(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
- CAS No.
- 13811-71-7
- Chemical Name:
- (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
- Synonyms
- DET;D-DET;D-tartrate;DIETHYL D-TARTRATE;(-)-Diethyl D-tartrate;D(-)diethyl tartarate;(2R,3R)-diethyl 2,3-dihydroxysuccinate;ETHYL TARTRATE;diethyl (2S,3S)-2,3-dihydroxybutanedioate;(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl
- CBNumber:
- CB7105982
- Molecular Formula:
- C8H14O6
- Molecular Weight:
- 206.19
- MDL Number:
- MFCD00064451
- MOL File:
- 13811-71-7.mol
- MSDS File:
- SDS
Melting point | 17 °C |
---|---|
Boiling point | 162 °C/19 mmHg (lit.) |
alpha | -9 º (neat) |
Density | 1.205 g/mL at 20 °C (lit.) |
refractive index |
n |
Flash point | 200 °F |
storage temp. | Store below +30°C. |
solubility | Chloroform (Slightly), Water (Slightly) |
pka | 11.61±0.20(Predicted) |
form | Viscous Liquid |
color | Clear colorless |
Specific Gravity | 1.21 |
optical activity | [α]23/D 8.5°, neat |
Water Solubility | insoluble |
Merck | 14,3855 |
BRN | 1727143 |
CAS DataBase Reference | 13811-71-7(CAS DataBase Reference) |
NIST Chemistry Reference | Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R*,R*)]-(13811-71-7) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H227 | |||||||||
Precautionary statements | P210e-P280a-P370+P378a-P403+P235-P501a | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 24/25-36-26 | |||||||||
WGK Germany | 3 | |||||||||
Hazard Note | Irritant | |||||||||
HS Code | 29181300 | |||||||||
NFPA 704 |
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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester price More Price(40)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 213969 | (?)-Diethyl D-tartrate ≥99% | 13811-71-7 | 5g | $50.6 | 2023-01-07 | Buy |
Sigma-Aldrich | 213969 | (?)-Diethyl D-tartrate ≥99% | 13811-71-7 | 25g | $87.2 | 2023-01-07 | Buy |
Sigma-Aldrich | 8.18685 | (2S,3S)-(-)-Diethyl tartrate for synthesis | 13811-71-7 | 25mL | $105 | 2023-01-07 | Buy |
TCI Chemical | T1195 | Diethyl D-(-)-Tartrate >97.0%(GC) | 13811-71-7 | 25g | $15 | 2023-01-07 | Buy |
TCI Chemical | T1195 | Diethyl D-(-)-Tartrate >97.0%(GC) | 13811-71-7 | 250g | $83 | 2023-01-07 | Buy |
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Chemical Properties,Uses,Production
Chemical Properties
Colorless to light yellow liqui
Uses
Diethyl D(-)-tartrate is mainly used in chiral pharmaceuticals, chiral intermediates and chiral catalysts. It can be used with titanium in enolic asymmetric epoxidization. The compound d-alpha-tocopherol is the principal compound present in natural vitamin E sources. At present, d-alpha-tocopherol and other tocopherol derivatives are used in pharmaceuticals, foods and animal feeds. It is used as a food additive.
Purification Methods
Distil the esters under high vacuum and store them under vacuum or in an inert atmosphere in a desiccator in round bottomed flasks equiped with a vacuum stopcock. They have also been distilled by Kügelrohr distillation and/or by 'wiped-film' molecular distillation. They are slightly soluble in H2O but miscible with EtOH and Et2O. [Gao et al. J Am Chem Soc 109 5770 (5771) 1987, IR: Pristera Anal Chem 25 844 1953, Beilstein 3 III 1025 for D-(-), 3 IV 1232 for L(+).]
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29810 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21975 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29922 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 86-18871470254 | linda@hubeijusheng.com | CHINA | 28185 | 58 |
Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8909 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | sales@amoychem.com | China | 6387 | 58 |
Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5911 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39919 | 58 |
View Lastest Price from (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
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2023-04-21 | Diethyl D Tartrate
13811-71-7
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Crovell Biotech Co Ltd | |
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2023-02-10 | (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
13811-71-7
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. | |
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2023-02-10 | Diisopropyl D-tartrate
13811-71-7
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. |
-
- Diethyl D Tartrate
13811-71-7
- US $5.00-2.00 / KG
- 99%
- Hebei Crovell Biotech Co Ltd
-
- (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
13811-71-7
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
-
- Diisopropyl D-tartrate
13811-71-7
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
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