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Ethyl bromoacetate

Ethyl bromoacetate
Ethyl bromoacetate structure
CAS No.
105-36-2
Chemical Name:
Ethyl bromoacetate
Synonyms
Antol;ethylbromacetate;hyl bromoacetate;Ethyl bromacetate;ETHYL BROMOACETATE;ethylbromoethanoate;ETHYL 2-BROMOACETATE;bromoacetated’ethyle;ethylmonobromoacetate;thyl monobromoacetate
CBNumber:
CB6852654
Molecular Formula:
C4H7BrO2
Formula Weight:
167
MOL File:
105-36-2.mol

Ethyl bromoacetate Properties

Melting point:
-38 °C
Boiling point:
159 °C(lit.)
Density 
1.506 g/mL at 25 °C(lit.)
vapor pressure 
2.6 mm Hg ( 25 °C)
refractive index 
n20/D 1.451(lit.)
Flash point:
118 °F
storage temp. 
Store below +30°C.
solubility 
water: insoluble
form 
Liquid
color 
Clear
Specific Gravity
1.506
Water Solubility 
Miscible with ethanol, acetone, benzene and ethyl ether. Immiscible with water.
BRN 
506456
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, water, strong acids.
InChIKey
PQJJJMRNHATNKG-UHFFFAOYSA-N
CAS DataBase Reference
105-36-2(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, ethyl ester(105-36-2)
EPA Substance Registry System
Acetic acid, bromo-, ethyl ester(105-36-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  T+
Risk Statements  26/27/28
Safety Statements  26-45-7/9-1/2
RIDADR  UN 1603 6.1/PG 2
WGK Germany  1
RTECS  AF6000000
19
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29159080
Hazardous Substances Data 105-36-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P320 Specific treatment is urgent (see … on this label).
P330 Rinse mouth.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.

NFPA 704

Diamond Hazard Value Description
2
0
Health  
Flammability   2 Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur and multiple finely divided suspended solids that do not require heating before ignition can occur. Flash point between 37.8 and 93.3 °C (100 and 200 °F). (e.g. diesel fuel, sulfur)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

Ethyl bromoacetate price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 133973 Ethyl bromoacetate reagent grade, 98% 105-36-2 5g $32.7 2018-11-22 Buy
Sigma-Aldrich 133973 Ethyl bromoacetate reagent grade, 98% 105-36-2 100g $33.9 2018-11-22 Buy
Alfa Aesar A10448 Ethyl bromoacetate, 98% 105-36-2 500g $87 2018-11-13 Buy
Alfa Aesar A10448 Ethyl bromoacetate, 98% 105-36-2 100g $30.8 2018-11-13 Buy
Sigma-Aldrich 133973 Ethyl bromoacetate reagent grade, 98% 105-36-2 500g $106 2018-11-22 Buy

Ethyl bromoacetate Chemical Properties,Uses,Production

Chemical Properties

colourless to light yellow liquid

Chemical Properties

Ethyl bromoacetate is a clear, colorless to light-yellow liquid.

Uses

Ethyl Bromoacetate, is used in the synthesis of metabolites of carcinogenic PAHs. Used in the preparation of steroidal antiestrogens through cyclic condensation. A reactant in the preparation of antim icrobial and antioxidant coumarinyloxymethyl-thiadiazolone.

General Description

A clear, colorless liquid (b.p. 318°F). Flash point 47°C. A lachrymator. Toxic by ingestion, inhalation and skin absorption; a strong irritant of the skin. Insoluble in water and soluble in alcohol, benzene, and ether. Specific gravity of 1.5.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

Ethyl bromoacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Toxic by ingestion, inhalation, and skin absorption; strong irritant.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

A poison. An irritant to skin, eyes, and mucous membranes. Questionable carcinogen with experimental neoplastigenic data. Flammable liquid when exposed to heat, flame, and oxidizers. Will react with water or steam to produce toxic and corrosive fumes. To fight fire, use water as a fire blanket. When heated to decomposition or on contact with acid or acid fumes, it emits highly toxic fumes of Br-. See also BROMIDES.

Potential Exposure

Used for making pharmaceuticals; as a warning gas in poisonous, odorless gasses; as a tear gas

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy

Shipping

UN1603 Ethyl bromoacetate, Hazard class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Wash the ester with saturated aqueous Na2CO3 (three times), 50% aqueous CaCl2 (three times) and saturated aqueous NaCl (twice). Dry with MgSO4, CaCl2 or CaCO3, and distil it. [Beilstein 2 IV 527.] LACHRYMATORY.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and reducing agents. Esters are generally incompatible with nitrates. Moisture may cause hydrolysis or other forms of decomposition.

Ethyl bromoacetate Preparation Products And Raw materials

Raw materials

Preparation Products


Ethyl bromoacetate Suppliers

Global( 271)Suppliers
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Yancheng Longshen Chemical Co.,Ltd.
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View Lastest Price from Ethyl bromoacetate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-22 Ethyl bromoacetate
105-36-2
US $1.00 / kg 1kg 99% Customized career henan chemical co

Ethyl bromoacetate Spectrum


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