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sec-Butylamine

sec-Butylamine
sec-Butylamine structure
CAS No.
13952-84-6
Chemical Name:
sec-Butylamine
Synonyms
SBA;2-AB;Tutane;Frucote;Butafume;Deccotane;sec-C4H9NH2;2-Butylamin;S-BUTYLAMINE;2-Aminobutan
CBNumber:
CB6853095
Molecular Formula:
C4H11N
Formula Weight:
73.14
MOL File:
13952-84-6.mol

sec-Butylamine Properties

Melting point:
-104 °C
Boiling point:
63 °C(lit.)
Density 
0.724 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.3928(lit.)
FEMA 
4240 | SEC-BUTYLAMINE
Flash point:
−3 °F
storage temp. 
Flammables area
solubility 
112g/l
form 
Liquid
pka
10.56(at 25℃)
color 
Clear colorless to light yellow
Specific Gravity
0.723 (20/4℃)
Odor
Ammonia-like.
explosive limit
1.8-9.0%(V)
Water Solubility 
MISCIBLE
Sensitive 
Air Sensitive
Merck 
14,1544
JECFA Number
1584
BRN 
1361345
Stability:
Stable, but light sensitive. Incompatible with strong oxidizing agents, strong acids. Highly flammable.
CAS DataBase Reference
13952-84-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Butanamine(13952-84-6)
EPA Substance Registry System
2-Butanamine(13952-84-6)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS05,GHS06,GHS09,GHS07
Signal word  Danger
Hazard statements  H225-H301-H314-H332-H410-H302-H318-H400
Precautionary statements  P210-P273-P280-P301+P310-P305+P351+P338-P310-P260h-P303+P361+P353-P405-P501a
Hazard Codes  F,C,N
Risk Statements  11-20/22-35-50
Safety Statements  9-16-26-28-36/37/39-45-61-28A
RIDADR  UN 2733 3/PG 2
WGK Germany  2
RTECS  EO3325000
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29211980

NFPA 704

Diamond Hazard Value Description
3
Health  
Flammability   3 Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions . Liquids having a flash point below 22.8 °C (73 °F) and having a boiling point at or above 37.8 °C (100 °F) or having a flash point between 22.8 and 37.8 °C (73 and 100 °F). (e.g. gasoline, acetone)
Instability  
Special  

(NFPA, 2010)

sec-Butylamine price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B89000 sec-Butylamine 99% 13952-84-6 100ml $26.7 2018-11-13 Buy
Sigma-Aldrich 90965 sec-Butylamine analytical standard 13952-84-6 1ml $50.5 2018-11-13 Buy
Alfa Aesar A13014 (±)-2-Aminobutane, 98% 13952-84-6 2500ml $129 2018-11-13 Buy
Alfa Aesar A13014 (±)-2-Aminobutane, 98% 13952-84-6 500ml $29.9 2018-11-13 Buy
Sigma-Aldrich B89000 sec-Butylamine 99% 13952-84-6 500ml $38.9 2018-11-13 Buy

sec-Butylamine Chemical Properties,Uses,Production

Description

Sec-butylamine is an amine of butane. It can be used as a fungicide. It can be used as a fumigant for control of gangrene, skin spot and silver scurf diseases of potato tubers, citrus fruit decay. However, it is highly toxic to aquatic organisms.

Chemical Properties

colourless liquid with an amine odour

Chemical Properties

Butyl amines are highly flammable, colorless liquids (n-turns yellow on standing) with ammoniacal or fishlike odors. n-isomer:

Chemical Properties

Colorless to yellow liquid; fishy ammonia aroma.

Uses

Fungicide.

Definition

ChEBI: A primary aliphatic amine that is butane in which one hydrogen at position 2 is replaced by an amino group. A fumigant fungicide with a high potential for bioaccumulation, it is not approved for fungicidal use in the European Union.

Aroma threshold values

High strength odor; fishy type; recommend smelling in a 0.10% solution or less.

Hazard

Flammable, dangerous fire risk.

