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Aniline

CAS No. 62-53-3
Chemical Name: Aniline
Synonyms: Anilin;Anyvim;Kyanol;Anilina;blueoil;ci76000;ANILINE;Benzidam;Blue Oil;ai3-03053
CBNumber: CB7169544
Molecular Formula: C6H7N
Formula Weight: 93.13
MOL File: 62-53-3.mol
Aniline Property
Melting point : -6.2 °C
Boiling point : 184 °C(lit.)
density : 1.022 g/mL at 25 °C(lit.)
vapor density : 3.22 (185 °C, vs air)
vapor pressure : 0.7 mm Hg ( 25 °C)
refractive index : n20/D 1.586(lit.)
Fp : 76 °C
storage temp. : 2-8°C
solubility : water: soluble
form : Liquid
pka: 4.63(at 25℃)
color : APHA: ≤250
Relative polarity: 0.42
PH: 8.8 (36g/l, H2O, 20℃)
explosive limit: 1.2-11%(V)
Water Solubility : 36 g/L (20 ºC)
Merck : 14,659
BRN : 605631
Stability:: Stable. Incompatible with oxidizing agents, bases, acids, iron and iron salts, zinc, aluminium. Light sensitive. Combustible.
CAS DataBase Reference: 62-53-3(CAS DataBase Reference)
NIST Chemistry Reference: Aniline(62-53-3)
EPA Substance Registry System: Benzenamine(62-53-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : T,N,F
Risk Statements : 23/24/25-40-41-43-48/23/24/25-50-68-48/20/21/22-39/23/24/25-11
Safety Statements : 26-27-36/37/39-45-46-61-63-36/37-16
RIDADR : UN 1547 6.1/PG 2
WGK Germany : 2
RTECS : BW6650000
F : 8-9
TSCA : Yes
HazardClass : 6.1
PackingGroup : II
Hazardous Substances Data: 62-53-3(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P391 Collect spillage. Hazardous to the aquatic environment
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Aniline Chemical Properties,Usage,Production

Chemical Properties
colourless liquid
Definition
ChEBI: A primary arylamine in which an amino functional group is substituted for one of the benzene hydrogens.
General Description
A yellowish to brownish oily liquid with a musty fishy odor. Melting point -6°C; boiling point 184°C; flash point 158°F. Denser than water (8.5 lb / gal) and slightly soluble in water. Vapors heavier than air. Toxic by skin absorption and inhalation. Produces toxic oxides of nitrogen during combustion. Used to manufacture other chemicals, especially dyes, photographic chemicals, agricultural chemicals and others.
Air & Water Reactions
Darkens on exposure to air and light. Polymerizes slowly to a resinous mass on exposure to air and light. Slightly soluble in water.
Reactivity Profile
Aniline is a heat sensitive base. Combines with acids to form salts. Dissolves alkali metals or alkaline earth metals with evolution of hydrogen. Incompatible with albumin, solutions of iron, zinc and aluminum, and acids. Couples readily with phenols and aromatic amines. Easily acylated and alkylated. Corrosive to copper and copper alloys. Can react vigorously with oxidizing materials (including perchloric acid, fuming nitric acid, sodium peroxide and ozone). Reacts violently with BCl3. Mixtures with toluene diisocyanate may ignite. Undergoes explosive reactions with benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, peroxodisulfuric acid and tetranitromethane. Violent reactions may occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane (293° F), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HNO3 + N2O4 + H2SO4), (nitrobenzene + glycerin), oleum, (HCHO + HClO4), perchromates, K2O2, beta-propiolactone, AgClO4, Na2O2, H2SO4, trichloromelamine, acids, FO3Cl, diisopropyl peroxy-dicarbonate, n-haloimides and trichloronitromethane. Ignites on contact with sodium peroxide + water. Forms heat or shock sensitive explosive mixtures with anilinium chloride (detonates at 464° F/7.6 bar), nitromethane, hydrogen peroxide, 1-chloro-2,3-epoxypropane and peroxomonosulfuric acid. Reacts with perchloryl fluoride form explosive products. .
Health Hazard
Aniline is classified as very toxic. Probable oral lethal dose in humans is 50-500 mg/kg for a 150 lb. person. Aniline poisoning is characterized by methemoglobin formation in the blood and resulting cyanosis or blue skin. The formation of methemoglobin interferes with the oxygen-carrying capacity of the blood. The approximate minimum lethal dose for a 150 lb. human is 10 grams. Serious poisoning may result from ingestion of 0.25 mL. People at special risk include individuals with glucose-6-phosphate-dehydrogenase deficiency and those with liver and kidney disorders, blood diseases, or a history of alcoholism.
Fire Hazard
Combustion can produce toxic fumes including nitrogen oxides and carbon monoxide. Aniline vapor forms explosive mixtures with air. Aniline is incompatible with strong oxidizers and strong acids and a number of other materials. Avoid heating. Hazardous polymerization may occur. Polymerizes to a resinous mass.
Aniline Preparation Products And Raw materials
Raw materials
Nitrogen Iron oxide Benzene Hydrogen Nitric acid Nitrobenzene
Preparation Products
N-PHENYLISONICOTINAMIDE Modified MDI 2-Anilinoethanol Butyl 2-[[3-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-hydroxy-1-naphthyl]azo]benzoate Acid Black 234 Direct Dark Brown NM Direct Bordeaux NGB Aniline hydrochloride N,N'-Diphenylurea 2,4,6-Trichloroaniline Pigment Red 175 Poly(1,2-dihydro-2,2,4-trimethylquinoline) UREA, N-(2,6-DIMETHYLPHENYL)-N'-[IMINO(METHYLAMINO)METHYL]- N-Phenyl-1-naphthylamine REACTIVE VIOLET 5 2-CHLOROMALONALDEHYDE 3-Hydroxydiphenylamine Acid Black 26 4-N-DECYLANILINE N,N-Bis(cyanoethyl)aniline Direct Orange S LANASOLBLUE3R SOLVENT BLACK 5 3-BROMOPYRIDINE-2-CARBOXYLIC ACID Dicyclohexylamine Acid Yellow 79 Disperse Scarlet S-3GFL 4-HYDROXY-2-(TRIFLUOROMETHYL)QUINOLINE N,N-Diphenyl-p-phenylenediamine Reactive Blue 222 Direct Green 89 N-(2-Naphthyl)aniline 4-bromo-2-(trifluoromethyl)quinoline 8-Anilino-1-naphthalenesulfonic acid Phenylhydrazine sulfate FLUORESCENT BRIGHTENER 28 2 BASIC ORANGE 2 Bronze Red sodium dibenzyl amine enzene sulfonate Sudan I
Aniline Suppliers      Global( 234)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
Shanghai Macklin Biochemical Co.,Ltd. 15221275939
021-51821727 shenlinxing@macklin.cn China 13254 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 25125 65
Creasyn Finechem(Tianjin) Co., Ltd. 86-22-83945878,83945171,83945172
4008266163-06019 export@creasyn.com sale@creasyn.com China 1006 68
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96831 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40403 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30314 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 sales@tcishanghai.com.cn China 22833 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 1443 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44197 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 sales@ouhechem.com China 10816 60
 
