METHYL 3-OXOTETRADECANOATE
- CAS No.
- 22348-97-6
- Chemical Name:
- METHYL 3-OXOTETRADECANOATE
- Synonyms
- Orlistat Impurity 61;Metyl lauroyl acetate;Methyl β-KetoMyristate;Methyl b-ketomyristate;Methyl Lauroyl Acetate;METHYL 3-OXOTETRADECANOATE;METHYL 3-KETOTETRADECANOATE;3-Oxomyristic acid methyl ester;3-Ketomyristic acid methyl ester;3-Oxotetradecanoic acid methyl ester
- CBNumber:
- CB7187955
- Molecular Formula:
- C15H28O3
- Molecular Weight:
- 256.38
- MDL Number:
- MFCD00673474
- MOL File:
- 22348-97-6.mol
- MSDS File:
- SDS
| Melting point | 29-30°C |
|---|---|
| Boiling point | 137-139 °C(Press: 0.9 Torr) |
| Density | 0.926±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,2-8°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly) |
| form | Solid |
| pka | 10.65±0.46(Predicted) |
| color | Light Yellow to Yellow |
| LogP | 5.500 (est) |
| FDA UNII | 5JZD9UC56Q |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H413 |
| Precautionary statements | P264-P270-P301+P312-P330-P501 |
METHYL 3-OXOTETRADECANOATE price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | M325865 | Methyl3-Oxotetradecanoate | 22348-97-6 | 500mg | $130 | 2021-12-16 | Buy |
| Matrix Scientific | 089325 | Methyl 3-oxotetradecanoate | 22348-97-6 | 1g | $151 | 2021-12-16 | Buy |
| Matrix Scientific | 089325 | Methyl 3-oxotetradecanoate | 22348-97-6 | 5g | $670 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0067306 | METHYL 3-OXOTETRADECANOATE 95.00% | 22348-97-6 | 1G | $739.2 | 2021-12-16 | Buy |
| AK Scientific | Q506 | Methyl3-Oxotetradecanoate | 22348-97-6 | 5g | $873 | 2021-12-16 | Buy |
METHYL 3-OXOTETRADECANOATE Chemical Properties,Uses,Production
Synthesis
The carboxylic acid (13.8 g, 69 mmol, 1.0 equivalents) was dissolved in dry THF under an inert atmosphere and cooled to 0 ºC. CDI (13.4 g, 83 mmol, 1.2 equivalents) was then added in small portions over several minutes. After 10 min, the reaction was allowed to warm slowly to room temperature and was then stirred for 1 h. In a separate flflask, monomethyl malonate (9.8g, 83 mmol, 1.2 equivalents) was dissolved in THF under an inert atmosphere and cooled to −78 ºC. To this solution was added dibutylmagnesium (1.0 M in heptane, 0.6 equivalents). A white solid formed instantly on addition of the base. After 10 min, the reaction was warmed to room temperature and stirred for 1 h. The acylimidazole was then added by cannula to the flflask containing the magnesium salt. The resulting slurry was stirred for 3 days. The reaction mixture was then concentrated on a rotary evaporator and the residue redissolved in EtOAc. The resulting solution was washed with 1.2 M HCl, saturated aqueous NaHCO3, and brine. The organic phase was dried over sodium sulfate, fifiltered, concentrated, and the residue purifified by flflash chromatography (7:1 hexanes:EtOAc) to give the β-keto ester (14.7g, 83%).
Reference: Durham, T. B.; Miller, M. J. J. Org. Chem. 2003, 68, 27–34.
Chemical Properties
Yellow Crystalline Solid
Uses
Methyl 3-Oxotetradecanoate (cas# 22348-97-6) is a compound useful in organic synthesis.
METHYL 3-OXOTETRADECANOATE Preparation Products And Raw materials
METHYL 3-OXOTETRADECANOATE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10248 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 6992 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Finetech Industry Limited | +86-27-87465837 +8618971612321 | info@finetechnology-ind.com | China | 9702 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
| Nextpeptide Inc | +86-0571-81612335 +8613336028439 | sales@nextpeptide.com | China | 19915 | 58 |
| Alfa Chemistry | +1-5166625404 | Info@alfa-chemistry.com | United States | 21317 | 58 |
| Coresyn Pharmatech Co., Ltd. | +86-571-86626709 +86-18157142896 | cbc@coresyn.com | China | 9991 | 58 |
| ZHEJIANG JIUZHOU CHEM CO., LTD | +86-0576225566889 +86-13454675544 | admin@jiuzhou-chem.com；jamie@jiuzhou-chem.com；alice@jiuzhou-chem.com | China | 20000 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49999 | 58 |
View Lastest Price from METHYL 3-OXOTETRADECANOATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-12-25 | METHYL 3-OXOTETRADECANOATE
22348-97-6
|
US $1.00 / KG | 1KG | 98%HPLC | 10t | Career Henan Chemical Co |
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- METHYL 3-OXOTETRADECANOATE
22348-97-6
- US $1.00 / KG
- 98%HPLC
- Career Henan Chemical Co