N-Ethylaniline | 103-69-5

N-Ethylaniline Properties

Melting point	-63 °C
Boiling point	205 °C(lit.)
Density	0.963 g/mL at 25 °C(lit.)
vapor density	4.2 (vs air)
vapor pressure	0.2 mm Hg ( 25 °C)
refractive index	n20/D 1.554(lit.)
Flash point	185 °F
storage temp.	Store below +30°C.
solubility	2.7g/l
form	Liquid
pka	5.12(at 24℃)
color	Clear light yellow to light brown
PH	11 (2.7g/l, H2O, 20℃)
explosive limit	1.8-10.0%(V)
Water Solubility	50 g/L (20 ºC)
Sensitive	Air & Light Sensitive
Merck	14,3764
BRN	507468
Stability	Stable, but decomposes upon prolonged exposure to air or light. Combustible. Incompatible with strong oxidizing agents. May react violently with nitric acid.
CAS DataBase Reference	103-69-5(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	7E45L4I2PS
NIST Chemistry Reference	Benzenamine, N-ethyl-(103-69-5)
EPA Substance Registry System	N-Ethylaniline (103-69-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS06,GHS08

Signal word

Danger

Hazard statements

H301+H311+H331-H373

Precautionary statements

P260-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314

Hazard Codes

T

Risk Statements

23/24/25-33

Safety Statements

28-37-45-28A

RIDADR

UN 2272 6.1/PG 3

WGK Germany

1

RTECS

BX9780000

F

8

Hazard Note

Toxic

TSCA

Yes

HazardClass

6.1

PackingGroup

III

HS Code

29214200

Toxicity

LD50 in rats (g/kg): 0.18 i.p., 0.28 orally, 4.7 s.c. (Sziza, Podhragyai)

NFPA 704

	2
3		0

N-Ethylaniline price More Price(16)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	426385	N-Ethylaniline 98%	103-69-5	100ml	$35.7	2022-05-15	Buy
TCI Chemical	E0059	N-Ethylaniline >99.0%(GC)(T)	103-69-5	25mL	$20	2022-04-27	Buy
TCI Chemical	E0059	N-Ethylaniline >99.0%(GC)(T)	103-69-5	500mL	$36	2022-04-27	Buy
Alfa Aesar	A15060	N-Ethylaniline, 97%	103-69-5	500ml	$27.7	2021-12-16	Buy
Alfa Aesar	A15060	N-Ethylaniline, 97%	103-69-5	2500ml	$91.4	2021-12-16	Buy

Product number	Packaging	Price	Buy
426385	100ml	$35.7	Buy
E0059	25mL	$20	Buy
E0059	500mL	$36	Buy
A15060	500ml	$27.7	Buy
A15060	2500ml	$91.4	Buy

N-Ethylaniline Chemical Properties,Uses,Production

Chemical Properties

yellow liquid

Chemical Properties

N-Ethylaniline is yellow-brown oil with a weak fishy odor.

Occurrence

Polyethylene bottles used in intravenous solutions have been reported to be contaminated with N-ethylaniline from rubber parts of the closure (Ulsaker and Teien 1979). It has been reported that rubber containing N,N^,-dithiodimorpholine accelerator of vulcanization can release N-ethylaniline into an aqueous media (Stankevich and Shurupova 1976). This compound has also been reported as a contaminant of cigarette smoke at a level of 55.8 ng per one U.S. 85 mm cigarette (Patrianakos and Hoffmann 1979).

Uses

N-Ethylaniline is used as an explosive stabilizer and in dyestuff manufacture.

Uses

N-Ethylaniline (NEA) may be used as an internal standard in the GC analysis of nicotine extraction from nicotine gum. It may be used in the synthesis of the following, 2-(N-ethylphenylamino)-1,4-benzoquinone, 2-(arylaminomethyl)phenylboronic acid, poly(methyl methacrylate) (PMMA) films containing NEA and poly(N-ethylaniline) (PNEA).

Uses

Organic synthesis.

Production Methods

Manufacture of N-ethylaniline is based on the reaction of aniline with alkyl halide or by heating aniline with ethyl alcohol under acidic conditions followed by purification (Windholz et al 1983).

Synthesis Reference(s)

Journal of the American Chemical Society, 78, p. 4778, 1956 DOI: 10.1021/ja01599a063
The Journal of Organic Chemistry, 21, p. 988, 1956
Tetrahedron Letters, 25, p. 1635, 1984 DOI: 10.1016/S0040-4039(01)81131-X

General Description

A dark liquid with an aromatic odor. Insoluble in water. Density 0.963 g / cm3. Toxic by skin absorption and inhalation of vapors. Evolves toxic fumes during combustion. Flash point 185°F.

Air & Water Reactions

Unstable to prolonged exposure to air and/or light. Insoluble in water.

Reactivity Profile

N-Ethylaniline may react violently with nitric acid. May react with strong oxidizing agents. . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Hazard

Toxic by ingestion, inhalation, and skin absorption.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Health Hazard

N-Ethylaniline is considered very hazardous in a fire situation, since it is highly toxic and readily absorbed by the inhalation, dermal and oral routes (HSDB 1988). Excessive exposure causes respiratory paralysis.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Industrial uses

N-Ethylaniline is used as an explosives stabilizer and as an intermediate in the manufacturing of dyes and pharmaceuticals (Northcott 1978).

Safety Profile

Poison by ingestion and intraperitoneal routes. Moderately toxic by an unspecified route. Mddly toxic by skin contact. An allergen. Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fire, use dry chemical, CO2, foam. Hypergolic reaction with red fuming nitric acid. When heated to decomposition or on contact with acid or acid fumes it emits highly toxic fumes of aniline and NOx.

