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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Uses
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate structure
CAS No.
35138-22-8
Chemical Name:
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms
Bis(cycloocta-1,5-dien)rho;(1Z,5Z)-cycloocta-1,5-diene,rhodium;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate;(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
CBNumber:
CB6666011
Molecular Formula:
C16H24BF4Rh
Formula Weight:
406.07
MOL File:
35138-22-8.mol

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Properties

Melting point:
210 °C
Density 
0.42 g/cm3 (20℃)
storage temp. 
Refrigerator (+4°C)
form 
Powder
color 
Red
PH
7 (5g/l, H2O, 20℃)
Water Solubility 
insoluble
Sensitive 
Slightly air & moisture sensitive
CAS DataBase Reference
35138-22-8(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F,Xi
Risk Statements  11-34
Safety Statements  16-45-36/37/39-26
RIDADR  UN 2921
WGK Germany  2
Hazard Note  Irritant
HazardClass  8
PackingGroup  III
HS Code  28439000
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
P210, P240,P241, P280, P370+P378
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P501 Dispose of contents/container to..…

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 14694 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 100mg $117 2018-11-13 Buy
TCI Chemical B3961 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 35138-22-8 1g $216 2018-11-22 Buy
TCI Chemical B3961 Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate 35138-22-8 100mg $36 2018-11-22 Buy
Alfa Aesar 044031 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 1g $332 2018-11-16 Buy
Alfa Aesar 044031 Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8 5g $1494 2018-11-16 Buy

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties,Uses,Production

Uses

  1. Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
  2. Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions. 

Chemical Properties

dark red

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products


Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Suppliers

Global( 135)Suppliers
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Henan DaKen Chemical CO.,LTD.
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+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40277 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30168 84

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Spectrum


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