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Allylboronic acid pinacol ester

CAS No.
72824-04-5
Chemical Name:
Allylboronic acid pinacol ester
Synonyms
2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane;AKOS BRN-1082;PINACOL ALLYLBORONATE;Allyl pinacol boronate;Pinacolyl 2-propenylboronate;Allylboronic acid pinacolate;Allylboronic acid picol ester;ALLYLBORONIC ACID PINACOL ESTER;Allylboronic acid piracol ester
CBNumber:
CB7169827
Molecular Formula:
C9H17BO2
Molecular Weight:
168.04
MDL Number:
MFCD00013347
MOL File:
72824-04-5.mol
MSDS File:
SDS
Last updated:2024-04-08 16:27:35

Allylboronic acid pinacol ester Properties

Boiling point 50-53 °C/5 mmHg (lit.)
Density 0.896 g/mL at 25 °C (lit.)
refractive index n20/D 1.4268(lit.)
Flash point 115 °F
storage temp. 2-8°C
solubility Chloroform, Methanol (Slightly)
form Liquid
color Clear colorless
Water Solubility Not miscible or difficult to mix in water.
BRN 4244068
CAS DataBase Reference 72824-04-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210-P233-P240-P241-P242-P243
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  26-36
RIDADR  UN 1993 3/PG 3
WGK Germany  3
Hazard Note  Irritant
HazardClass  3
PackingGroup  III
HS Code  29310095
NFPA 704
2
2 1

Allylboronic acid pinacol ester price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 324647 Allylboronic acid pinacol ester 97% 72824-04-5 1g $50.1 2024-03-01 Buy
Sigma-Aldrich 324647 Allylboronic acid pinacol ester 97% 72824-04-5 10g $308 2024-03-01 Buy
TCI Chemical A2157 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >96.0%(GC) 72824-04-5 1g $41 2024-03-01 Buy
TCI Chemical A2157 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >96.0%(GC) 72824-04-5 5g $115 2024-03-01 Buy
Alfa Aesar L16232 Allylboronic acid pinacol ester, 98+% 72824-04-5 1g $37.65 2024-03-01 Buy
Product number Packaging Price Buy
324647 1g $50.1 Buy
324647 10g $308 Buy
A2157 1g $41 Buy
A2157 5g $115 Buy
L16232 1g $37.65 Buy

Allylboronic acid pinacol ester Chemical Properties,Uses,Production

Chemical Properties

Clear corless liquid

Uses

Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .

Uses

Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.

Global( 235)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20293 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29798 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18629 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32836 60
Shanghai Arbor Chemical Co., Ltd.
021-60451682 act@arborchemical.com CHINA 906 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc.
+1-858-6993322 info@accelachem.com United States 19536 58
Changzhou Ditong Chemical Co.,Ltd
+86-0519-88299272 info@edengenechem.com China 2169 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58

View Lastest Price from Allylboronic acid pinacol ester manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Allylboronic acid pinacol ester pictures 2024-04-08 Allylboronic acid pinacol ester
72824-04-5
US $34.00-1.20 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Allylboronic acid pinacol ester pictures 2021-07-13 Allylboronic acid pinacol ester
72824-04-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Allylboronic acid pinacol ester pictures 2021-07-10 Allylboronic acid pinacol ester
72824-04-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Allylboronic acid pinacol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Allylboronic acid pinacol ester 97% 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane Allyl pinacol boronate Pinacolyl 2-propenylboronate 2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Allylboronic acid pinacol ester, 98% 1GR Allylboronic acid pinacol ester(stabilized with Phenothiazine) 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAB 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propen-1-yl)- (2-Propen-1-yl)-boronic acid pinacol ester Allyl pinacol boronate Pinacolyl 2-propenylboronate 3-Hydroxy-2,3-dimethylbutan-2-yl hydrogen allylboronate Allylboronic acid picol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane for synthesis PINACOL ALLYLBORONATE ALLYLBORONIC ACID, PINACOL CYCLIC ESTER ALLYLBORONIC ACID PINACOL ESTER AKOS BRN-1082 ALLBORONIC ACID,PINACOL CYCLIC ESTER Allylboronic acid piracol ester Allylboronic acid pinacolate Allylboronic acid pinacol ester, 98+% 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Pinacol allylboronate 4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)> 4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 72824-04-5 CH34C2O2BCH2CHCH2 Boronate Esters Boronic Acids and Derivatives Alkyl Organometallic Reagents Alkyl Boronate Esters Boronate Esters Boronic Acids and Derivatives Chemical Synthesis Organometallic Reagents Olefin Organoborons B (Classes of Boron Compounds) Boronic Acids Esters CHIRAL CHEMICALS