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tert-Butyl nitrite

tert-Butyl nitrite Structure
tert-Butyl nitrite structure
CAS No.
540-80-7
Chemical Name:
tert-Butyl nitrite
Synonyms
tBuoNo;T-BUTYL NITRITE;t-BuNO2;t-butyl ester;Tertiary butyl nitrite;tert-Butyl nitrite 90%;2-methyl-2-nitritopropane;2-Methyl-2-nitrosooxy-propane;t-Buthyl nitrite;ert-buty nitrite
CBNumber:
CB6853772
Molecular Formula:
C4H9NO2
Molecular Weight:
103.12
MDL Number:
MFCD00002055
MOL File:
540-80-7.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-09 08:01:58
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tert-Butyl nitrite Properties

Boiling point 61-63 °C(lit.)
Density 0.867 g/mL at 25 °C(lit.)
vapor pressure 13.466kPa at 25℃
refractive index n20/D 1.368(lit.)
Flash point −10 °F
storage temp. 2-8°C
solubility alcohol: very soluble(lit.)
form Liquid
color Clear yellow
Water Solubility slightly soluble
Merck 14,1583
BRN 1209339
Henry's Law Constant 7.9×10-3 mol/(m3Pa) at 25℃, Hilal et al. (2008)
InChI 1S/C4H9NO2/c1-4(2,3)7-5-6/h1-3H3
InChIKey IOGXOCVLYRDXLW-UHFFFAOYSA-N
SMILES CC(C)(C)ON=O
LogP 2.24 at 20℃
CAS DataBase Reference 540-80-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 4780H7U8LU
NIST Chemistry Reference (CH3)3CONO(540-80-7)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H302+H332
Precautionary statements  P210-P233-P240-P241-P301+P312-P304+P340+P312
PPE Eyeshields, Faceshields, Gloves
Hazard Codes  F,Xn
Risk Statements  11-20/22
Safety Statements  16-24-46
RIDADR  UN 2351 3/PG 2
WGK Germany  1
RTECS  RA0802000
F  8
HazardClass  3
PackingGroup  II
HS Code  29209085
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Flam. Liq. 2
REACH Registrations Active
Limited Quantities 1.0 L (0.3 gallon) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3
2 0

tert-Butyl nitrite price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 20370 tert-Butyl nitrite technical, ≥90% (GC) 540-80-7 100mL $101 2026-04-30 Buy
Sigma-Aldrich 20370 tert-Butyl nitrite technical, ≥90% (GC) 540-80-7 500mL $355 2026-04-30 Buy
TCI Chemical N0357 tert-Butyl Nitrite >90.0%(GC) 540-80-7 25mL $62 2026-04-30 Buy
TCI Chemical N0357 tert-Butyl Nitrite >90.0%(GC) 540-80-7 250mL $372 2026-04-30 Buy
Usbiological 410399 1,1-Dimethylethyl Nitrite 540-80-7 1g $389 2026-06-03 Buy
Product number Packaging Price Buy
20370 100mL $101 Buy
20370 500mL $355 Buy
N0357 25mL $62 Buy
N0357 250mL $372 Buy
410399 1g $389 Buy

tert-Butyl nitrite Chemical Properties, Uses, Production

Chemical Properties

clear yellow liquid

Uses

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Uses

Jet propellant.

General Description

tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.

Purification Methods

If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]

tert-Butyl nitrite Preparation Products And Raw materials

Raw materials

Silver nitrate 2-Chloro-2-methylpropane Nitrogen Tetroxide Nitric oxide Benzyln-butylether
tert-butoxy tert-Butyl nitrate 2-Methyl-2-nitropropane tert-Butanol tert-Butyl hydroperoxide
3,3-dimethylbutanal 2-Bromo-2-methylpropane

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Preparation Products

8-Quinolineboronic acid 2-Bromo-5-hydroxypyridine radical ion(1+) 2-Chloro-5-cyano-3-methylpyridine Goserelin 2-Chloro-5-iodo-3-methylpyridine
4,7-Dihydro-4-oxo-3H-pyrrolo[2,3-d][1,2,3]triazine-5-carboxamide 2-Bromo-5-fomylthiazole 2,6-Dibromoanthraquinone 3,5-Diiodobenzoic acid 4-Chloro-2-nitrophenol
tert-butyl 2-bromo-6,7-dihydrothiazolo[5,4-c]pyridine-5(4H)-carboxylate S-Nitrosoglutathione

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tert-Butyl nitrite Suppliers

