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DIETHYL (CHLOROMETHYL)PHOSPHONATE

CAS No.
3167-63-3
Chemical Name:
DIETHYL (CHLOROMETHYL)PHOSPHONATE
Synonyms
NSC 67753;Diethyl (chloromethyl);DIETHYL (CHLOROMETHYL)PHOSPHONATE;[DIETHYL-(CHLORMETHYL)]-PHOSPHONAT;Diethyl chloromethylphosphonate 97%;Diethyl (chloromethyl)phosphonate,98%;Diethyl (Chloromethyl)phosphonate >Diethyl(chloromethyl)phosphonate, 97 %;(chloromethyl)-phosphonicacidiethylester;1-[chloromethyl(ethoxy)phosphoryl]oxyethane
CBNumber:
CB7297881
Molecular Formula:
C5H12ClO3P
Molecular Weight:
186.57
MDL Number:
MFCD00010189
MOL File:
3167-63-3.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:38

DIETHYL (CHLOROMETHYL)PHOSPHONATE Properties

Boiling point 109-110 °C10 mm Hg(lit.)
Density 1.2 g/mL at 25 °C(lit.)
refractive index n20/D 1.437(lit.)
Flash point 188 °F
storage temp. 2-8°C
form Liquid
Specific Gravity 1.2
color Clear colorless to light yellow
BRN 1363361
FDA UNII H3LYK2K3U6
EPA Substance Registry System Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  29319090
NFPA 704
1
1 0

DIETHYL (CHLOROMETHYL)PHOSPHONATE price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 263613 Diethyl chloromethylphosphonate 97% 3167-63-3 1ml $124 2023-06-20 Buy
TCI Chemical D4588 Diethyl (Chloromethyl)phosphonate >98.0%(GC) 3167-63-3 1g $120 2024-03-01 Buy
TCI Chemical D4588 Diethyl (Chloromethyl)phosphonate >98.0%(GC) 3167-63-3 5g $400 2024-03-01 Buy
TRC D444128 Diethyl (Chloromethyl)phosphonate 3167-63-3 50mg $45 2021-12-16 Buy
TRC D444128 Diethyl (Chloromethyl)phosphonate 3167-63-3 500mg $90 2021-12-16 Buy
Product number Packaging Price Buy
263613 1ml $124 Buy
D4588 1g $120 Buy
D4588 5g $400 Buy
D444128 50mg $45 Buy
D444128 500mg $90 Buy

DIETHYL (CHLOROMETHYL)PHOSPHONATE Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to light yellow liquid

Uses

Reactant involved in:

  • Subsequent alkylation after nucleophilic substitution
  • One-pot alkylation-boration of α-haloalkylphosphonates
  • Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
  • Phosphorylation leading to P-containing cyclopropanes
  • Wadsworth-Emmons reactions
  • Ring expansion of zircnacycles via carbenoid insertion

Synthesis Reference(s)

Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1

DIETHYL (CHLOROMETHYL)PHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 132)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
Zhejiang ZETian Fine Chemicals Co. LTD
18957127338 stella@zetchem.com China 2141 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12468 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58
Alfa Chemistry
info@alfa-chemistry.com United States 2344 58
Aston Chemical
13000000000 sales@astonchem.com United States 1634 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58

View Lastest Price from DIETHYL (CHLOROMETHYL)PHOSPHONATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
DIETHYL (CHLOROMETHYL)PHOSPHONATE pictures 2020-01-13 DIETHYL (CHLOROMETHYL)PHOSPHONATE
3167-63-3
US $1.00 / g 1g 99.0% 100kg Career Henan Chemical Co
(chloromethyl)-phosphonicacidiethylester DIETHYL (CHLOROMETHYL)PHOSPHONATE [DIETHYL-(CHLORMETHYL)]-PHOSPHONAT Diethyl(chloromethyl)phosphonate, 97 % (Chloromethyl)phosphonic acid diethyl ester Diethyl (chloromethyl)phosphonate,98% NSC 67753 Diethyl chloromethylphosphonate 97% Diethyl (chloromethyl) 1-[chloromethyl(ethoxy)phosphoryl]oxyethane Phosphonic acid P -(chloromethyl)-diethyl ester Diethyl (Chloromethyl)phosphonate > 3167-63-3 C5H12ClO3P ClCH2POOC2H52 C-C Bond Formation Olefination Synthetic Reagents Horner-Wadsworth-Emmons Reagents C-C Bond Formation Horner-Wadsworth-Emmons Reagents Olefination