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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE

CAS No.
18388-03-9
Chemical Name:
2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE
Synonyms
2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE;2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE;2-Methylene-3-chloropropyltrimethylsilane;2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE;2-(chloromethyl)prop-2-enyl-trimethylsilane;2-(Trimethylsilylmethyl)-3-chloro-1-propene;2-(Trimethylsilylmethyl)-2-propenyl chloride;[2-(Chloromethyl)-2-propenyl]trimethylsilane;Silane, [2-(chloromethyl)-2-propen-1-yl]trimethyl-;2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride
CBNumber:
CB7243343
Molecular Formula:
C7H15ClSi
Molecular Weight:
162.73
MDL Number:
MFCD00013253
MOL File:
18388-03-9.mol
MSDS File:
SDS
Last updated:2023-05-15 10:44:01

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Properties

Boiling point 162-163 °C/768 mmHg (lit.)
Density 0.899 g/mL at 25 °C (lit.)
refractive index n20/D 1.453(lit.)
Flash point 110 °F
storage temp. 2-8°C
solubility Chloroform, Methanol (Slightly)
form Oil
color Clear Colourless
Specific Gravity 0.899
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 1747038
Stability Moisture Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P233-P240-P241-P303+P361+P353-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  26-36
RIDADR  UN 1993 3/PG 3
WGK Germany  3
TSCA  No
HazardClass  3.2
PackingGroup  III

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 318345 2-(Chloromethyl)allyl-trimethylsilane 97% 18388-03-9 1g $116 2024-03-01 Buy
Sigma-Aldrich 318345 2-(Chloromethyl)allyl-trimethylsilane 97% 18388-03-9 5g $414 2024-03-01 Buy
TRC C371430 2-​(Chloromethyl)​allyl-​trimethylsilane 18388-03-9 500mg $95 2021-12-16 Buy
Arctom SY248950 [2-(Chloromethyl)allyl]trimethylsilane ≥97% 18388-03-9 1g $1350 2021-12-16 Buy
AHH MT-05953 2-Chloromethyl-3-trimethylsilyl-1-propene 97% 18388-03-9 10g $318 2021-12-16 Buy
Product number Packaging Price Buy
318345 1g $116 Buy
318345 5g $414 Buy
C371430 500mg $95 Buy
SY248950 1g $1350 Buy
MT-05953 10g $318 Buy

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Chemical Properties,Uses,Production

Uses

2-??(Chloromethyl)??allyl-??trimethylsilane is one of the reagents to synthesize Leucasandrolide A Macrolide (I) via Mukaiyama aldol coupling.2-??(Chloromethyl)??allyl-??trimethylsilane was used in catalytic Sakurai reaction of a,??b-??enones.

2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-CHLOROMETHYL-3-TRIMETHYLSILYL-1-PROPENE 2-(CHLOROMETHYL)ALLYL-TRIMETHYLSILANE 2-(TRIMETHYLSILYLMETHYL)ALLYL CHLORIDE [2-(Chloromethyl)-2-propenyl]trimethylsilane 2-(Trimethylsilylmethyl)-2-propenyl chloride 2-(Trimethylsilylmethyl)-3-chloro-1-propene 2-Methylene-3-chloropropyltrimethylsilane 2-(Chloromethyl)-3-trimethylsilyl-1-propene, 2-(Trimethylsilylmethyl)allyl chloride Silane, [2-(chloromethyl)-2-propen-1-yl]trimethyl- 2-(chloromethyl)prop-2-enyl-trimethylsilane 18388-03-9 CH33SiCH2CCH2ClCH2 C7H15ClSi Alkenyl Halogenated Hydrocarbons Organic Building Blocks Building Blocks