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Bismuth nitrate pentahydrate

Description Uses Chemical Synthesis Preparation Sources
Bismuth nitrate pentahydrate
Bismuth nitrate pentahydrate structure
CAS No.
10035-06-0
Chemical Name:
Bismuth nitrate pentahydrate
Synonyms
BismuthNitrateGr;Bismuth trinitrate;Bismuth(III)-nitrat;Bismuth Nitrate ACS;BISMUTH NITRATE 5H2O;BISMUTH(III) NITRATE;BismuthNitrate5H2OAcs;BISMUTH NITRATE HYDRATE;BISMUTH NITRATE 5HYD XTL;BISMUTH NITRATE extrapure
CBNumber:
CB6438568
Molecular Formula:
BiH10N3O14
Formula Weight:
485.07
MOL File:
10035-06-0.mol

Bismuth nitrate pentahydrate Properties

Melting point:
30 °C(lit.)
Boiling point:
75-80 °C(lit.)
Density 
2,83 g/cm3
solubility 
Soluble in dilute nitric acid solution, dilute acetic acid, glycerol and acetone. Insoluble in alcohol, ethyl acetateSoluble in acetone, acetic acid and glycerol. Insoluble in ethanol and ethyl acetate.
form 
Solid
Specific Gravity
2.83
color 
White
Odor
Slight nitric acid odor
Water Solubility 
MAY DECOMPOSE
Sensitive 
Hygroscopic
Merck 
14,1271
Stability:
Stable. Incompatible with strong acids, strong reducing agents, organic materials, finely powdered metals, moisture. Strong oxidizer.
CAS DataBase Reference
10035-06-0(CAS DataBase Reference)
FDA UNII
FO2ICY167B
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS03,GHS07
Signal word  Danger
Hazard statements  H303-H272-H315-H319-H335
Precautionary statements  P210a-P405-P501a-P210-P220-P221-P305+P351+P338-P370+P378
Hazard Codes  O,Xi
Risk Statements  8-36/37/38
Safety Statements  17-26-36-37/39
RIDADR  UN 1477 5.1/PG 2
WGK Germany  2
RTECS  EB2984430
8
TSCA  Yes
HazardClass  5.1
PackingGroup  II
HS Code  28342990
Toxicity LD50 orally in Rabbit: 4042 mg/kg
NFPA 704
0
2 2
OX

Bismuth nitrate pentahydrate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 248592 Bismuth(III) nitrate pentahydrate reagent grade, 98% 10035-06-0 100g $30.4 2021-03-22 Buy
Sigma-Aldrich 248592 Bismuth(III) nitrate pentahydrate reagent grade, 98% 10035-06-0 500g $91.7 2021-03-22 Buy
Sigma-Aldrich 1.01878 Bismuth(III) nitrate alkaline for analysis EMSURE? Reag. Ph Eur 10035-06-0 100 g $157.25 2021-03-22 Buy
Alfa Aesar 012231 Bismuth(III) nitrate pentahydrate, ACS, 98% 10035-06-0 1kg $149 2021-03-22 Buy
Alfa Aesar 012231 Bismuth(III) nitrate pentahydrate, ACS, 98% 10035-06-0 250g $50.1 2021-03-22 Buy

Bismuth nitrate pentahydrate Chemical Properties,Uses,Production

Description

Bismuth nitrate is the bismuth salt form of nitrate, usually existing in pentahydrate form. People apply bismuth salt to the skin for hemorrhoids. People use bismuth as an enema for pouchitis. This condition involves inflammation in an artificial rectum created after surgery for ulcerative colitis. Bismuth salts are also added to cosmetics, batteries, paints, and pigment plastics in manufacturing. Bismuth nitrate is used to catalyze various kinds of reactions including chemo-selective synthesis of acylals from aromatic aldehydes, one-pot synthesis of alpha-amino phosphates as well as pharmaceutically functionalized piperidine derivatives, protection of carbonyl compounds and various kinds of Michel reactions. It is also an excellent oxidant for a variety of 4-substituted Hantzsch 1, 4-dihydropyridines.It is a convenient reagent for selective oxidation of sufides to sulfoxides.

