ChemicalBook >> CAS DataBase List >>TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- CAS No.
- 13170-43-9
- Chemical Name:
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- Synonyms
- TRIMETHYLSILYLMETHYL;siL;(Trimethylsilyl)methylmagnesium;(20% in Ethyl Ether, ca. 1Mol/L);Trimethylsilylmethylchloromagnesium;Trimethylsiylmethylmagnesium chloride;(Trimethylsilylmethyl)chloromagnesium;TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;TriMethylsilylMethylMagnesiuM Chloride
- CBNumber:
- CB6732457
- Molecular Formula:
- C4H11ClMgSi
- Molecular Weight:
- 146.97
- MDL Number:
- MFCD00009916
- MOL File:
- 13170-43-9.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 105.8-106.4 °C |
|---|---|
| Density | 1.04 |
| Flash point | -40°C |
| storage temp. | Flammables + water-Freezer (-20°C)e area |
| solubility | Sol ethereal solvents; reacts with protic solvents. |
| form | Low Melting Solid |
| Specific Gravity | 0.912 |
| color | Clear colorless to yellow to greenish |
| Sensitive | Air & Moisture Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 3587255 |
| CAS DataBase Reference | 13170-43-9(CAS DataBase Reference) |
| NCI Dictionary of Cancer Terms | SIL |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H302-H314-H336-H313-H318 | |||||||||
| Precautionary statements | P260h-P303+P361+P353-P405-P501a-P210-P261-P280-P305+P351+P338-P310 | |||||||||
| Hazard Codes | F+,C,F | |||||||||
| Risk Statements | 12-14-22-34-66-67-19-11 | |||||||||
| Safety Statements | 16-26-36/37/39-43-45 | |||||||||
| RIDADR | UN 3399 4.3/PG 1 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 10 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 256021 | (Trimethylsilyl)methylmagnesium chloride solution 1.0 M in diethyl ether | 13170-43-9 | 100ml | $182 | 2024-03-01 | Buy |
| TCI Chemical | T1451 | Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L) | 13170-43-9 | 100mL | $108 | 2024-03-01 | Buy |
| TCI Chemical | T2609 | Trimethylsilylmethylmagnesium Chloride (ca. 18% in Tetrahydrofuran, ca. 1mol/L) | 13170-43-9 | 100mL | $119 | 2024-03-01 | Buy |
| Alfa Aesar | H54635 | (Trimethylsilyl)methylmagnesium chloride 0.5M in 2-MeTHF | 13170-43-9 | 100ml | $137.65 | 2024-03-01 | Buy |
| TRC | T895985 | (Trimethylsilyl)methylmagnesiumChloride,1.3MsolutioninTHF,J&KSeal | 13170-43-9 | 1mL | $45 | 2021-12-16 | Buy |
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties,Uses,Production
Chemical Properties
Grey liquid
Uses
Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.
Uses
Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.
Preparation
From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 178)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Win-Win Chemical CO., Limited | 0086-577-64498589 | sales@win-winchemical.com | CHINA | 998 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Standardpharm Co. Ltd. | 86-714-3992388 | overseasales1@yongstandards.com | United States | 14336 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
View Lastest Price from TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-09-06 | trimethylsilylmethylmagnesium chloride
13170-43-9
|
US $0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | |
 |
2021-07-02 | (Trimethylsilyl)methylmagnesium chloride solution
13170-43-9
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | |
 |
2019-07-06 | TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
13170-43-9
|
US $1.00 / KG | 1KG | 98% | 1kg,5kg,100kg | Career Henan Chemical Co |
-
- trimethylsilylmethylmagnesium chloride
13170-43-9
- US $0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
-
- (Trimethylsilyl)methylmagnesium chloride solution
13170-43-9
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
13170-43-9
- US $1.00 / KG
- 98%
- Career Henan Chemical Co
13170-43-9(TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE)Related Search:
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TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
(trimethylsilyl)methylmagnesium chl. sol
Trimethylsilylmethylmagnesium chloride (20% in ethyl ether
(TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER
(TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER
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(Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF
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Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca. 1mol/L)
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(trimethylsilyl) methyl magnesium chloride 1.3M tetrahydrofuran
(Trimethylsilyl)methylmagnesium chloride, 0.50 M in 2-MeTHF
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(Trimethylsilyl)methylmagnesium chloride, 1,3m solution in THF
(Trimethylsilyl)methylmagnesium chloride1.3M solution in THFAcroSeal§3
(Trimethylsilylmethyl)chloromagnesium
Trimethylsilylmethylchloromagnesium
(Trimethylsilyl)methylmagnesium chloride solution 1.0 in diethyl ether
(Trimethylsilyl)methylmagnesium chloride, 1.3M solution in THF, AcroSeal
TriMethylsilylMethylMagnesiuM Chloride (ca. 18% in Tetrahydrofuran, ca. 1Mol/L)
(TriMethylsilyl)MethylMagnesiuM chloride, 1.3M solution in THF, AcroSeal 100ML
(TriMethylsilyl)MethylMagnesiuM chloride, 0.5M in 2-MeTHF
(20% in Ethyl Ether, ca. 1Mol/L)
TriMethylsilylMethylMagnesiuM Chloride
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in Methyltetrahydrofuran
(TriMethylsilyl)MethylMagnesiuM chloride, 1.0M solution in diethyl ether, J&KSeal
(TriMethylsilyl)MethylMagnesiuM chloride solution 1.0 M in diethyl ether
(TriMethylsilyl)MethylMagnesiuM chloride, 1.0 M solution in diethyl ether, SpcSeal
(TriMethylsilyl)MethylMagnesiuM chloride, 1.3 M solution in THF, J&KSeal
(Trimethylsilyl)methylmagnesium chloride 1.3MTHF
siL
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 3M in methyltetrahydrofuran (46-48 wt %)
TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE, 1.0M in diethyl ether (19 wt %)
(Trimethylsilyl)methylmagnesium Chloride, Tetrahydrofuran
Solution (abt. 1mol/l) [TMSCH2MgCl(THF)]
TIANFU CHEM-- TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
TRIMETHYLSILYLMETHYL
Magnesium, chloro[(trimethylsilyl)methyl]- (7CI, 8CI, 9CI)
Trimethyl silyl methyl magnesium chloride 1. M in THF
(Trimethylsilyl)methylmagnesium
13170-43-9
CH33SiCH2MgCl
C4H11ClMgSi
Alkyl
Organometallic Reagents
Si-(C)4 Compounds
Grignard Reagents & Alkyl Metals
Grignard Reagents
Classes of Metal Compounds
Si (Classes of Silicon Compounds)
Silicon Compounds (for Synthesis)
Typical Metal Compounds
Mg (Magnesium) Compounds
Si (Classes of Silicon Compounds)
Si-(C)4 Compounds
Silicon Compounds (for Synthesis)
Synthetic Organic Chemistry