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tert-Butyl nitrite

CAS No.
540-80-7
Chemical Name:
tert-Butyl nitrite
Synonyms
t-BuNO2;T-BUTYL NITRITE;t-butyl ester;2-Methyl-2-nitrosooxy-propane;t-Buthyl nitrite;ert-buty nitrite;ert-Butylnitrite;Tert-buty nitrite;TERT-BUTYL NITRITE;TIMTEC-BB SBB007659
CBNumber:
CB6853772
Molecular Formula:
C4H9NO2
Molecular Weight:
103.12
MDL Number:
MFCD00002055
MOL File:
540-80-7.mol
MSDS File:
SDS
Last updated:2024-04-01 18:08:31

tert-Butyl nitrite Properties

Boiling point 61-63 °C(lit.)
Density 0.867 g/mL at 25 °C(lit.)
vapor pressure 13.466kPa at 25℃
refractive index n20/D 1.368(lit.)
Flash point −10 °F
storage temp. 2-8°C
solubility alcohol: very soluble(lit.)
form Liquid
color Clear yellow
Water Solubility slightly soluble
Merck 14,1583
BRN 1209339
LogP 2.24 at 20℃
CAS DataBase Reference 540-80-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 4780H7U8LU
NIST Chemistry Reference (CH3)3CONO(540-80-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H302+H332
Precautionary statements  P210-P233-P240-P241-P301+P312-P304+P340+P312
Hazard Codes  F,Xn
Risk Statements  11-20/22
Safety Statements  16-24-46
RIDADR  UN 2351 3/PG 2
WGK Germany  1
RTECS  RA0802000
8
HazardClass  3
PackingGroup  II
HS Code  29209085
NFPA 704
3
2 0

tert-Butyl nitrite price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 20370 tert-Butyl nitrite technical, ≥90% (GC) 540-80-7 100mL $92 2024-03-01 Buy
Sigma-Aldrich 20370 tert-Butyl nitrite technical, ≥90% (GC) 540-80-7 500mL $323 2024-03-01 Buy
TCI Chemical N0357 tert-Butyl Nitrite >90.0%(GC) 540-80-7 25mL $65 2024-03-01 Buy
TCI Chemical N0357 tert-Butyl Nitrite >90.0%(GC) 540-80-7 250mL $392 2024-03-01 Buy
Alfa Aesar L16135 tert-Butyl nitrite tech. 90% 540-80-7 25g $35.4 2023-06-20 Buy
Product number Packaging Price Buy
20370 100mL $92 Buy
20370 500mL $323 Buy
N0357 25mL $65 Buy
N0357 250mL $392 Buy
L16135 25g $35.4 Buy

tert-Butyl nitrite Chemical Properties,Uses,Production

Chemical Properties

clear yellow liquid

Uses

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Uses

Jet propellant.

General Description

tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.

Purification Methods

If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]

Global( 423)Suppliers
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Henan Fengda Chemical Co., Ltd
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airuikechemical co., ltd.
+undefined86-15315557071 sales02@airuikechemical.com China 994 58
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Xiamen AmoyChem Co., Ltd
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Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58

View Lastest Price from tert-Butyl nitrite manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tert-Butyl nitrite pictures 2024-04-10 Tert-Butyl nitrite
540-80-7
US $0.00-0.00 / Kg 1Kg 99.99% 20 tons airuikechemical co., ltd.
t-butyl nitrite pictures 2024-01-22 t-butyl nitrite
540-80-7
US $8.00-0.80 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
tert-Butyl nitrite pictures 2023-07-25 tert-Butyl nitrite
540-80-7
US $50.00 / KG 25KG 98% 200 tons Hebei Yanxi Chemical Co., Ltd.
  • t-butyl nitrite pictures
  • t-butyl nitrite
    540-80-7
  • US $8.00-0.80 / KG
  • 99%
  • Henan Fengda Chemical Co., Ltd
TERT-BUTYL NITRITE: TECH., 90% 1,1-dimethylethylnitrite 2-methyl-2-nitritopropane alpha,alpha-Dimethylethyl nitrite alpha,alpha-dimethylethylnitrite 2-methyl-2-propyl nitrite tert-Butyl nitrite, technical, 90% tert-Butyl nitrite 90% tert-Butyl nitrite technical, >=90% (GC) tert-Butyl nitrite, 90%, pure Nitrous acid tert-butyl tert-Butyl nitrite ,95% Tert-buty nitrite tert-Butyl nitrite, pure, 90% 500GR 1,1-diMethylethyl ester Nitrous acid TERT-BUTYL NITRITE FOR SYNTHESIS Nitrous acid, 1,1-dimethylethyl ester Nitrous acid, t-butyl ester nitrousacid,1,1-dimethylethylester nitrousacid,t-butylester TERT-BUTYL NITRITE NITROUS ACID TERT-BUTYL ESTER TIMTEC-BB SBB007659 tert-Butylnitrite,tech.90% tert-Butyl nitrite, pure, 90% t-Buthyl nitrite α,α-Dimethylethyl nitrite ert-buty nitrite tert-Butyl nitrite, 95%, for synthesis 1,1-Dimethylethyl Nitrite (~90%) tert-ButylNitrite> ert-Butylnitrite TERT-BUTYL NITRITE 540-80-7 tert-Butylnitrite,technical,90% alpha,alpha-DimethylethylnitriChemicalbookte α,α-Dimethylethyl nitrite t-butyl ester 2-Methyl-2-nitrosooxy-propane T-BUTYL NITRITE t-BuNO2 Tterobutyrate nitrite tert-Butyl nitrite (6CI, 7CI) tert-Butyl nitrite(TBN) Borane-methyl sulfide complex 10m in Dimethylsilfide Tertiary butyl nitrite tert-Butyl Nitrite, ≥ 90.0% 540-80-7 CH33CONO Organic Building Blocks Nitrogen Compounds Organic Nitrates/Nitrites Building Blocks Nitrogen Compounds Organic Building Blocks Organic Nitrates/Nitrites Imidazoles straight chain compounds