2'-Iodoacetophenone
- CAS No.
- 2142-70-3
- Chemical Name:
- 2'-Iodoacetophenone
- Synonyms
- 1-(2-Iodophenyl)ethan-1-one;2-IODOACETOPHENONE;1-(2-iodophenyl)ethanone;2-iodophenone;O-IODOACETOPHENONE;2'-IODOACETOPHENONE;2'-Iodoacetophenone;2'-Iodoacetophenone>2''-IODOACETOPHENONE 97%;2'-IODOACETOPHENONE, 99+%
- CBNumber:
- CB7291551
- Molecular Formula:
- C8H7IO
- Molecular Weight:
- 246.05
- MDL Number:
- MFCD00094998
- MOL File:
- 2142-70-3.mol
- MSDS File:
- SDS
| Boiling point | 139-140°C 12mm |
|---|---|
| Density | 1.72 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 218 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | Liquid |
| Specific Gravity | 1.720 |
| color | Clear yellow |
| Sensitive | Light Sensitive |
| BRN | 2325078 |
| CAS DataBase Reference | 2142-70-3(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P280a-P305+P351+P338-P321-P332+P313-P337+P313-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 36/38 | |||||||||
| Safety Statements | 26-36-24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29147000 | |||||||||
| NFPA 704 |
|
2'-Iodoacetophenone price More Price(37)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 540676 | 2′-Iodoacetophenone 97% | 2142-70-3 | 1g | $30.4 | 2023-01-07 | Buy |
| TCI Chemical | I0689 | 2'-Iodoacetophenone >98.0%(GC) | 2142-70-3 | 1g | $16 | 2024-03-01 | Buy |
| TCI Chemical | I0689 | 2'-Iodoacetophenone >98.0%(GC) | 2142-70-3 | 5g | $40 | 2024-03-01 | Buy |
| Alfa Aesar | B25345 | 2'-Iodoacetophenone, 98+% | 2142-70-3 | 1g | $32.65 | 2024-03-01 | Buy |
| Alfa Aesar | B25345 | 2'-Iodoacetophenone, 98+% | 2142-70-3 | 5g | $99.65 | 2024-03-01 | Buy |
2'-Iodoacetophenone Chemical Properties,Uses,Production
Chemical Properties
Clear yellow liquid
Uses
2′-Iodoacetophenone (2-Iodoacetophenone) may be used in the synthesis of:
indene derivatives
di-(o-acetylphenyl)acetylene
indenol derivative
Preparation
2'-Iodoacetophenone can be synthesized by diazotization of 2-acetylaniline.
To a solution of p-TsOH (22.80 g, 120 mmol) in CH3CN (160 mL) was added an aromatic amine (40 mmol). The resulting amine salt suspension was cooled to 0-5°C. A solution of NaNO2 (5.52 g, 80 mmol) in H2O (12 mL) and KI (16.6 g, 100 mmol) in H2O (12 mL) were added sequentially. The reaction mixture was stirred for 10 minutes, then allowed to warm to ambient temperature and stirred until all the amine was consumed. To the reaction mixture were then added H2O (700 mL), NaHCO3 (1M; until pH=9-10) and Na2S2O3 (2M, 80 mL). The reaction mixture was extracted with EtOAc and purified by column chromatography (hexanes:EtOAc, 9:1 v/v) to give 2'-iodoacetophenone:yellow oil in 94% yield.
Reactions
2'-Iodoacetophenone is a bioactive molecule that reacts with boronic acids to form aryl boronic acid derivatives. This reaction can be carried out in chlorobenzene or dihedral solvents, and it is scalable and applicable to a variety of boronic acids. The product of this reaction is an organocatalyst for the synthesis of bioactive molecules. 2'-Iodoacetophenone also reacts with dipole-containing additives to form dichlorodiphenyldichloroethane, which has been used as a fungicide, insecticide, and herbicide.
General Description
2′-Iodoacetophenone is a halogenated aromatic ketone.
2'-Iodoacetophenone Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Nanjing Fred Technology Co., Ltd. | +86-02584696168 15380713688 | Austin@fredchem.cn | CHINA | 865 | 58 |
| WinWin Chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 13854 | 58 |
| Wuxi Rejoys chemical Technology Co., Ltd. | 0510-86103381 | sales@rejoyschem.com | CHINA | 976 | 58 |
| Finetech Industry Limited | +86-27-87465837 +8618971612321 | info@finetechnology-ind.com | China | 9702 | 58 |
View Lastest Price from 2'-Iodoacetophenone manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-09-03 | 2'-Iodoacetophenone
2142-70-3
|
US $7.00 / KG | 1KG | 99% | JD 793 | Career Henan Chemical Co |
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- 2'-Iodoacetophenone
2142-70-3
- US $7.00 / KG
- 99%
- Career Henan Chemical Co