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D(+)-Carvone

CAS No.
2244-16-8
Chemical Name:
D(+)-Carvone
Synonyms
D-CARVONE;CARVOL;FEMA 2249;2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-, (5S)-;D-CAVONE;D-Cavrone;(+)-carvon;(+)-CARVONE;Carvone,98%;(+)-Carvone
CBNumber:
CB7178520
Molecular Formula:
C10H14O
Molecular Weight:
150.22
MDL Number:
MFCD00062997
MOL File:
2244-16-8.mol
MSDS File:
SDS
Last updated:2024-03-22 11:43:20

D(+)-Carvone Properties

Melting point 88.9°C
alpha 57 º (c=neat)
Boiling point 96-98 °C/10 mmHg (lit.)
Density 0.96 g/mL at 25 °C (lit.)
vapor pressure 20.665hPa at 25℃
FEMA 2249 | CARVONE
refractive index n20/D 1.499
Flash point 204 °F
storage temp. Store below +30°C.
solubility 1300mg/l
form Liquid
color Clear colorless to pale yellow
Odor at 100.00 %. spice mint bread caraway
Odor Type minty
Viscosity 24.7mm2/s
optical activity [α]23/D +55.0±7°, neat
Water Solubility <0.1 g/100 mL at 25 ºC
JECFA Number 380
Merck 14,1874
BRN 2042970
Dielectric constant 11.0(22℃)
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong reducing agents.
LogP 3.07 at 25℃
CAS DataBase Reference 2244-16-8(CAS DataBase Reference)
EWG's Food Scores 1-2
FDA UNII 4RWC1CMS3X
NIST Chemistry Reference 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-, (S)-(2244-16-8)
EPA Substance Registry System D-Carvone (2244-16-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317
Precautionary statements  P261-P272-P280-P302+P352-P333+P313-P362+P364
Hazard Codes  Xi
Risk Statements  22
Safety Statements  24/25
RIDADR  2810
WGK Germany  1
RTECS  OS8670000
8-9-23
Hazard Note  Irritant
TSCA  Yes
HazardClass  6.1(a)
PackingGroup  II
HS Code  29142900
Toxicity LD50 oral in rat: 3710uL/kg
NFPA 704
1
2 0

D(+)-Carvone price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W224928 D-Carvone ≥96%, FG 2244-16-8 100g $76.5 2024-03-01 Buy
Sigma-Aldrich W224928 D-Carvone ≥96%, FG 2244-16-8 1kg $204 2024-03-01 Buy
Sigma-Aldrich W224928 D-Carvone ≥96%, FG 2244-16-8 5kg $711 2024-03-01 Buy
Sigma-Aldrich 8.18410 (S)-(+)-Carvone for synthesis 2244-16-8 25mL $64.9 2024-03-01 Buy
Sigma-Aldrich 22070 (+)-Carvone analytical standard 2244-16-8 1ml $41 2024-03-01 Buy
Product number Packaging Price Buy
W224928 100g $76.5 Buy
W224928 1kg $204 Buy
W224928 5kg $711 Buy
8.18410 25mL $64.9 Buy
22070 1ml $41 Buy

D(+)-Carvone Chemical Properties,Uses,Production

Description

Carvone is a pale yellow to white clear liquid.Molecular weight=150.22; Boiling point=230℃; Flashpoint=93℃. Hazard Identification (based on NFPA 704 MRating System): Health 2, Flammability 2, Reactivity 0.

Chemical Properties

colourless or pale yellow liquid

Chemical Properties

Caravone occurs in different forms. l-Carvone exhibits odor of spearmint, while d-carvone exhibits odor reminiscent of caraway.

Chemical Properties

Carvone is a pale yellow to white clear liquid.

Occurrence

The optically active and inactive forms have been reported among the constituents of about 70 essential oils. The dextro form is present in carvi, Antheum graveolens, Antheum sowa, Lippia carviodora, Mentha arvensis, etc. The levo form is present in Metha vifidis var. crispa, Mentha longifolia from South Africa, Eucalyptus globules and several mint species. The racemic form is present in ginger grass, Litsea gutalemaleusis, lavender and Artemisia ferganensis. Reported found in citrus oil and juice (lemon, lime, orange), celery seed, anise, clove, coriander seed, calamus, caraway herb and dill seed.

Uses

(S)-(+)-Carvone can be used as a starting material to synthesize:

  • (-)-Samaderine Y, a pentacyclic quassinoid.
  • (-)-Ambrox, a terpenoid responsible for the odor of ambergris.
  • 3β-Acetoxydrimenin (a sesquiterpene) via conjugated addition of potassium cyanide followed by base catalyzed Robinson annulation reaction.
  • Thapsigargin family members such as trilobolide, nortrilobolide, and thapsivillosin F.

Definition

ChEBI: A carvone having (S) configuration.

Aroma threshold values

Detection: d-Carvone: 6.7 to 820 ppb; l-carvone: 2.7 to 600 ppb

General Description

Pale yellow or colorless liquid.

Air & Water Reactions

May be sensitive to prolonged exposure to light and air. Insoluble in water.

Reactivity Profile

D(+)-Carvone may be sensitive to prolonged exposure to light and air. Incompatible with strong oxidizing agents and strong reducing agents

Fire Hazard

D(+)-Carvone is combustible.

Flammability and Explosibility

Not classified

Safety Profile

Poison by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.

Synthesis

Carvone occurs in the dextro, levo and racemic form; l-carvone can be isolated from the essential oil of spearmint or is commercially synthesized from d-limonene; d-carvone is usually prepared by fractional distillation of oil of caraway, also from dillseed and dillweed oils, but this type differs in odor and flavors.

