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Anisic acid

Uses Description Application Description References
Anisic acid
Anisic acid structure
CAS No.
100-09-4
Chemical Name:
Anisic acid
Synonyms
Anisic;p Acid;FEMA 3945;p-Anissure;Anisic aci;ANISIC ACID;draconicacid;'LGC' (2407);Draconic acid;p-Anisc Acid
CBNumber:
CB6746524
Molecular Formula:
C8H8O3
Formula Weight:
152.15
MOL File:
100-09-4.mol

Anisic acid Properties

Melting point:
182-185 °C(lit.)
Boiling point:
275 °C
Density 
1.385
refractive index 
1.571-1.576
FEMA 
3945 | 4-METHOXYBENZOIC ACID
Flash point:
185 °C
storage temp. 
Store below +30°C.
solubility 
H2O: soluble2500 parts
form 
Powder
pka
4.50(at 25℃)
color 
White to slightly gray-beige
PH
3-4 (0.3g/l, H2O, 20℃)
Water Solubility 
Soluble in water at 20°C 0.3g/L. Soluble in alcohol, ethyl acetate and ether.
Merck 
14,666
JECFA Number
883
BRN 
508910
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
ZEYHEAKUIGZSGI-UHFFFAOYSA-N
CAS DataBase Reference
100-09-4(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS)
4-METHOXYBENZOIC ACID
EWG's Food Scores
1
FDA UNII
4SB6Y7DMM3
NIST Chemistry Reference
Benzoic acid, 4-methoxy-(100-09-4)
EPA Substance Registry System
Benzoic acid, 4-methoxy- (100-09-4)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P305+P351+P338-P301+P312+P330
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-22
Safety Statements  26-36-24/25
WGK Germany  1
RTECS  BZ4395000
Autoignition Temperature 185 °C
Hazard Note  Irritant
TSCA  Yes
HS Code  29189090
Toxicity LD50 orally in Rabbit: > 5000 mg/kg

Anisic acid price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 117390 4-Methoxybenzoic acid ReagentPlus , 99% 100-09-4 5g $14.7 2021-03-22 Buy
Sigma-Aldrich 117390 4-Methoxybenzoic acid ReagentPlus , 99% 100-09-4 100g $40.5 2021-03-22 Buy
Sigma-Aldrich W394512 p-Anisic acid natural, 99%, FG 100-09-4 100 g $75 2021-03-22 Buy
Sigma-Aldrich 8.05971 4-Methoxybenzoic acid for synthesis 100-09-4 250 g $92.13 2021-03-22 Buy
Sigma-Aldrich 8.05971 4-Methoxybenzoic acid for synthesis 100-09-4 1 kg $208.12 2021-03-22 Buy

Anisic acid Chemical Properties,Uses,Production

Uses

4-Methoxybenzoic acid was used in oxidation and reduction of cytochrome c in solution through different self-assembled monolayers on gold electrodes using cyclic voltammetry. It is also the sole source of carbon and energy for growth in the cultures of Nocardia sp. DSM 1069.

Description

Anisic acid or methoxybenzoic acid is an organic compound which is a carboxylic acid. P-Anisic acid, known also as 4-methoxybenzoic acid or Draconic acid, which is a methoxybenzoic acid substituted with a methoxy group at position C-4, and P-Anisic acid is an organic acid with sweet flavor. It is one of the isomers (m-anisic acid, and o-anisic acid) of anisic acid. The term anisic acid is often used to describe p-anisic acid and P-anisic acid is produced through the oxidation of p-cresyl-methyl ether. P-Anisic acid is a carboxylic acid found naturally in anise, a flowering plant in the family Apiaceae. P-Anisic acid exists as a white crystalline solid which is insoluble in water, highly soluble in alcohols, and soluble in ether and ethyl acetate.

Application

P-Anisic acid is used mostly as photographic chemicals and dye intermediate. It is also used as fragrance and flavoring agent for pharmaceuticals, drug, antimicrobial (against bacterias, mold and yeast), repellent, ovicide, antirheumatic agent, synthetic flavoring agent in foods, lab reagent, fragrance ingredient, and odor masking agent for products, furthermore, it is also used for the preparation of p-aniosylchloride.
P-Anisic acid has antiseptic properties and is typically used as a preservative in cosmetics and skin care products. Because P-Anisic acid is derived from anise, a flowering plant native, it is safe ingredients in cosmetics to replace potentially toxic preservatives like parabens in some natural or organic skin care products.

Description

P-anisic acid, known also as 4-methoxybenzoic acid or draconic acid, is an organic acid with sweet flavor. It is one of the isomers (m-anisic acid, and o-anisic acid) of anisic acid. The term anisic acid is often used to describe p-anisic acid. P-anisic acid is produced through the oxidation of p-cresyl-methyl ether.
P-anisic acid is used mostly as photographic chemicals and dye intermediate. It is also used as fragrance and flavoring agent for pharmaceuticals, drug, antimicrobial (against bacterias, mold and yeast), repellent, ovicide, antirheumatic agent, synthetic flavoring agent in foods, lab reagent, fragrance ingredient, and odor masking agent for products. It is also used for the preparation of p-aniosylchloride. Furthermore, it is marketed as preservative-free for surfactant based formulations, such as shampoos, shower gels, and bubble baths.

References

[1] Michael Ash (2004) Handbook of Preservatives
[2] Asim Kumar Mukhopadhyay (2004) Industrial Chemical Cresols and Downstream Derivatives
[3] https://en.wikipedia.org/wiki/P-Anisic_acid

Chemical Properties

white powder

Chemical Properties

4-Methoxybenzoic acid is practically odorless.

Uses

Intermediates of Liquid Crystals

Definition

ChEBI: A methoxybenzoic acid substituted with a methoxy group at position C-4.

Synthesis Reference(s)

Journal of Heterocyclic Chemistry, 25, p. 973, 1988 DOI: 10.1002/jhet.5570250351
Tetrahedron Letters, 34, p. 4603, 1993 DOI: 10.1016/S0040-4039(00)60635-4

Safety Profile

Poison by subcutaneous route.When heated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

Crystallise p-anisic acid from EtOH, water, EtOH/water or toluene. The S-benzylisothiuronium salt has m 189o (from EtOH). [Beilstein 10 II 91, 10 III 280, 10 IV 346.]

Anisic acid Preparation Products And Raw materials

Raw materials

Preparation Products


Anisic acid Suppliers

Global( 532)Suppliers
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HANGZHOU CLAP TECHNOLOGY CO.,LTD
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Related articles


View Lastest Price from Anisic acid manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-11-30 Anisic acid
100-09-4
US $100.00 / KG 1KG 99.9% 1000kg/month Shanxi Lianxu New Material Co., LTD
2021-11-30 Anisic acid
100-09-4
US $45.00 / KG 1KG 99% 1 ton Baoji Guokang Bio-Technology Co., Ltd.
2021-11-30 4-Methoxybenzoic acid
100-09-4
US $20.00 / ASSAYS 1KG 99% 10tons Xingtai Haoxun Import and Export Trade Co., Ltd.

Anisic acid Spectrum


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