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4,7-DIMETHYL-1H-INDENE

CAS No.
6974-97-6
Chemical Name:
4,7-DIMETHYL-1H-INDENE
Synonyms
Nsc22051;4,7-Dimethylindene;4,7-DIMETHYL-1H-INDENE;1H-Indene, 4,7-dimethyl-;3-pyridin-4-yl-1-propanethiol
CBNumber:
CB7129698
Molecular Formula:
C11H12
Molecular Weight:
144.21
MDL Number:
MFCD06797433
MOL File:
6974-97-6.mol
Last updated:2025-07-24 18:13:51
Product description Number Pack Size Price
4,7-Dimethyl-1H-indene J54994 250mg $35
4,7-Dimethyl-1H-indene 97% 034861 5g $215
4,7-DIMETHYL-1H-INDENE 95.00% CHM0079463 5G $909.56
4,7-Dimethyl-1H-indene 97% 034861 100g $2995
4,7-Dimethyl-1H-indene 97% A148811 1g $15
More product size

4,7-DIMETHYL-1H-INDENE Properties

Boiling point 230℃
Density 0.998
Flash point 87℃
storage temp. Sealed in dry,Room Temperature
Appearance Colorless to light yellow Liquid
FDA UNII HM99RV5YLV

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

4,7-DIMETHYL-1H-INDENE price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
AK Scientific J54994 4,7-Dimethyl-1H-indene 6974-97-6 250mg $35 2021-12-16 Buy
Oakwood 034861 4,7-Dimethyl-1H-indene 97% 6974-97-6 5g $215 2021-12-16 Buy
American Custom Chemicals Corporation CHM0079463 4,7-DIMETHYL-1H-INDENE 95.00% 6974-97-6 5G $909.56 2021-12-16 Buy
Oakwood 034861 4,7-Dimethyl-1H-indene 97% 6974-97-6 100g $2995 2021-12-16 Buy
Ambeed A148811 4,7-Dimethyl-1H-indene 97% 6974-97-6 1g $15 2021-12-16 Buy
Product number Packaging Price Buy
J54994 250mg $35 Buy
034861 5g $215 Buy
CHM0079463 5G $909.56 Buy
034861 100g $2995 Buy
A148811 1g $15 Buy

4,7-DIMETHYL-1H-INDENE Chemical Properties,Uses,Production

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 6627, 1994 DOI: 10.1016/S0040-4039(00)73452-6

Synthesis

1,3-Cyclopentadiene

542-92-7

2,5-Hexanedione

110-13-4

4,7-DIMETHYL-1H-INDENE

6974-97-6

The general procedure for the synthesis of 4,7-dimethyl-1H-indene from cyclopentadiene and 2,5-hexanedione was as follows: sodium filaments (426 mmol, 9.8 g) were pressed into a three-necked flask under argon protection, and about 100 mL of dry methanol was added slowly until the sodium filaments were completely dissolved. Subsequently, freshly distilled cyclopentadiene (260 mmol, 21.2 mL) and 2,5-hexanedione (170 mmol, 26.5 mL) were added, and the reaction mixture was stirred for 24 h, during which time bubbles were observed. Upon completion of the reaction, 50 mL of water was added to quench the reaction. After removal of the methanol solvent by steam distillation, the pH of the reaction solution was adjusted to neutral with dilute hydrochloric acid. The aqueous phase was extracted three times with 200 mL of petroleum ether, and the organic phases were combined, dried over anhydrous magnesium sulfate and filtered. The solvent was removed by rotary evaporation to give a dark brown liquid. The liquid was distilled under reduced pressure and the 76-80 °C fraction was collected at a pressure of 4 mmHg to give a final 21.5 g of yellow oily liquid product.

References

[1] Patent: CN106565404, 2017, A. Location in patent: Paragraph 0076; 0077; 0078
[2] Tetrahedron, 1995, vol. 51, # 15, p. 4347 - 4358
[3] Tetrahedron Letters, 1994, vol. 35, # 36, p. 6627 - 6630
[4] Patent: US5194619, 1993, A

542-92-7
110-13-4
6974-97-6
Synthesis of 4,7-DIMETHYL-1H-INDENE from 1,3-Cyclopentadiene and 2,5-Hexanedione

4,7-DIMETHYL-1H-INDENE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4,7-DIMETHYL-1H-INDENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4,7-DIMETHYL-1H-INDENE pictures 2019-07-06 4,7-DIMETHYL-1H-INDENE
6974-97-6
US $1.00 / KG 1G 98% 100KG Career Henan Chemical Co
1H-Indene, 4,7-dimethyl- Nsc22051 4,7-Dimethylindene 4,7-DIMETHYL-1H-INDENE 3-pyridin-4-yl-1-propanethiol 6974-97-6 Indanone & Indene