Potential Exposure

Carvone is found in various natural oils, including caraway and dillseed; mandarin peel and spearmint oils. A food additive, it is used in flavoring liqueurs; in perfumes and soaps.

First aid

Skin Contact: Flood all areas of body that have contacted the substance with water. Do not wait to remove contaminated clothing; do it under the water stream. Use soap tohelp assure removal. Isolate contaminated clothing whenremoved to prevent contact by others. Eye Contact: Removeany contact lenses at once. Flush eyes well with copious quantities of water or normal saline for at least 20-30 min. Seekmedical attention. Inhalation: Leave contaminated area immediately; breathe fresh air. Proper respiratory protection must besupplied to all rescuers. If coughing, difficult breathing, or anyother symptoms develop, seek medical attention at once, evenif symptoms develop many hours after exposure. Ingestion: Ifconvulsions are not present, give a glass or two of water ormilk to dilute the substance. Assure that the person’s airway isunobstructed and contact a hospital or poison center immediately for advice on whether or not to induce vomiting.

storage

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Store in a cool, dry place or in a refrigerator

Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

D(+)-Carvone Preparation Products And Raw materials

Global( 285)Suppliers
Supplier Tel Email Country ProdList Advantage
airuikechemical co., ltd.
+undefined86-15315557071 15315557071@163.com China 630 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
Shanghai Zheyan Biotech Co., Ltd.
18017610038 zheyansh@163.com CHINA 3620 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5909 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Shanghai Standard Technology Co., Ltd.
18502101150 ft-sales@nature-standard.com CHINA 1923 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58

View Lastest Price from D(+)-Carvone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
d( )-carvOne pictures 2024-03-23 d( )-carvOne
2244-16-8
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
D-Carvone pictures 2023-05-26 D-Carvone
2244-16-8
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
(S)-(+)-Carvone pictures 2023-02-24 (S)-(+)-Carvone
2244-16-8
US $0.00 / ml 0.1ml GC≥98% 100 ml Shanghai Standard Technology Co., Ltd.
  • d( )-carvOne pictures
  • d( )-carvOne
    2244-16-8
  • US $0.00-0.00 / Kg
  • 99.9%
  • airuikechemical co., ltd.
  • D-Carvone pictures
  • D-Carvone
    2244-16-8
  • US $5.00-2.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co,.LTD
  • (S)-(+)-Carvone pictures
  • (S)-(+)-Carvone
    2244-16-8
  • US $0.00 / ml
  • GC≥98%
  • Shanghai Standard Technology Co., Ltd.
D-6,8(9)-P-MENTHADIEN-2-ONE d-1-methyl-4-isopropenyl-6-cyclohexen-2-one D-p-Mentha-6,8,(9)-dien-2-one (+)-CARVONE CARVONE, (+)- ALPHA(+)-CARVONE D-CARVONE 96+% (+)-CARVONE, TERPENE STANDARD D(+)-Carvone, natural, 98% D(+)-Carvone, synthetic, 98% (+)-carvone,(+)-(4S)-2-methyl-5-(1-methylethenyl)-2-cyclohexen-1-one,(+)-(4S)-carvol,D-carvone (5S)-2-methyl-5-prop-1-en-2-yl-cyclohex-2-en-1-one Carvone,98% (S)-2-methyl-5-(1-methylvinyl)cyclohex-2-en-1-one DEXTRO-CARVONE (S)-2-Methyl-5-(1-methylvinyl)cyclohex-2-en-1-on CARVON-RECHTS 2-Cyclohexen-1-one,2-methy (S)-2-Cyclohexen-1-one-2-methyl-5-(1-methylethenyl) 6,8-p-menthadiene-2-one (S)-(+)-CARVONE 99+% (+)-Carvone, (S)-(+)-Carvone, (S)-5-Isopropenyl-2-methyl-2-cyclohexenone, p-Mentha-6,8-dien-2-one (+)-carvon (s)-(+)-p-mentha-8-dien-2-one (s)-2-cyclohexen-1-on (s)-d-p-mentha-6,8,(9)-dien-2-one 2-methyl-5-(1-methylethenyl)-,(S)-2-Cyclohexen-1-one p-Mentha-6,8-dien-2-one, (S)-(+)- (S)-(+)-5-ISOPROPENYL-2-METHYL-2-CYCLOHEXANONE (S)-5-ISOPROPENYL-2-METHYL-2-CYCLOHEXENONE (S)-(+)-P-MENTHA-6,8-DIEN-2-ONE (S)-(+)-CARVONE D-CAVONE D(+)-CARVONE (+)-Carvone, (S)-5-Isopropenyl-2-methyl-2-cyclohexenone, p-Mentha-6,8-dien-2-one D-Cavrone D(+)-Carvone, 98%, natural D(+)-Carvone, 98%, synthetic D(+)-Carvone, 96%, natural D(+)-Carvone, synthetic, 98% 25ML (S)-(+)-CARVONE FOR SYNTHESIS (S)-2-Methyl-5-(prop-1-en-2-yl)cyclohex-2-enone (S)-(+)-Carvone 96% (5S)-2-methyl-5-(1-methylethenyl)-1-cyclohex-2-enone d-CARVONE (SYNTHETIC) FCC CARVOL,(+)-CARVONE,CARVONE (S)-(+)-Carvone,96% (S)-(+)-Carvone > D(+)-Carvone USP/EP/BP 2244-16-8 D(+)-Carvone 2-Methyl-4-(1 -methylethenyl)-2-cyclohexene-1 -one (+)-Carvone CARVOL 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-, (5S)- FEMA 2249 D-CARVONE 2244-16-8 Organic Building Blocks