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N-METHYLBUTYLAMINE

N-METHYLBUTYLAMINE
N-METHYLBUTYLAMINE structure
CAS No.
110-68-9
Chemical Name:
N-METHYLBUTYLAMINE
Synonyms
Butylmethylamine;Methylbutylamine;Methylaminobutane;N-Butylmethylamin;N-Methylbutylamin;N-Methylbutanamine;n-methyl-butylamin;N-BUTYLMETHYLAMINE;N-METHYLBUTYLAMINE;Methyl-N-butylamine
CBNumber:
CB6492418
Molecular Formula:
C5H13N
Formula Weight:
87.16
MOL File:
110-68-9.mol

N-METHYLBUTYLAMINE Properties

Melting point:
-75 °C
Boiling point:
90.5-91.5 °C(lit.)
Density 
0.736 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.3995(lit.)
Flash point:
35 °F
storage temp. 
Flammables area
pka
pK1: 10.90(+1) (25°C)
explosive limit
1.3%(V)
BRN 
1209231
CAS DataBase Reference
110-68-9(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  F,C
Risk Statements  11-20/21/22-34
Safety Statements  16-26-36/37/39-45
RIDADR  UN 2945 3/PG 2
WGK Germany  3
RTECS  EO5250000
HazardClass  3
PackingGroup  II
HS Code  29211999
Toxicity LD50 orally in Rabbit: 420 mg/kg LD50 dermal Rabbit 932 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
3
3 0
Health   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
Flammability   3 Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

N-METHYLBUTYLAMINE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.18639 N-Methylbutylamine for synthesis. CAS 110-68-9, EC Number 203-791-2, chemical formula CH (CH ) NHCH ., for synthesis 110-68-9 8186390100 $30.8 2018-11-23 Buy
Sigma-Aldrich 8.18639 N-Methylbutylamine for synthesis. CAS 110-68-9, EC Number 203-791-2, chemical formula CH (CH ) NHCH ., for synthesis 110-68-9 8186390500 $96 2018-11-23 Buy
TCI Chemical M0179 N-Methylbutylamine >93.0%(GC) 110-68-9 25mL $13 2018-11-22 Buy

N-METHYLBUTYLAMINE Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Chemical Properties

Butyl amines are highly flammable, colorless liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer:

Uses

Intermediate.

Definition

ChEBI: A secondary aliphatic amine having methyl and n-butyl as the two alkyl groups.

General Description

A water-white liquid with an ammonia-like odor. Density 0.736 g / cm3 and flash point 35°F (Aldrich) .Vapors heavier than air. Used to make other chemicals.

Air & Water Reactions

Highly flammable. Slightly soluble in water.

Reactivity Profile

N-METHYLBUTYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Hazard

Flammable, dangerous fire risk.

Health Hazard

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Mildly toxic by inhalation. A skin and severe eye irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.

Potential Exposure

Alert: (n-isomer): Possible risk of forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (sec-isomer): Drug. n-Butylamine is used in pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate (a lube oil additive); as an intermediate in the production of rubber and in rust preventatives and emulsion deterrents in petroleum products. It is used in the manufacture of several drugs

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Rinse out mouth and do not induce vomiting. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy

Shipping

UN1125 n-Butylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material. UN2014 Isobutylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material

Incompatibilities

May form explosive mixture with air. May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts with strong oxidizers and acids, causing fire and explosion hazard. Incompatible with organic anhydrides; isocyanates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in presence of moisture. The tert-isomer will attack some forms of plastics

Waste Disposal

Use a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed.

N-METHYLBUTYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products


N-METHYLBUTYLAMINE Suppliers

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N-METHYLBUTYLAMINE Spectrum


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