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Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate

CAS No.
194999-85-4
Chemical Name:
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate
Synonyms
BBI 109;DTBPIO-nF;DTBPI-PFBS;photoacid generator I;Bis(4-t-butylphenyl)iodonium nonaflate;BIS(4-T-BUTYLPHENYL)IODONIUM PERFLUORO-1;BIS(4-TERT-BUTYLPHENL)IODONIUM PERFLUOR&;Bis(4-tert-butylphenyl)iodonium nonaflate;Di(4-tert-butylphenyl)iodonium perfluorobutanesulfonate;Bis(4-tert-butylphenyl)iodonium perfluorobutanesulfonate
CBNumber:
CB6500274
Molecular Formula:
C20H26I.C4F9O3S
Molecular Weight:
692.414
MDL Number:
MFCD02683473
MOL File:
194999-85-4.mol
MSDS File:
SDS
Last updated:2023-12-04 11:13:42

Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Properties

Melting point 175-177 °C (lit.)
solubility PGMEA: ~40%
InChIKey DJBAOXYQCAKLPH-UHFFFAOYSA-M
SMILES C(C(F)(F)C(F)(F)F)(F)(F)C(F)(F)S([O-])(=O)=O.C1(C(C)(C)C)=CC=C([I+]C2=CC=C(C(C)(C)C)C=C2)C=C1
EPA Substance Registry System Bis(4-tert-butylphenyl)iodanium nonafluorobutane-1-sulfonate (194999-85-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3

Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 531014 Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate electronic grade, ≥99% 194999-85-4 1g $124 2024-03-01 Buy
American Custom Chemicals Corporation HCH0318478 BIS(4-TERT-BUTYLPHENYL)IODONIUM PERFLUORO-1-BUTANESULFONATE 95.00% 194999-85-4 5MG $500.67 2021-12-16 Buy
Product number Packaging Price Buy
531014 1g $124 Buy
HCH0318478 5MG $500.67 Buy

Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Chemical Properties,Uses,Production

Uses

Cationic photoinitiator. Photoacid generator.

Research

To test the reactivity of gaseous 18F-AcF in radiofluorination, bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate was radiofluorinated with anhydrous 18F-CsF (generated from 18F-AcF and 20 mg Cs2CO3) in 0.3 mL anisole. The results supported the high reactivity for 18F-fluoride derived from 18F-AcF [1].    Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate is a photoinitiator (PI). The photoinitiator (PI) mechanisms are radical and cationic. In the cationic PI system, light is absorbed, causing heterolytic and homolytic cleavage that forms a cationic portion (labeled in green) and anionic portion (labeled in pink). The generated molecules are reactive with monomers, forming an acid and free radicals, propagating polymerization[2].    
Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate

References

[1] Huailei Jiang , Timothy R. DeGrado, Stephen G. DiMagno . “Production and transport of gaseous 18F-synthons: 18F-acyl fluorides.” Journal of Fluorine Chemistry 180 (2015): Pages 181-185.
[2] Megan Carve, &Donald Wlodkowic. “3D-Printed Chips: Compatibility of Additive Manufacturing Photopolymeric Substrata with Biological Applications.” Micromachines 9 2 (2018).

Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 59)Suppliers
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View Lastest Price from Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(4-tert-butylphenyl) Iodonium Perfluoro-1-Butane sulfonate; Bis(4-tert-butylphenyl) Iodoniumnonaflate pictures 2023-03-15 Bis(4-tert-butylphenyl) Iodonium Perfluoro-1-Butane sulfonate; Bis(4-tert-butylphenyl) Iodoniumnonaflate
194999-85-4
US $0.00-0.00 / kg 1kg 99.50% 20 TON Shanghai Z&T Chemical Co., Ltd
BIS(4-TERT-BUTYLPHENL)IODONIUM PERFLUOR& BBI 109 Bis(4-t-butylphenyl)iodonium nonaflate Bis(4-tert-butylphenyl)iodonium nonaflate Bis(4-tert-butylphenyl)iodonium nonafluorobutanesulfonate Bis(4-tert-butylphenyl)iodonium perfluorobutanesulfonate Di(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate Di(4-tert-butylphenyl)iodonium perfluorobutanesulfonate DTBPI-PFBS BIS(4-T-BUTYLPHENYL)IODONIUM PERFLUORO-1 Bis[4-(1,1-dimethylethyl)phenyl]iodonium salt with 1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonic acid (1:1) Bis(4-tertbutylphenyl) iodanium,1,1,2,2,3,3,4, 4,4-nonafluorobutane-1-sulfonate Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate electronic grade, >=99% DTBPIO-nF Bis(4-tert-butylphenyl)iodonium perfluoro-1-butanesulfonate electronic grade photoacid generator I 2H-Isoindole-2-acetamide,α-(5-fluoro-2-hydroxyphenyl)-1,3-dihydro-1-oxo-N-6-thiazolyl- Iodonium, bis[4-(1,1-dimethyl- ethyl)phenyl]-,1,1,2,2,3,3,4,4,4-nonafluoro-1-butanesulfonate BIS(4-TERT-BUTYLPHENYL)IODONIUM PERFLUORO-1-BUTANESULFONATE Bis(4-tert-butylphenyl)iodonium Nonafluoro-1-butanesulfonate 194999-85-4 CH33CC6H42IC4F9SO3 C20H26IC4F9O3S Cationic PhotoinitiatorsSelf Assembly&Contact Printing Organic Photoinitiators Photoacid Generators (PAGs) Photoresists Polymerization Initiators