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9-Fluorenylmethyl chloroformate

9-Fluorenylmethyl chloroformate
9-Fluorenylmethyl chloroformate structure
CAS No.
28920-43-6
Chemical Name:
9-Fluorenylmethyl chloroformate
Synonyms
FMOC-C;EMOCCI;FMOC-C1;FoMc-Cl;FMOC-CL;fmoc-ci;AminoTag;9-Fluoroe;FMOC-CHLORIDE;Fmoc-Clsee22072
CBNumber:
CB7234569
Molecular Formula:
C15H11ClO2
Formula Weight:
258.7
MOL File:
28920-43-6.mol

9-Fluorenylmethyl chloroformate Properties

Melting point:
62-64 °C(lit.)
Boiling point:
365.79°C (rough estimate)
Density 
1.1780 (rough estimate)
refractive index 
1.5330 (estimate)
storage temp. 
2-8°C
solubility 
dioxane: 0.1 g/mL, clear, colorless
form 
Crystalline Powder
color 
White to very pale yellow
Sensitive 
Moisture Sensitive
BRN 
2279177
CAS DataBase Reference
28920-43-6(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05,GHS07
Signal word  Danger
Hazard statements  H314-H290-H302+H312+H332-H302-H318-H332
Precautionary statements  P260h-P301+P330+P331-P303+P361+P353-P501a-P234-P260-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501-P280-P305+P351+P338-P310
Hazard Codes  C,T
Risk Statements  34-20/21/22
Safety Statements  26-36/37/39-45-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
RTECS  LQ6250000
10-21
TSCA  No
HazardClass  6.1
PackingGroup  II
HS Code  29159020

9-Fluorenylmethyl chloroformate price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 160512 Fmoc chloride 97% 28920-43-6 1g $20.7 2018-11-20 Buy
Sigma-Aldrich 160512 Fmoc chloride 97% 28920-43-6 5g $63.5 2018-11-20 Buy
TCI Chemical F0197 9-Fluorenylmethyl Chloroformate [N-Protecting Agent for Peptides Research] >97.0%(HPLC)(T) 28920-43-6 5g $49 2018-11-22 Buy
TCI Chemical F0197 9-Fluorenylmethyl Chloroformate [N-Protecting Agent for Peptides Research] >97.0%(HPLC)(T) 28920-43-6 25g $167 2018-11-22 Buy
Alfa Aesar A11683 9-Fluorenylmethyl chloroformate, 98+% 28920-43-6 1g $17.5 2018-11-13 Buy

9-Fluorenylmethyl chloroformate Chemical Properties,Uses,Production

Chemical Properties

White to off white crystalline powder

Uses

9-Fluorenylmethyl chloroformate is an N-Protecting agent for peptides research and was used for the pre-column derivatization of the biogenic amines (BAs) cadaverine (Cad), histamine (Him), octopami ne (Ocp), phenylethylamine (Pea), putrescine (Put), spermidine (Spd), spermine (Spm), tyramine (Tym).

Uses

9-Fluorenylmethyl chloroformate can be used as N-protecting reagent for oligonucleotide and peptide syntheses.

Uses

9-Fluorenylmethyl chloroformate can act as reagent for the introduction of Fmoc-amino-protecting group, which is stable towards acids but is readily cleaved under mildly basic non-hydrolytic conditions.

Safety Profile

A poison. Mutation data reported. A corrosive. When heated to decomposition it emits toxic vapors of Cl-.

Purification Methods

If the IR contains no OH bands (at ~3000 cm-1) due to the hydrolysis product 9-fluorenylmethanol, then purify it by recrystallisation from dry Et2O. IR (CHCl3) has a band at 1770 cm-1 (C=O), and the NMR (CDCl3) has  at 4-4.6 (m 2H, CHCH2) and 7.1-7.8 (m, 8 aromatic H) ppm. The azide (FMOC-N3) has m 89-90o (from -1hexane) and IR (CHCl3) at 2135 (N3) and 1730 (C=O) cm , and the carbazate (FMOC-NHNH2) has m 171o(dec) (from nitromethane), IR (KBr) 3310, 3202 (NH) and 1686 (CONH) cm-1. [Caprino & Han J Org Chem 37, 3404 1972 , J Am Chem Soc 92 5748 1970, Koole et al. J Org Chem 59 1657 1989, Fürst et al. J Chromatogr 499 537 1990.]

9-Fluorenylmethyl chloroformate Preparation Products And Raw materials

Raw materials

Preparation Products


9-Fluorenylmethyl chloroformate Suppliers

Global( 344)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19918 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21701 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20672 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 24191 60
Shanghai Zheyan Biotech Co., Ltd.
18017610038
zheyansh@163.com CHINA 3623 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29979 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293
+86 0531-67809011 sales@sdzschem.com CHINA 2995 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23978 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 8922 58

View Lastest Price from 9-Fluorenylmethyl chloroformate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-16 9-Fluorenylmethyl chloroformate
28920-43-6
US $7.00 / kg 1kg 99% 100KG career henan chemical co

9-Fluorenylmethyl chloroformate Spectrum


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