ChemicalBook
Chinese Japanese Germany Korea

Chlorodiphenylphosphine

Chlorodiphenylphosphine
Chlorodiphenylphosphine structure
CAS No.
1079-66-9
Chemical Name:
Chlorodiphenylphosphine
Synonyms
DPPC;PH2PCL;ClPPh2;PPh2Cl;AURORA KA-1322;95% (C6H5)2PCl;Chlordiphenylphosphin;CHLORODIPHENYLPHOSPINE;DIPHENYLCHLOROPHOSPHINE;CHLORODIPHENYLPHOSPHINE
CBNumber:
CB6365608
Molecular Formula:
C12H10ClP
Formula Weight:
220.63
MOL File:
1079-66-9.mol

Chlorodiphenylphosphine Properties

Melting point:
14-16°C
Boiling point:
320 °C(lit.)
Density 
1.229 g/mL at 25 °C(lit.)
vapor density 
7.8 (vs air)
vapor pressure 
1.3 hPa (20 °C)
refractive index 
n20/D 1.636(lit.)
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
Miscible with alcohol. Slightly miscible with ammonia.
form 
Liquid
color 
Colorless to yellow
Specific Gravity
1.229
Water Solubility 
Reacts violently
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
512032
InChIKey
XGRJZXREYAXTGV-UHFFFAOYSA-N
CAS DataBase Reference
1079-66-9(CAS DataBase Reference)
FDA UNII
WO975PJK1Y
NIST Chemistry Reference
Chlorodiphenylphosphine(1079-66-9)
EPA Substance Registry System
Phosphinous chloride, diphenyl- (1079-66-9)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H318-H314
Precautionary statements  P280-P305+P351+P338-P310-P260-P303+P361+P353-P304+P340+P310-P305+P351+P338+P310-P264-P301+P330+P331+P310-P303+P361+P353+P310+P363-P405-P501-P402
Hazard Codes  C
Risk Statements  14-34-29-36
Safety Statements  26-36/37/39-45-8-30-25-27
RIDADR  UN 3265 8/PG 2
WGK Germany  2
1-9-19
Autoignition Temperature 320 °C
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29310095
Toxicity LD50 orally in Rabbit: 316 mg/kg
NFPA 704
1
3 2
W

Chlorodiphenylphosphine price More Price(49)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich C39601 Chlorodiphenylphosphine 96% 1079-66-9 25g $52.7 2021-12-16 Buy
Sigma-Aldrich 8.10158 Chlorodiphenylphosphine for synthesis 1079-66-9 25 mL $59.85 2021-12-16 Buy
Sigma-Aldrich 766054 P-Chlorodiphenylphosphine 99% 1079-66-9 25g $71.2 2021-12-16 Buy
Sigma-Aldrich 8.10158 Chlorodiphenylphosphine for synthesis 1079-66-9 100 mL $143.37 2021-12-16 Buy
TCI Chemical C0597 Chlorodiphenylphosphine >97.0%(T) 1079-66-9 25g $22 2021-12-16 Buy

Chlorodiphenylphosphine Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Chlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 3526, 1955 DOI: 10.1021/ja01618a030

Purification Methods

This air-sensitive, pale yellow lachrymatory liquid is purified by careful fractional distillation and discarding the lower boiling fraction which contains the main impurity PhPCl2 (b 48-51o/0.7mm), and checking for impurities by NMR. [Weinberg J Org Chem 40 3586 1975, Honer et al. Chem Ber 94 2122 1961, Beilstein 16 IV 969.]

Chlorodiphenylphosphine Preparation Products And Raw materials

Raw materials

Preparation Products


Chlorodiphenylphosphine Suppliers

Global( 365)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 15426 58
Shanghai Bojing Chemical Co.,Ltd.
+86-21-37122233
+86-21-37127788 Candy@bj-chem.com CHINA 497 55
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com China 22607 55
Shanghai Time Chemicals CO., Ltd.
+8618017249410 +86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com China 1807 55
Hangzhou FandaChem Co.,Ltd.
008615858145714
+86-571-56059825 fandachem@gmail.com CHINA 9115 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679
86-0551-65418697 info@tnjchem.com China 3000 55
career henan chemical co
+86-0371-55982848
sales@coreychem.com China 29954 58
Tianjin Huiren Chemtech Co., Ltd
86-13672008665
86-22-23707858 huirentech@foxmail.com CHINA 110 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5941 58

View Lastest Price from Chlorodiphenylphosphine manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2022-01-14 Chlorodiphenylphosphine
1079-66-9
US $10.00 / KG/Tin 1KG 99% 5000tons per month Wuhan Mulei New Material Technology Co. Ltd
2020-03-16 Chlorodiphenylphosphine
1079-66-9
US $1.00-0.00 / KG 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd
2020-02-27 Chlorodiphenylphosphine
1079-66-9
US $0.00 / L 200L 98% 1000MT Hefei TNJ Chemical Industry Co.,Ltd.

Chlorodiphenylphosphine Spectrum


1079-66-9(Chlorodiphenylphosphine)Related Search:


Copyright 2017 © ChemicalBook. All rights reserved