ChemicalBook >> CAS DataBase List >>Piperonylic acid

Piperonylic acid

CAS No.
94-53-1
Chemical Name:
Piperonylic acid
Synonyms
Benzo[d][1,3]dioxole-5-carboxylic acid;Heliotropic acid;1,3-BENZODIOXOLE-5-CARBOXYLIC ACID;PIPEROYLICACID;3,4-(METHYLENEDIOXY)BENZOIC ACID;AKOS 213-90;Pepper acid;heliotropicacid;PIPERONYLIC ACID;PiperonylicAcid>
CBNumber:
CB7162666
Molecular Formula:
C8H6O4
Molecular Weight:
166.13
MDL Number:
MFCD00005830
MOL File:
94-53-1.mol
MSDS File:
SDS
Last updated:2023-12-04 17:50:15

Piperonylic acid Properties

Melting point 229-231 °C (lit.)
Boiling point 254.32°C (rough estimate)
Density 1.3579 (rough estimate)
refractive index 1.5090 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly), Methanol (Slightly)
form Powder
pka 4.35±0.20(Predicted)
color Off-white to beige
Water Solubility slightly soluble
Merck 14,7477
BRN 150206
LogP 0.810 (est)
CAS DataBase Reference 94-53-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII QX3V1NO0KH
NIST Chemistry Reference 1,3-Benzodioxole-5-carboxylic acid(94-53-1)
EPA Substance Registry System 1,3-Benzodioxole-5-carboxylic acid (94-53-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H315-H318-H335-H319
Precautionary statements  P264-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P280a-P304+P340-P405-P501a-P261-P280-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  22-37/38-41-36/37/38
Safety Statements  26-36/37/39-37/39
WGK Germany  3
RTECS  DF4912765
Hazard Note  Irritant
TSCA  Yes
HS Code  29329970
NFPA 704
0
2 0

Piperonylic acid price More Price(42)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich P49805 Piperonylic acid 99% 94-53-1 5g $59 2024-03-01 Buy
Sigma-Aldrich P49805 Piperonylic acid 99% 94-53-1 25g $98 2024-03-01 Buy
TCI Chemical P0459 Piperonylic Acid >98.0%(GC)(T) 94-53-1 25g $50 2024-03-01 Buy
Alfa Aesar A14105 Piperonylic acid, 98+% 94-53-1 25g $59.65 2024-03-01 Buy
Alfa Aesar A14105 Piperonylic acid, 98+% 94-53-1 100g $192 2024-03-01 Buy
Product number Packaging Price Buy
P49805 5g $59 Buy
P49805 25g $98 Buy
P0459 25g $50 Buy
A14105 25g $59.65 Buy
A14105 100g $192 Buy

Piperonylic acid Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Piperonylic Acid is a compound closely mimicking the structure of transcinnamic acid involved in the phenylpropanoid pathway in plant physiology.

Definition

ChEBI: Piperonylic acid is a member of the class of benzodioxoles that is 1,3-benzodioxole substituted by a carboxy group at position 5. It is a natural product isolated from several plant species. It is a selective mechanism-based inactivator of the trans-cinnamate 4-hydroxylase enzyme and exhibits antifungal and skin wound healing properties. It has a role as a plant metabolite, an EC 1.14.14.91 ( trans-cinnamate 4-monooxygenase) inhibitor, a vulnerary and an antifungal agent. It is a member of benzodioxoles, a monocarboxylic acid and an aromatic carboxylic acid. It is a conjugate acid of a piperonylate.

Synthesis Reference(s)

The Journal of Organic Chemistry, 40, p. 3803, 1975 DOI: 10.1021/jo00913a051

Purification Methods

Crystallise the acid from EtOH or water. [Beilstein 19/7 V 300.]

2635-13-4
124-38-9
94-53-1
Synthesis of Piperonylic acid from 4-Bromo-1,2-(methylenedioxy)benzene and Carbon dioxide
Global( 336)Suppliers
Supplier Tel Email Country ProdList Advantage
ZHEJIANG JIUZHOU CHEM CO., LTD
+86-0576225566889 +86-13454675544 admin@jiuzhou-chem.com;jamie@jiuzhou-chem.com;alice@jiuzhou-chem.com China 20000 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5988 58
Nanjing Deda New Material Technology Co., Ltd
+8613223293093 bella@njdeda.com China 76 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Jinan Finer Chemical Co., Ltd
+86-531-88989536 +86-15508631887 sales@finerchem.com China 2967 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58

View Lastest Price from Piperonylic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Piperonylic acid pictures 2024-03-28 Piperonylic acid
94-53-1
US $0.00 / Kg/Drum 1KG 99% 200mt/year Jinan Finer Chemical Co., Ltd
Piperonylic Acid  pictures 2024-03-28 Piperonylic Acid
94-53-1
US $10.00-5.00 / kg 1kg 99.5 10 ton per month Nanjing Deda New Material Technology Co., Ltd
Heliotropic acid;5-benzodioxolecarboxylicacid pictures 2024-01-18 Heliotropic acid;5-benzodioxolecarboxylicacid
94-53-1
US $15.00 / KG 1KG 99% large quantity Xiamen Wonderful Bio Technology Co., Ltd.
  • Piperonylic Acid  pictures
  • Piperonylic Acid
    94-53-1
  • US $10.00-5.00 / kg
  • 99.5
  • Nanjing Deda New Material Technology Co., Ltd
3,4-METHYLENDIOXYBENZOIC ACID RARECHEM AL BO 0210 3,4-(methylenedioxy)benzoic acid, piperonylic acid Piperonylic acid, 98+% 3,4-Methylendioxybenzoic acid 98% AKOS 213-90 β(3,4-methylenedioxy-styryl)acrylic acid 5-carboxy-2H-1,3-benzodioxol-5-iuM 1,3-Benzodioxole-5-carboxylic acid 98% 3,4-(Methylendioxy)benzoic acid, Piperonylic acid 1,3-Benzodioxole-5-carboxylic acid, 3,4-(Methylenedioxy)benzoic acid Piperonylic acid ,99% 3,4-Methylenebisoxybenzoic acid 2-phenyl-2H-1,3-dioxole-4-carboxylic acid Piperonylic acid,1,3-Benzodioxole-5-carboxylic acid, 3,4-(Methylenedioxy)benzoic acid TIMTEC-BB SBB003897 5-benzodioxolecarboxylicacid Benzoic acid, 3,4-(methylenedioxy)- heliotropicacid Protocatechuic acid methylene ether 3,4-dioxymethylenebenzoicacid PROTOCATECHUIC ACID METHYLENETHER 5-Carboxy-1,3-benzodioxole, 3,4-(Methylendioxy)benzoic acid, Piperonylic acid Piperonylic acid 99% PIPERONYLIC ACID PiperonylicAcid> Tadalafil Impurity 90 1,3-BENZODIOXOLE-5-CARBOXYLIC ACID 3,4-(METHYLENEDIOXY)BENZOIC ACID PIPEROYLICACID Benzo[d][1,3]dioxole-5-carboxylic acid Heliotropic acid Pepper acid 94-53-1 94-53-11 OCH2OC6H3COOH CH2O2C6H3COOH C8H6O4 CH2O2C6H3CHCHCHCHCOOH Carboxylic Acids Carbonyl Compounds C8 Building Blocks Organic Building Blocks Building Blocks C8 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Benzodiozoles, Benzodioxines & Benzodioxepines Carboxylic Acids Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Benzodiozoles, Benzodioxines & Benzodioxepines Carboxylic Acids Quinoxalines ,Quinazolines ,Quinaldines