Global Suppliers ( 451)
Supplier Tel Email Country ProdList Advantage
Dalian Idery Biotechnology Co., Ltd. 15141125520 15141125520 3489496641@qq.com China 152 58
Shanghai Heng Pan Biological Medicine Co., LTD 18217762875 2136632918@qq.com China 11 58
Yangzhou Aoxin Chemical Co., Ltd 0514-87754778 13901446058 sales@aochem.com China 69 66
Changzhou Xiaqing Technological Co., Ltd. 88783621 15961106108 john.chiang@xialichem.com China 144 70
Zouping Innovation Pharmaceutical Co., Ltd. 13561560789 xinxiaoxiao2008@126.com China 686 58
Changzhou Liren Medical Technology Co. Ltd. 0519-85859058 13915836899 2078957504@qq.com China 454 58
Nanjing Wanpu Pharmaceutical Technology Co.,Ltd 13814527050; 13814527050 3773605130@qq.com China 213 58
Shanghai Yanze Chemical Co., Ltd. 15345144255 19975051755 260924549@qq.com China 2979 58
Qingdao Haizhi Weiyuan Biotechnology Co., Ltd. 18317699790 18317699790 l202008112023@163.com China 7733 58
Qingdao Dexin Chemical Co. LTD 18560810705 354907727@qq.com China 299 58
Supplier Advantage
Dalian Idery Biotechnology Co., Ltd. 58
Shanghai Heng Pan Biological Medicine Co., LTD 58
Yangzhou Aoxin Chemical Co., Ltd 66
Changzhou Xiaqing Technological Co., Ltd. 70
Zouping Innovation Pharmaceutical Co., Ltd. 58
Changzhou Liren Medical Technology Co. Ltd. 58
Nanjing Wanpu Pharmaceutical Technology Co.,Ltd 58
Shanghai Yanze Chemical Co., Ltd. 58
Qingdao Haizhi Weiyuan Biotechnology Co., Ltd. 58
Qingdao Dexin Chemical Co. LTD 58

Related articles

View Latest Price from tert-Butyl nitrite manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
t-butyl nitrite pictures 2026-09-02 t-butyl nitrite
540-80-7
 $8.00 1KG 99% Henan Fengda Chemical Co., Ltd
Tert-buty nitrite pictures 2026-08-07 Tert-buty nitrite
540-80-7
 $1.00 1KG 99% 200000KG Shaanxi Dideu Medichem Co. Ltd
Tert-butyl nitrite pictures 2026-07-07 Tert-butyl nitrite
540-80-7
 1KG 99% 20Tons Shaanxi Dideu New Materials Co. Ltd

tert-Butyl nitrite Spectrum

tert-Butyl nitrite(540-80-7)MStert-Butyl nitrite(540-80-7)1HNMRtert-Butyl nitrite(540-80-7)13CNMRtert-Butyl nitrite(540-80-7)IR1

540-80-7 (tert-Butyl nitrite) Related Search:

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TERT-BUTYL NITRITE: TECH., 90% 1,1-dimethylethylnitrite alpha,alpha-Dimethylethyl nitrite alpha,alpha-dimethylethylnitrite 2-methyl-2-propyl nitrite tert-Butyl nitrite, technical, 90% tert-Butyl nitrite technical, >=90% (GC) tert-Butyl nitrite, 90%, pure Nitrous acid tert-butyl tert-Butyl nitrite ,95% Tert-buty nitrite tert-Butyl nitrite, pure, 90% 500GR 1,1-diMethylethyl ester Nitrous acid TERT-BUTYL NITRITE FOR SYNTHESIS Nitrous acid, 1,1-dimethylethyl ester Nitrous acid, t-butyl ester nitrousacid,1,1-dimethylethylester nitrousacid,t-butylester TERT-BUTYL NITRITE NITROUS ACID TERT-BUTYL ESTER TIMTEC-BB SBB007659 tert-Butylnitrite,tech.90% tert-Butyl nitrite, pure, 90% t-Buthyl nitrite α，α-Dimethylethyl nitrite ert-buty nitrite tert-Butyl nitrite, 95%, for synthesis 1,1-Dimethylethyl Nitrite (~90%) tert-ButylNitrite> ert-Butylnitrite TERT-BUTYL NITRITE 540-80-7 tert-Butylnitrite,technical,90% alpha,alpha-DimethylethylnitriChemicalbookte 2-Methyl-2-nitrosooxy-propane Tterobutyrate nitrite tert-Butyl nitrite (6CI, 7CI) tert-Butyl nitrite(TBN) Borane-methyl sulfide complex 10m in Dimethylsilfide tert-Butyl Nitrite, ≥ 90.0% tert-Butyl nitrite - 90% purity by G.C tert-Butyl nitrite Tert Butyl Nitrite 90%-Bulk 2-methyl-2-nitritopropane t-butyl ester T-BUTYL NITRITE t-BuNO2 tBuoNo tert-Butyl nitrite 90% Tertiary butyl nitrite 540-80-7 8131-95-7 CH33CONO Organic Building Blocks Nitrogen Compounds Organic Nitrates/Nitrites Building Blocks Nitrogen Compounds Organic Building Blocks