Health Hazard

Recommended Personal Protective Equipment: Chemical safety goggles; rubber gloves and apron; respiratory protective equipment; non-sparking shoes; Symptoms Following Exposure: Inhalation causes irritation of burns of the respiratory system; exposure to concentrated vapors can cause asphyxiation. Ingestion causes burns of mouth and stomach. Contact with eyes causes lachrymation, conjunctivitis, burns, corneal edema. Contact with skin causes irritation or burns, dermatitis; General Treatment for Exposure: INHALATION: remove patient from exposure; keep him quiet; contact physician. INGESTION: give large amount of water; induce vomiting; consult a physician. EYES: flush thoroughly with water for 15 min.; call physician immediately. SKIN: remove all contaminated clothing; flood affected area with large quantities of water; consult a physician; Toxicity by Inhalation (Threshold Limit Value): Data not available; Short-Term Exposure Limits: Data not available; Toxicity by Ingestion: Grade 3; oral LD50 = 380 mg/kg (rat); Late Toxicity: Data not available; Vapor (Gas) Irritant Characteristics: Vapors are moderately irritating such that personnel will not usually tolerate moderate or high concentrations; Liquid or Solid Irritant Characteristics: Severe skin irritant. Causes second- and third-degree burns on short contact and is very injurious to the eyes; Odor Threshold: Data not available.

Chemical Reactivity

Reactivity with Water: No reaction; Reactivity with Common Materials: May corrode some metals in presence of water; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

A poison by ingestion. A powerful irritant. Moderately toxic by skin contact. Dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits toxic fumes of NOx. A fungicide.

Potential Exposure

Alert: (n-isomer): Possible risk of forming tumors, suspected of causing genetic defects, suspected reprotoxic hazard, Primary irritant (w/o allergic reaction), (sec-isomer): Drug. n-Butylamine is used in pharmaceuticals; dyestuffs, rubber, chemicals, emulsifying agents; photography, desizing agents for textiles; pesticides, and synthetic agents. sec-Butylamine is used as a fungistate. tert-Butylamine is used as a chemical intermediate in the production of tert-Butylaminoethyl methacrylate (a lube oil additive); as an intermediate in the production of rubber and in rust preventatives and emulsion deterrents in petroleum products. It is used in the manufacture of several drugs

Shipping

UN1125 n-Butylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material. UN2014 Isobutylamine, Hazard Class: 3; Labels: 3—Flammable liquid, 8—Corrosive material

Incompatibilities

May form explosive mixture with air. May accumulate static electrical charges, and may causeignition of its vapors. n-Butylamine is a weak base; reacts with strong oxidizers and acids, causing fire and explosion hazard. Incompatible with organic anhydrides; isocyanates, vinyl acetate; acrylates, substituted allyls; alkylene oxides; epichlorohydrin, ketones, aldehydes, alcohols, glycols, phenols, cresols, caprolactum solution. Attacks some metals in presence of moisture. The tert-isomer will attack some forms of plastics

Waste Disposal

Use a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner andscrubber. All federal, state, and local environmental regulations must be observed.

References

Smilanick, J. L., and J. W. Eckert. "Growth, sporulation, and virulence of isolates of Penicillium digitatum resistant to the fungicide sec-butylamine. " Phytopathology 76.8(1986).
Graham, D. C., et al. "Use of 2-aminobutane as a fumigant for control of gangrene, skin spot and silver scurf diseases of potato tubers." Potato Research 16.2(1973):109-125.
Gutter, Y. "Combined treatment with thiabendazole and 2-aminobutane for control of citrus fruit decay." Crop Protection 4.3(1985):346-350.

sec-Butylamine Preparation Products And Raw materials

Raw materials

Preparation Products


sec-Butylamine Suppliers

Global( 164)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 30002 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23976 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28236 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6372 58
Kono Chem Co., Ltd
+86-132 8924 6953(Whatsapp/Wechat)
+86-29-86107037 info@konochemical.com CHINA 2997 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 sales@guangaobio.com CHINA 23049 58
Shandong chuangyingchemical Co., Ltd.
13156170209
sale@chuangyingchem.com CHINA 4405 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 35440 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76

View Lastest Price from sec-Butylamine manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-07-12 sec-Butylamine
13952-84-6
US $8.80 / KG 1KG 97%-99% 100kg career henan chemical co

sec-Butylamine Spectrum


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