Uses

Bismuth(III) nitrate pentahydrate is a non-toxic, inexpensive, easy to handle and air insensitive reagent, commonly used in organic synthesis with a wide range of applications.
Bismuth(III) nitrate pentahydrate
Bismuth(III) nitrate pentahydrate is a convenient and selective reagent for conversion of thiocarbonyls to their carbonyl compounds.
Bismuth(III) nitrate pentahydrate and air as a cocatalyst is claimed to be a superior reagent for the oxidative deprotection of dithioacetals.

Chemical Synthesis

Bismuth(III) nitrate pentahydrate may be used in the following processes:
  1. Conversion of thioamides and thioureas to their oxo derivatives.
  2. Transformation of aromatic aldehydes to carboxylic acids under microwave and solvent free conditions.
  3. Synthesize coumarins by Pechmann condensation under solvent free conditions.
  4. As a precursor in the synthesis of pure and lanthanum-modified bismuth ferrite (BFO) ceramics.
  5. As a nitrating agent in the synthesis of methyl nitramino-2,4,6-trinitrobenzenes under microwave irradiation.
  6. As a catalyst in the preparation of 4-amino-5-pyrimidine carbonitrile and pyrimidinone derivatives.
  7. Synthesis of glycosides by Fischer glycosylation of unprotected sugars.
  8. Synthesis of bismuth oxide (Bi2O3) nanoparticles.
  9. Oxidation of 4-substituted Hantzsch 1,4-dihydropyridines.
  10. Selective oxidation of sufides to sulfoxides.

Preparation

Bismuth nitrate pentahydrate can be obtained by dissolving metallic bismuth granules in nitric acid, or by pouring molten metallic bismuth into an acid solution while stirring.

Sources

https://en.wikipedia.org/wiki/Bismuth(III)_nitrate
Bhattacharya, Asish K., and T. Kaur.  Cheminform 38.30(2007):0745-0748.
Aggen, David H., et al. Tetrahedron 35.31(2004):3675-3679.
Brahmachari, Goutam, and S. Das. Cheminform 43.28(2012):1479-1484.
Srivastava, Neeta, S. K. Dasgupta, and B. K. Banik. Tetrahedron Letters 34.17(2003):1191-1193.
Banik, Bimal K., I. Garcia, and F. R. Morales. Cheminform 38.33(2007):no-no.
Srivastava, N, and B. K. Banik. Cheminform 68.6(2003):2109-14.
https://www.sigmaaldrich.com/catalog/product/aldrich/254150?lang=en&region=US
https://www.webmd.com/vitamins/ai/ingredientmono-1502/bismuth

Chemical Properties

White Crystal

Physical properties

Lustrous triclinic crystals; acid taste; hygroscopic; density 2.83 g/cm3; decomposes at 75°C; reacts slowly with water; soluble in acids and acetone; insoluble in alcohol.

Uses

An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines.1 Convenient reagent for selective oxidation of sufides to sulfoxides.2

Uses

Bismuth Nitrate Pentahydrate acts as a precursor in the prepoaration of photocatalysts.

Preparation

Bismuth nitrate is prepared by dissolving bismuth in concentrated nitric acid, followed by evaporation and crystallization .

Bismuth nitrate pentahydrate Preparation Products And Raw materials

Raw materials

Preparation Products


Bismuth nitrate pentahydrate Suppliers

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Henan DaKen Chemical CO.,LTD.
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View Lastest Price from Bismuth nitrate pentahydrate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-08-26 Bismuth nitrate pentahydrate
10035-06-0
US $9.60 / KG 1KG 98% 5000kg Hebei Crovell Biotech Co Ltd
2019-12-31 Bismuth nitrate pentahydrate
10035-06-0
US $7.00 / KG 1KG 99% 100KG Career Henan Chemical Co

Bismuth nitrate pentahydrate Spectrum


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