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Methyl bromoacetate

Methyl bromoacetate
Methyl bromoacetate
CAS No.
96-32-2
Chemical Name:
Methyl bromoacetate
Synonyms
BAM;Methyl bomoacetate;BROMO METHYLACETATE;METHYL BROMOACETATE;METHYL 2-BROMOACETATE;2-BROMOMETHYL ACETATE;BroMine Methyl acetate;methylmonobromoacetate;Methyl broMoacetate 97%;Methyl monobromoacetate
CBNumber:
CB7171783
Molecular Formula:
C3H5BrO2
Formula Weight:
152.97
MOL File:
96-32-2.mol

Methyl bromoacetate Properties

Melting point:
-50°C
Boiling point:
51-52 °C15 mm Hg(lit.)
Density 
1.616 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.458(lit.)
Flash point:
145 °F
storage temp. 
Store at R.T.
form 
Liquid
color 
Clear colorless to slightly yellow
Water Solubility 
Miscible with methanol, ether and acetone. Slightly miscible with water
FreezingPoint 
<-50℃
BRN 
506256
CAS DataBase Reference
96-32-2(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, methyl ester(96-32-2)
EPA Substance Registry System
Acetic acid, bromo-, methyl ester(96-32-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,Xi,F
Risk Statements  25-34-37-23/24/25-40-36/37/38-38
Safety Statements  26-36/37/39-45-28A-36-16
RIDADR  UN 2643 6.1/PG 2
WGK Germany  3
RTECS  AF6300000
19
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29159080
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

Methyl bromoacetate price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 157910 Methyl bromoacetate 97% 96-32-2 25g $24.6 2018-11-13 Buy
Sigma-Aldrich 157910 Methyl bromoacetate 97% 96-32-2 100g $77.6 2018-11-13 Buy
TCI Chemical B0533 Methyl Bromoacetate >98.0%(GC) 96-32-2 25g $17 2017-11-08 Buy
TCI Chemical B0533 Methyl Bromoacetate >98.0%(GC) 96-32-2 100g $50 2017-11-08 Buy
Alfa Aesar A10605 Methyl bromoacetate, 98+% 96-32-2 250g $94.8 2018-11-13 Buy

Methyl bromoacetate Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes

General Description

A colorless to straw-colored liquid with a sharp penetrating odor. Denser than water and soluble in water. Severly irritates skin and eyes. Toxic by ingestion and inhalation. Used to make vitamins and pharmaceuticals.

Air & Water Reactions

Highly flammable. Soluble in water.

Reactivity Profile

Methyl bromoacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Methyl bromoacetate Preparation Products And Raw materials

Raw materials

Preparation Products


Methyl bromoacetate Suppliers

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