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2-Butyne-1,4-diol

2-Butyne-1,4-diol
2-Butyne-1,4-diol structure
CAS No.
110-65-6
Chemical Name:
2-Butyne-1,4-diol
Synonyms
BOZ;Butynediol;agrisynthb3d;2-Butynediol;1,4-butinodiol;1,4-BUTYNEDIOL;Butynediol,99%;Butyne-1.4-diol;2-Butin-1,4-diol;2-BUTYN-1,4-DIOL
CBNumber:
CB6852816
Molecular Formula:
C4H6O2
Formula Weight:
86.09
MOL File:
110-65-6.mol

2-Butyne-1,4-diol Properties

Melting point:
54 °C
Boiling point:
238 °C(lit.)
Density 
1.2
vapor pressure 
<0.1 mm Hg ( 55 °C)
refractive index 
1.4804
Flash point:
306 °F
storage temp. 
Refrigerator
solubility 
3740g/l
form 
Crystalline Platelets or Flakes
color 
slightly brown
PH
4-7.5 (100g/l, H2O, 23℃)
Water Solubility 
3740 g/L (20 ºC)
BRN 
1071237
Stability:
Stable. Highly flammable solid. Incompatible with strong oxidizing agents, acid chlorides, acid anhydrides, strong acids, strong bases.
CAS DataBase Reference
110-65-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Butyne-1,4-diol(110-65-6)
EPA Substance Registry System
2-Butyne-1,4-diol(110-65-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  T,C
Risk Statements  21-23/25-34-43-48/22
Safety Statements  25-26-36/37/39-45-46
RIDADR  UN 2716 6.1/PG 3
WGK Germany  2
RTECS  ES0525000
23-10
Autoignition Temperature 410 °C
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29053980
Hazardous Substances Data 110-65-6(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 100 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H228 Flammable solid Flammable solids Category 1
Category 2
Danger
Warning
P210, P240,P241, P280, P370+P378
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning P280,P302+P352, P312, P322, P363,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H402 Harmful to aquatic life Hazardous to the aquatic environment, acute hazard Category 3
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P314 Get medical advice/attention if you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
1
0
Health  
Flammability   1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

2-Butyne-1,4-diol price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B103209 2-Butyne-1,4-diol 99% 110-65-6 100g $22.8 2018-11-13 Buy
Sigma-Aldrich B103209 2-Butyne-1,4-diol 99% 110-65-6 1kg $56.4 2018-11-13 Buy
TCI Chemical B0749 2-Butyne-1,4-diol >99.0%(GC) 110-65-6 25g $10 2018-11-22 Buy
TCI Chemical B0749 2-Butyne-1,4-diol >99.0%(GC) 110-65-6 500g $47 2018-11-22 Buy
Alfa Aesar A14539 2-Butyne-1,4-diol, 98+% 110-65-6 1000g $52.8 2018-11-13 Buy

2-Butyne-1,4-diol Chemical Properties,Uses,Production

Chemical Properties

yellow solid

Uses

Basic brightener in nickel electroplating baths,also an important intermediate for organic synthesis

Uses

2-Butyne-1,4-diol is used to produce butanedioland butenediol, in metal plating andpickling baths, and in making the carbamateherbicide Barban (Carbyne).

Definition

ChEBI: A butynediol that is but-2-yne substituted by hydroxy groups at positions 1 and 4.

General Description

White to light-brown solid or brownish-yellow aqueous solution. Solid sinks and mixes with water.

Air & Water Reactions

Water soluble.

Reactivity Profile

Pure 2-Butyne-1,4-diol is non-explosvie. Small amounts of certain impurities-alkali hydroxides, alkaline earth hydroxides, halides-may cause explosive decomposition upon distillation. 2-Butyne-1,4-diol should not be treated with basic catalysts in the absence of a solvent at room temperature, and its stability is less with elevated temperatures. In strong acids, contamination with mercury salts can also result in violent decomposition [NFPA 491M 1991].

Hazard

Toxic by ingestion. May explode on con- tamination with mercury salts, strong acids, and alkaline earth hydroxides and halides at high tem- peratures.

Health Hazard

2-Butyne-1,4-diol exhibits moderate to hightoxicity in test animals. It is about 10 timesmore toxic than are the saturated C4 diols.The oral LD50 value in rats is 0.125 mL/kg.It causes irritation to the skin.

Health Hazard

May cause dermatitis.

Fire Hazard

Noncombustible solid, flash point (open cup) 152°C (305.6°F). It is stable at room temperature. But the dry compound explodes in the presence of certain heavy metal salts, such as mercuric chloride. Heating with alkaline solution may result in an explosion.

Safety Profile

A poison by ingestion. A skin sensitizer upon long or repeated contact. Moderately explosive. When heated to decomposition it emits acrid smoke and fumes and may explode. Explosive reaction with traces of alkaltes, alkali earth hydroxides, halide salts, strong acids, mercury salts + strong acids. See also ACETYLENE COMTOUNDS.

storage

2-Butyne-1,4-diol can be stored in steel,aluminum, nickel, glass, epoxy, and phenolicliner containers. Rubber hose may be usedfor transfer. Avoid contact with heavy metalsalt contaminants.

Purification Methods

Crystallise the diol from EtOAc. [Beilstein 1 IV 2687.]

2-Butyne-1,4-diol Preparation Products And Raw materials

Raw materials

Preparation Products


2-Butyne-1,4-diol Suppliers

Global( 220)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd.
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View Lastest Price from 2-Butyne-1,4-diol manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-07-11 2-Butyne-1,4-diol
110-65-6
US $1.00 / KG 1KG 99% 25kg career henan chemical co

2-Butyne-1,4-diol Spectrum


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