluble |
λmax | 330 nm (MeOH) |
BRN | 187211 |
Stability | Stable, but moisture and light-sensitive. Combustible. Incompatible with strong oxidizing agents. |
Major Application | Detection of nitrated explosives; measuring ultraviolet ray power; photoacid generators; polyurethane foams; photoresists silica nanoparticles |
Biological Applications | Analyzing/detecting carboxylic acids;analyzing/labeling fatty acids; detecting nitric oxide; detecting/separating bile acids; labeling pyrimidine nucleobases; anticancer agents; biomedical trace analysis; herbicides; as a substrate for measuring histone acetyltransferases (HATs) activity, peptidases activity, sirtuin activity |
LogP | 2.730 (est) |
CAS DataBase Reference | 35231-44-8(CAS DataBase Reference) |
FDA UNII | 4K32PB5K8Q |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi,Xn | |||||||||
Risk Statements | 36/37/38-22 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
RIDADR | 1759 | |||||||||
WGK Germany | 3 | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29322090 | |||||||||
NFPA 704 |
|
4-Bromomethyl-7-methoxycoumarin price More Price(32)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 235202 | 4-Bromomethyl-7-methoxycoumarin 97% | 35231-44-8 | 1g | $65.4 | 2024-03-01 | Buy |
Sigma-Aldrich | 235202 | 4-Bromomethyl-7-methoxycoumarin 97% | 35231-44-8 | 5g | $248 | 2024-03-01 | Buy |
TCI Chemical | A5551 | Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling] >98.0%(T) | 35231-44-8 | 1g | $91 | 2024-03-01 | Buy |
TCI Chemical | A5551 | Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling] >98.0%(T) | 35231-44-8 | 5g | $272 | 2024-03-01 | Buy |
TRC | B685400 | 4-Bromomethyl-7-methoxycoumarin | 35231-44-8 | 1g | $90 | 2021-12-16 | Buy |
4-Bromomethyl-7-methoxycoumarin Chemical Properties,Uses,Production
Chemical Properties
Light Green-Yellow Crystals
Uses
4-Bromomethyl-7-methoxycoumarin has been used:
- as derivatization reagent in determination of 5-fluorouracil (5-FU) in human plasma by HPLC-tandem mass spectrometry
- as derivatization reagent in fluorescence detection of sodium monofluoroacetate (MFA-Na) in biological samples by HPLC
- in the synthesis of new caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3′,5′-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3′,5′-monophosphate (8-Br-cGMP)
- in TLC and HPLC separation and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2
Uses
4-Bromomethyl-7-methoxycoumarin can be used as fluorescent label for fatty acids. For derivatization, TLC and HPLC separation, and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2.
Purification Methods
The coumarin crystallises from boiling AcOH; the crystals are washed with AcOH, EtOH and dried in a vacuum; 1HNMR (TFA) 3.97s, 4.57s, 6.62s, 6.92-7.19m and 7.80d. [Secrist et al. Biochem Biophys Res Commun 45 1262 1971, Dünges Anal Chem 49 442 1977, Beilstein 18 III/IV 348.]
4-Bromomethyl-7-methoxycoumarin Preparation Products And Raw materials
Global( 164)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanxi Tihondan Pharmaceutical Technology Co., Ltd | +8618235132063 | sales@tihondan.com | China | 3741 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4242 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49392 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 13363 | 58 |
SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 | marketing@targetmol.com | United States | 19892 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34571 | 58 |
View Lastest Price from 4-Bromomethyl-7-methoxycoumarin manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2022-01-15 | 4-Bromomethyl-7-methoxycoumarin
35231-44-8
|
US $0.00 / KG | 1KG | 98.7% | 100 tons | Honest Joy Holdings Limited
|
||
2021-10-30 | 4-Bromomethyl-7-methoxycoumarin
35231-44-8
|
US $1.10 / g | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | ||
2019-07-06 | 4-Bromomethyl-7-methoxycoumarin
35231-44-8
|
US $1.00 / KG | 1KG | 98% | 1kg,5kg,100kg | Career Henan Chemical Co |
- 4-Bromomethyl-7-methoxycoumarin
35231-44-8
- US $0.00 / KG
- 98.7%
- Honest Joy Holdings Limited
- 4-Bromomethyl-7-methoxycoumarin
35231-44-8
- US $1.10 / g
- 99.00%
- Dideu Industries Group Limited
- 4-Bromomethyl-7-methoxycoumarin
35231-44-8
- US $1.00 / KG
- 98%
- Career Henan Chemical Co
35231-44-8(4-Bromomethyl-7-methoxycoumarin)Related Search:
Br-Mmc (=4-Bromomethyl-7-methoxycoumarin) [for HPLC Labeling]
BR-MMC (=4-BROMOETHYL-7-METHOXYCOUMARIN)
4-BROMOMETHYL-7-METHOXYCOUMARIN [FOR HPLC LABELING]
BMC, Br-Mmc
2H-1-Benzopyran-2-one, 4-(bromomethyl)-7-methoxy-
4-(Bromomethyl)-7-methoxychromen-2-one
4-(Bromomethyl)-7-methoxy-2H-1-benzopyran-2-one
7-Methoxy-4-bromomethylcoumarin
4-bromomethyl-7-hydroxycoumarin
4-(Bromomethyl)-7-methoxycoumarin,99%
4-(Bromomethyl)-7-methoxycoumarin,97%
Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)
4-Bromomethyl-7-methoxycoumarin,BMC, Br-Mmc
4-Bromomethyl-7-methoxycoumarin (BrMMC) [for HPLC Labeling]
BROMOMETHYL-7-METHOXYCOUMARIN, 4-(RG)
4-(BroMoMethyl)-7-MethoxycouMarin, 97% 1GR
4-BroMoMethyl-7-MethoxycouMarine
4-BroMoMethyl-7-MethoxycouMarin 97%
4-(BroMoMethyl)-7-Methoxy-2H-chroMen-2-one
BR-MMC
4-BROMOMETHYL-7-METHOXYCOUMARIN
4-BROMOETHYL-7-METHOXYCOUMARIN
4-BROMOMETHYL-7-METHOXYCOUMARIN, FOR FLU ORESCENCE
4-Bromomethyl-7-methoxycoumain
4-BROMOMETHYL-7-METHOXYCOUMARIN (BR-MMC)
Br-Mmc (=4-Bromomethyl-7-methoxycoumarin)[for HPLC Labeling]>
4-Bromomethyl-7-methoxycoumarin ISO 9001:2015 REACH
4-(bromomethyl)-7-methoxy-2H-chromene-2-one
-7-methoxy-2H-chromen-2-one
BMC
Br-Mmc (=4-Bromomethyl-7-methoxycoumarin), for HPLC,≥ 98.0%
35231-44-8
C11H9BrO3
ESTER
HPLC Labeling Reagents
Fluorescence Detection (HPLC Labeling Reagents)
Carboxyl Group Labeling Reagents for Fluorescence HPLC
Detection
Fluorescent Labels
Fluorescent Probes, Labels, Particles and Stains
Other Fluorescent Labels
Biochemicals and Reagents
BioChemical
Carboxyl Group Labeling Reagents for Fluorescence HPLC
Fluorescence Detection (HPLC Labeling Reagents)
HPLC Labeling Reagents
Fluorescent Labels & Indicators
Fluorescent Labels and Indicators
Coumarins
Analytical Chemistry