Potential Exposure

This material is used as an intermediate in dyes, pharmaceuticals and explosives; in organic synthesis.

Metabolism

The metabolism of N-ethylaniline has been studied more as a tool to understanding microsomal drug metabolizing activity than as the central item of inquiry. However, the following have been clearly defined as metabolic products of N-ethylaniline: phenylhydroxylamine, N-hydroxyl, N-ethylaniline; N-ethyl-p-aminophenol; and aniline (Appel et al 1965; Heinze 1970; Hlavica 1970; Hlavica and Kiese 1969; Kampffmeyer and Kiese 1965; Kroeber et al 1970; Lange 1967 and Lange 1968). Nonmicrosomal metabolism has not been reported. Species shown capable of metabolism include rabbit, mouse, rat, dog, pig, and guinea pig with the proportions of the various metabolites often species dependent. Compounds similar to N-ethylaniline such as N-methyl-N-ethylaniline can form N-ethylaniline via demethylation (Gorrod et al 1975a,b).

Shipping

UN2272 N-Ethylaniline, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Incompatibilities

May form explosive mixture with air. Decomposes on contact with light or air. Reacts with many materials. Neutralizes acids in exothermic reactions to form salts plus water. Flammable gaseous hydrogen may be generated in combination with strong reducing agents such as hydrides, nitrides, alkali metals, and sulfides. Contact with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials; strong acids, such as nitric acid, can cause fire; explosions with formation of toxic vapors of aniline and oxides of nitrogen; strong bases, isocyanates, halogenated organics, phenols (acidic), epoxides, anhydrides, and acid halides

N-Ethylaniline Preparation Products And Raw materials

Raw materials

Ethanol 2-Ethylaniline Tosyl chloride Aniline

Preparation Products

[2-[[4-[(2-cyano-4-nitrophenyl)azo]phenyl]ethylamino]ethyl]trimethylammonium methyl sulphate Acid Violet 17 Disperse Blue 257 [2-[[4-[(2-chloro-4-nitrophenyl)azo]phenyl]ethylamino]ethyl]trimethylammonium Reactive Blue BRF

Disperse Violet 77 Disperse Scarlet SE-R Zinc ethylphenyl dithiocarbamate Reactive Red ME-2G 4-(2-(N-PHENYL-N-ETHYLAMINO)ETHOXY)-3,5-DICHLOROBENZENAMINE

Benzenamine, N-ethyl-4-nitro-N-nitroso- [2-[ethyl[4-[(4-nitrophenyl)azo]phenyl]amino]ethyl]trimethylammonium chloride N-Ethylcyclohexylamine N-NITROSO-N-ETHYLANILINE N-Chloroethyl-N-ethylaniline

Paquinimod Reactive Red 252 trisodium 5-[[4-chloro-6-(ethylphenylamino)-1,3,5-triazin-2-yl]amino]-4-hydroxy-3-[(2-sulphonatophenyl)azo]naphthalene-2,7-disulphonate

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N-Ethylaniline Suppliers

Global( 260)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Changde Changlian Chemical Co., Ltd.	+86-025-86736270 +8615905172087	brian.he@royal-chem.com	China	96	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	22021	55
Hangzhou FandaChem Co.,Ltd.	+8615858145714	fandachem@gmail.com	China	9396	55
Anhui Royal Chemical Co., Ltd.	+86-25-86655873 +8613962173137	marketing@royal-chem.com	China	536	55
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418679	info@tnjchem.com	China	2995	55
Tianjin Zhongxin Chemtech Co., Ltd.	+86-022-66880623 +8618622897568	sales@tjzxchem.com	China	547	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29960	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	CHINA	2940	58
Shenzhen Nexconn Pharmatechs Ltd	15013857715	admin@nexconn.com	CHINA	3004	58
Hubei Jusheng Technology Co.,Ltd.	86-18871470254	linda@hubeijusheng.com	CHINA	28229	58

Supplier	Advantage
Changde Changlian Chemical Co., Ltd.	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Anhui Royal Chemical Co., Ltd.	55
Hefei TNJ Chemical Industry Co.,Ltd.	55
Tianjin Zhongxin Chemtech Co., Ltd.	58
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Shenzhen Nexconn Pharmatechs Ltd	58
Hubei Jusheng Technology Co.,Ltd.	58

View Lastest Price from N-Ethylaniline manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-05-24	N-Ethylaniline 103-69-5	US $0.00 / kg	1kg	99%	1000mt/year	Jinan Finer Chemical Co., Ltd
2022-03-26	N-Ethylaniline 103-69-5	US $6.00 / ml	100ml	99%	5000ml	Henan Guange Biotechnology Co. LTD
2021-06-02	N-Ethylaniline 103-69-5	US $1.00 / PCS	1KG	99%	10 mt	Hebei Guanlang Biotechnology Co., Ltd.

N-Ethylaniline
103-69-5
US $0.00 / kg
99%
Jinan Finer Chemical Co., Ltd

N-Ethylaniline
103-69-5
US $6.00 / ml
99%
Henan Guange Biotechnology Co. LTD

N-Ethylaniline
103-69-5
US $1.00 / PCS
99%
Hebei Guanlang Biotechnology Co., Ltd.

N-Ethylaniline Spectrum

N-Ethylaniline(103-69-5)MS N-Ethylaniline(103-69-5)¹HNMR N-Ethylaniline(103-69-5)¹³CNMR N-Ethylaniline(103-69-5)IR1 N-Ethylaniline(103-69-5)IR2 N-Ethylaniline(103-69-5)ESR

103-69-5(N-Ethylaniline)Related Search:

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