62-53-3(Aniline)Related Search:
Benzidine Diphenylamine 2-(3-METHOXYPROPOXY)-5-(TRIFLUOROMETHYL)ANILINE n,n-dimethyl-p-(3’-methylphenylazo)-anili 2-Anisidine-4-sulfonic acid 2,4-DIFLUORO-N-(2,2,-DIMETHYLPROPANOYL)ANILIN m-Aminobenzene arsonic acid 2-(3-METHYLPHENOXY)-5-(TRIFLUOROMETHYL)ANILINE 3-Ethoxyaniline 2-(2-MORPHOLIN-4-YLETHOXY)ANILIN n-dichloromethylene-anili 3,5-Bis(trifluoromethyl)aniline N,N-Bis(trifluoromethylsulfonyl)aniline N-(4-CHLORO-PHENYL)-OXALAMIC ACID ETHYL ESTER 4-Bromo-N,N-dimethylaniline N-METHYL-N-PHENYLCARBAMOYL CHLORIDE Diphenylcarbamyl chloride 2-Chloro-N-[4-chloro-2-(2-chlorobenzoyl)phenyl]acetamide
ai3-03053 amino-benzen Aminophen Anilin anilin(czech) Anilina anilina(italian,polish) Aniline reagent aniline(andhomologs) Aniline(benzenamine) aniline15 anilineandhomologues Anyvim arylamine benzamine Benzene, amino- benzene,amino Benzidam Blue Oil blueoil C.I. 76000 C.I. Oxidation base 1 c.i.76000 c.i.oxidationbase1 caswellno051c ci76000 cioxidationbase1 epapesticidechemicalcode251400 Huile D'aniline huiled’aniline huiled’aniline(french) Krystallin Kyanol ncic03736 NCI-C03736 Rcra waste number U012 rcrawastenumberu012 BENZENEAMINE BENZENAMINE ANILINE OIL ANILINE 62-53-3 AKOS BBS-00003680 AMINOBENZENE C2 to C6 AM to AQ Analytical Standards Building Blocks Amines Analytical Chromatography Product Catalog Alphabetic Organic Building Blocks Nitrogen Compounds PHENYLAMINE Aniline;Aminobenzene; Phenylamine L-Aniline ANILINE EXTRA PURE ANILINE, STANDARD FOR GC
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