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ChemicalBook >> CAS DataBase List >>(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Structure
(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin structure
CAS No.
1169835-86-2
Chemical Name:
(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin
Synonyms
(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin;(3aS,8aS)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin;1,3-Dioxolo[4,5-e][1,3,2]dioxaphosphepin, 4,4,8,8-tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-, (3aS,8aS)-
CBNumber:
CB72709575
Molecular Formula:
C45H49O4P
Molecular Weight:
684.84
MDL Number:
MFCD23705048
MOL File:
1169835-86-2.mol
Last updated:2023-04-23 13:52:06
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(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Properties

Boiling point 717.8±60.0 °C(Predicted)
form solid
color off-white

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-1512 (3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin 1169835-86-2 100mg $79 2024-03-01 Buy
Strem Chemicals 15-1512 (3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin 1169835-86-2 500mg $319 2024-03-01 Buy
Ambeed A714406 (3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin 98% 1169835-86-2 250mg $150 2021-12-16 Buy
Arctom AS643153 (3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin 98% 1169835-86-2 100mg $66 2021-12-16 Buy
BLDpharm BD635922 (3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin 98% 1169835-86-2 100mg $79 2021-12-16 Buy
Product number Packaging Price Buy
15-1512 100mg $79 Buy
15-1512 500mg $319 Buy
A714406 250mg $150 Buy
AS643153 100mg $66 Buy
BD635922 100mg $79 Buy

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Chemical Properties,Uses,Production

Reaction

  1. Chiral ligand used in the nickel-catalyzed, enantioselective, conjugate allylation of activated enones.
  2. Chiral ligand used in the platinum-catalyzed, asymmetric, 1,4-dihydroxylation of 1,3-dienes via catalytic enantioselective diboration.
  3. Chiral ligand used in the platinum-catalyzed, asymmetric addition of B2(pin)2 to N-silyl imines for the synthesis of α-amino boronates.
  4. Asymmetric 1,4-dihydroxylation of 1,3-dienes by catalytic enantioselective diboration.
Reactions of 1169835-86-2

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Preparation Products And Raw materials

Raw materials

Preparation Products

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin Suppliers

Global( 22)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94837 76
Beijing HwrkChemical Technology Co., Ltd 0757-86329057 18501085097 sales3.gd@hwrkchemical.com China 7639 55
Adamas Reagent, Ltd. 400-6009262 16621234537 zhangsn@titansci.com China 14113 59
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 6943 65
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 3021 50
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Domole Scientific 13275595566 domole.infsci@outlook.com China 507 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5751 58
Supplier Advantage
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
Beijing HwrkChemical Technology Co., Ltd 55
Adamas Reagent, Ltd. 59
Daicel Chiral Technologies (China)CO.,LTD 65
Tianjin Derchemist Science & Technology Co., Ltd. 50
Bide Pharmatech Ltd. 60
LaaJoo 58
Domole Scientific 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-diMethylphenyl)tetrahydro-2,2-diMethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin (3aS,8aS)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin 1,3-Dioxolo[4,5-e][1,3,2]dioxaphosphepin, 4,4,8,8-tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-, (3aS,8aS)- 1169835-86-2 Chiral Phosphine TADDOL Phos