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Hexazinone

Chemical Properties Uses Mechanism of action Toxicity Preparation method
Hexazinone
Hexazinone structure
CAS No.
51235-04-2
Chemical Name:
Hexazinone
Synonyms
VELPAR;dpx3674;velpark;velparl;DPX 3674;gridball;Hexazinon;Hexazinoe;sha107201;DPX-A3674
CBNumber:
CB7319547
Molecular Formula:
C12H20N4O2
Formula Weight:
252.31
MOL File:
51235-04-2.mol

Hexazinone Properties

Melting point:
97-100.5°
Boiling point:
395.49°C (rough estimate)
Density 
1.2500
refractive index 
1.6120 (estimate)
Flash point:
11℃
storage temp. 
APPROX 4°C
pka
2.05±0.70(Predicted)
form 
Powder
color 
Beige
Water Solubility 
33g/L(25 ºC)
BRN 
618801
CAS DataBase Reference
51235-04-2(CAS DataBase Reference)
EWG's Food Scores
2
FDA UNII
Y51727MR1Y
NIST Chemistry Reference
1,3,5-Triazine-2,4(1h,3h)-dione, 3-cyclohexyl-6-(dimethylamino)-1-methyl-(51235-04-2)
EPA Substance Registry System
Hexazinone (51235-04-2)
Pesticides: Freedom of Information Act (FOIA)
Hexazinone
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS06,GHS08,GHS07,GHS09
Signal word  Danger
Hazard statements  H225-H301-H311-H331-H370-H302-H319-H410
Precautionary statements  P210-P260-P280-P301+P310-P311-P273-P305+P351+P338-P501
Hazard Codes  Xn,N,T,F
Risk Statements  22-36-50/53-39/23/24/25-23/24/25-11
Safety Statements  60-61-45-36/37-16-7
RIDADR  UN3077 9/PG 3
WGK Germany  3
RTECS  XY7850000
HS Code  29336990
Toxicity LD50 orally in rats: 1690 mg/kg (Neary)

Hexazinone price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 36129 Hexazinone PESTANAL 51235-04-2 100mg $63 2021-03-22 Buy
TCI Chemical H1686 Hexazinone >98.0%(HPLC)(T) 51235-04-2 5g $71 2021-03-22 Buy
TCI Chemical H1686 Hexazinone >98.0%(HPLC)(T) 51235-04-2 25g $213 2021-03-22 Buy

Hexazinone Chemical Properties,Uses,Production

Chemical Properties

The pure product is white crystalline solid. m.p.115~117℃. Vapour pressure is 2.7×10-3Pa (25℃)、8.5×10-3Pa (86℃). Relative density is 1.25. The solubility at 25 ℃: 3880g/kg in chloroform, 2650g/kg in methanol, 836g/kg in dimethylformamide,790g/kg in acetone, 940g/kg in benzene, 386g/kg in toluene, 3g/kg in hexane and 33g/kg in water. In the water solution with pH value of 5~9, it is stable at normal temperature and will be decomposed by microbes in the soil.

Uses

Post bud contact killing herbicide and the inhibitor of photosynthesis in plants. Its weed killing spectrum and killing shrub spectrum are wide, and its toxicity is strong and effective. It is used for tending young forests of evergreen coniferous forests, such as Pinus koraiensis, Pinus sylvestris, Picea spruce, Pinus massoniana and so on. Before the afforestation, it is applied to weeding and extinguishing irrigation, maintaining and opening forest fire prevention and forest soil improvement etc...It can also be used for weeding and irrigation on both sides of the oil depot, airport and road. It can prevent green bristlegrass, filipendula palmate, angelica dahurica,sedge, herba elsholtziae, reed, deyeuxia angustifolia, fern, clematis, veronica spuria, cephalanoplos segetum, wild oats, quinoa, millet, etc.. The woody plants it can can control include yellow lonicera japonica, pearl, hazel wood, spiraea salicifolia, acanthopanax senticosus, acanthopanax, winged elm, aspen, birch, quercus mongolica, linden, oak, linden, ashtree, phellodendron amurense rupr, juglans mandshurica etc.. It can control annual weed and biennial weed. A dose of 2~5kg/hm2 control weeds for a short term. Most perennial weeds can be prevented by the dose of 6~12kg/hm2. Nonionic surfactants can be added to this product.

