ChemicalBook >> CAS DataBase List >>(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE structure

CAS No.: 158923-09-2

Chemical Name:: (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

Synonyms: OSIPHOS SL-J004-1;JOSIPHOS SL-J004-1;(R)1[(1S)2(di-C-hex;(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&;(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET;(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin;R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphe...;(R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine;(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE

CBNumber:: CB7211931

Molecular Formula:: C36H44FeP210*

Molecular Weight:: 594.53

MDL Number:: MFCD00800280

MOL File:: 158923-09-2.mol

Last updated:2023-04-23 13:52:06

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(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Properties

alpha	-100° ±5° (c 0.5, CHCl3)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	orange

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P280-P301+P312-P302+P352-P305+P351+P338
Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
F	10
HS Code	29319090

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE price More Price(26)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	88723	(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine ≥97%	158923-09-2	100mg	$96.8	2024-03-01	Buy
Sigma-Aldrich	88723	(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine ≥97%	158923-09-2	1g	$727	2024-03-01	Buy
Strem Chemicals	26-1230	(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97%	158923-09-2	100mg	$107	2024-03-01	Buy
Strem Chemicals	26-1230	(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine, min. 97%	158923-09-2	500mg	$375	2024-03-01	Buy
Sigma-Aldrich	88723	(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine ≥97%	158923-09-2	500mg	$442	2023-06-20	Buy

Product number	Packaging	Price	Buy
88723	100mg	$96.8	Buy
88723	1g	$727	Buy
26-1230	100mg	$107	Buy
26-1230	500mg	$375	Buy
88723	500mg	$442	Buy

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Chemical Properties,Uses,Production

Chemical Properties

Red crystal

Uses

(R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

To prepare iridium metal complex (Ir^IJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

Reactions

1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .
Reactions of 158923-09-2

General Description

sold in collaboration with Solvias AG

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Suppliers

Global( 62)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	378	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4242	58
AFINE CHEMICALS LIMITED	0571-85134551	info@afinechem.com	CHINA	15377	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418684 +8618949823763	sales@tnjchem.com	China	25363	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58
PT CHEM GROUP LIMITED	+86-85511178 +86-85511178	peter68@ptchemgroup.com	China	35453	58
GIHI CHEMICALS CO.,LIMITED	+8618058761490	info@gihichemicals.com	China	49999	58
Shaoxin Catsyn Co., Ltd.	+undefined-0575-82040869 +86-0575-82040869;	sales@catsyn.com	China	6116	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76

Supplier	Advantage
XINXIANG RUNYU MATERIAL CO., LTD.	58
Changzhou Ansciep Chemical Co., Ltd.	58
AFINE CHEMICALS LIMITED	58
Dayang Chem (Hangzhou) Co.,Ltd.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Hangzhou MolCore BioPharmatech Co.,Ltd.	58
PT CHEM GROUP LIMITED	58
GIHI CHEMICALS CO.,LIMITED	58
Shaoxin Catsyn Co., Ltd.	58
J & K SCIENTIFIC LTD.	76

158923-09-2((R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE)Related Search:

ETHYLDIPHENYLPHOSPHINE (S)-1-[(1R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE 1,3-BIS(DIMETHYLPHOSPHINO)PROPANE DICYCLOHEXYLPHOSPHINE

1,3-BIS(PHOSPHINO)PROPANE TRIISOPROPYLPHOSPHINE TRIHEXYLPHOSPHINE

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(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN& (R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97% (r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas) (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97% (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine Josiphos SL-J004-1, (1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS) (R)1[(1S)2(di-C-hex (S)-(-)-l-[(S)-2-( Dicyclohexylphosphino)ferroceny1] ethyldicyclohexylphosphino JOSIPHOS SL-J004-1 OSIPHOS SL-J004-1 (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ET (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine >=97% (R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE (R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin Ferrocene, 1-(dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]-, (1R)- (R)-1-[(R)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphe... 158923-09-2 C36H44FeP2 C31H39P2C5H5Fe Solvias Ligands Privileged Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Chiral Phosphine Ferrocene Series Josiphos Series organophosphine ligand