Mechanism of action

It mainly inhibits the photosynthesis of plants and causes the disordered generation of plants and causes death. Both plant root and leaf surface can absorb the cyclohexanone, which is transported mainly through the xylem. It has great mobility in the soil and can be decomposed by soil microbes after entering the soil. It has no harm to the root of the pine tree. 7 days after the weeds have been treated, the leaves will have necrosis until the whole leaf has withered. The whole process including the upper part above ground (about 2 weeks) and the rotting of the root lasts for 1 month. It will last for 1 month from the appearance of necrosison the new leaves to rotting roots of the shrubs lasts for about 2 months. The first defoliation of non - objective arbor takes place 20~30 days after the injury. In the future, the new born leaves will be molted again, repeating 3~5 times in a row. From the spot to the formation of shrub leaf rot lasted for about 2 months. The upper part of the ground dies in 60~120 days. The roots rot in the fall of second.

Toxicity

The drug is of toxicity when acute oral LD50 is 1690mg/kg in rats, acute percutaneous is LD50>5278mg/kg in rabbits, acute transdermal is LD50>2000mg/kg in rats. It has a stimulating effect on the eyes of rabbits. The accumulative coefficient K value is >5, which belongs to the mild accumulative pesticide.There is no teratogenic, carcinogenic and mutagenic effects on animals within the range of experiments. No abnormality is found in the three generation reproduction test and neurotoxicity test. The non-cation dose for two years of feeding test: 200mg/kg for rats,LC50388mg/L for rainbow trout, LD50>5000mg/kg for quail, LD50>10000mg/kg for wild duck and, LC5060μg for per bee.

Preparation method

Uses

Herbicide.

Uses

Hexazinone is a triazine compound used as a preemergence or postemergence herbicide to control many annual grasses and broad-leaved weeds in noncropped land and certain crops such as alfalfa, blueberries, coffee, pecans and sugarcane

Production Methods

Hexazinone is a postemergence contact herbicide effective against many annual and biennial weeds and, except for Johnson grass, most perennial weeds. Human contact is likely at the use stage, and dermal contact and inhalation are of most concern.

General Description

White crystalline solid. Corrosive eye irritant. Used as an herbicide.

Air & Water Reactions

Water soluble. Rapidly decomposed in solution by strong acids and bases.

Reactivity Profile

A triazine.

Carcinogenicity

No carcinogenicity was detected among pups of rats fed up to 5000 ppm for 2 years. Similarly, no increase in tumors was produced by feeding up to 10,000 ppm hexazinone to mice.

Environmental Fate

Soil/Plant. Biodegrades in soil and natural waters releasing carbon dioxide. The reported half-life in soil is 1 to 6 months (Hartley and Kidd, 1987). Rhodes (1980a) found that the persistence of hexazinone varied from 4 weeks in a Delaware sandy loam to 24 weeks in a Mississippi silt loam.
Hexazinone is subject to microbial degradation (Rhodes, 1980a; Feng, 1987). Metabolites identified in soils, alfalfa and/or sugarcane include 3-(4-hydroxycyclohexyl)-6(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione, 3-cyclohexyl-6-(methylamino)-1
Feng (1987) monitored the persistence and degradation of hexazinone in a silt loam soil 104 days after treatment of the herbicide. After 104 days, 66% of the hexazinone degraded via hydroxylation to form the major metabolite 3-(4-hydroxycyclohexyl)-6(dime
No traces of hexazinone or its metabolites were detected on treated blueberries (Jenson and Kimball, 1985).
Photolytic. Photodegradation products identified in aqueous hexazinone solutions following exposure to UV light (λ = 300–400 nm) were 3-(4-hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione, 3-cyclohexyl-6-(methylamino)

Metabolic pathway

In clay and sand soils, hexazinone is metabolized by hydroxylation at the 4-position of the cyclohexane ring and mono-N-demethylation to give [3-(4- hydroxycyclohexyl)-6-(dimethylamino)-1-methyl-1,3,5- triazine-2,4-(1H,3H )-dione], and [3-cyclohexyl-6- (methylamino)-1-methyl-1,3,5-triazine-2,4-(1H,3H )- dione, respectively. N-Demethylated metabolite is found in a comparatively higher percentage than the hydroxylated metabolite in both clay and sand soils.

Hexazinone Preparation Products And Raw materials

Raw materials

Preparation Products


Hexazinone Suppliers

Global( 161)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 20911 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com CHINA 47498 58
career henan chemical co
13203830695 0086-371-86658258
0086-371-86658258 factory@coreychem.com CHINA 29864 58
SIMAGCHEM CORP
13806087780 +86 13806087780
shaobowang@simagchem.com CHINA 17505 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
0551-65418697 sales@tnjchem.com CHINA 37441 58
Alfa Chemistry
+15166625404
1-516-927-0118 inquiry@alfa-chemistry.com United States 10563 58
Mainchem Co., Ltd. +86-0592-6210733
+86-0592-6210733 sale@mainchem.com CHINA 32439 55

View Lastest Price from Hexazinone manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2020-01-10 Hexazinone
51235-04-2
US $1.00 / g 1g 99.0% 100kg Career Henan Chemical Co

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