ChemicalBook >> CAS DataBase List >>5-Bromo-2-methylpyridine

5-Bromo-2-methylpyridine

5-Bromo-2-methylpyridine structure

CAS No.: 3430-13-5

Chemical Name:: 5-Bromo-2-methylpyridine

Synonyms: 5-BROMO-2-PICOLINE;5-BROMOPICOLINE;3-BROMO-6-PICOLINE;2-Methyl-5-bromopyrid;5-Bromo-2-picoline,99%;5-BROMO-2-METHYLPYRIDINE;3-BROMO-6-METHYLPYRIDINE;2-METHYL-5-BROMOPYRIDINE;5-broMo-1-Methylpyridine;5-bormo-2-methylpyridine

CBNumber:: CB7327298

Molecular Formula:: C6H6BrN

Molecular Weight:: 172.02

MDL Number:: MFCD00661170

MOL File:: 3430-13-5.mol

MSDS File:: SDS

Last updated:2024-04-08 17:36:13

Request For Quotation

5-Bromo-2-methylpyridine Properties

Melting point	32-36 °C
Boiling point	74 °C / 17mmHg
Density	1.494±0.06 g/cm3(Predicted)
storage temp.	Inert atmosphere,Room Temperature
solubility	Chloroform (Slightly), Ethyl Acetate (Slightly)
form	Solid
pka	3.59±0.10(Predicted)
color	Off-White to Light Yellow
BRN	107324
InChI	InChI=1S/C6H6BrN/c1-5-2-3-6(7)4-8-5/h2-4H,1H3
InChIKey	OFKWIQJLYCKDNY-UHFFFAOYSA-N
SMILES	C1(C)=NC=C(Br)C=C1
CAS DataBase Reference	3430-13-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07,GHS06

Signal word

Warning

Hazard statements

H315-H319-H335-H301-H311-H332

Precautionary statements

P261-P305+P351+P338-P301+P310a-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Hazard Codes

Xi,Xn

Risk Statements

36/37/38-20/21/22

Safety Statements

26-36-36/37/39

WGK Germany

HazardClass

IRRITANT

HS Code

29333990

NFPA 704

	1
2		0

5-Bromo-2-methylpyridine price More Price(31)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	B2572	5-Bromo-2-methylpyridine >98.0%(GC)	3430-13-5	1g	$19	2024-03-01	Buy
TCI Chemical	B2572	5-Bromo-2-methylpyridine >98.0%(GC)	3430-13-5	5g	$58	2024-03-01	Buy
Alfa Aesar	H27085	5-Bromo-2-methylpyridine, 98%	3430-13-5	250mg	$44.3	2023-06-20	Buy
Alfa Aesar	H27085	5-Bromo-2-methylpyridine, 98%	3430-13-5	1g	$84.4	2023-06-20	Buy
TRC	B685590	5-Bromo-2-picoline	3430-13-5	50g	$1390	2021-12-16	Buy

Product number	Packaging	Price	Buy
B2572	1g	$19	Buy
B2572	5g	$58	Buy
H27085	250mg	$44.3	Buy
H27085	1g	$84.4	Buy
B685590	50g	$1390	Buy

5-Bromo-2-methylpyridine Chemical Properties,Uses,Production

Description

It is an important intermediate in the organic synthesis, which has many applications, such as pharmaceutical intermediate, organic synthesis, organic solvent, production of dyes, pesticide, and spice. Specifically, this chemical can act as the raw material to prepare 2:2’-dipyridyl and its derivatives.¹ Moreover, this compound may be involved in the synthesis of biaryls through a one-pot tandem borylation/Suzuki-Miyaura cross-coupling reaction catalyzed by a palladacycle.² In addition, 5-bromo-2-methylpyridine has been demonstrated to function as the substrate in a general palladium-catalyzed coupling of aryl bromides/triflates and thiols.³ Besides, this substance can facilitate the synthesis of 5-arylamino-2-picolines via displacement of bromide by anthranilic acid and decarboxylation.⁴

Referrence

Willink, H. D. T.; Wibaut, J. P., The preparation of 2 : 2'-dipyridyl and some of its derivatives. Recueil Des Travaux Chimiques Des Pays-Bas 1935, 54, 275-283.
Wang, L. H.; Cui, X. L.; Li, J. Y.; Wu, Y. S.; Zhu, Z. W.; Wu, Y. J., Synthesis of Biaryls through a One-Pot Tandem Borylation/Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by a Palladacycle. Eur. J. Org. Chem. 2012, 595-603.
Itoh, T.; Mase, T., A general palladium-catalyzed coupling of aryl bromides/triflates and thiols. Org. Lett. 2004, 6, 4587-4590.
Louis H. Peterson; Tolman, R. L., Reinvestigation of the synthesis of 5-arylamino-2-picolines J. Heterocycl. Chem. 1977.

Chemical Properties

Light yellow Cryst

Uses

5-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds.

5-Bromo-2-methylpyridine synthesis

Synthesis of 5-Bromo-2-methylpyridine from 3-Hydroxy-6-methylpyridine

5-Bromo-2-methylpyridine Preparation Products And Raw materials

Raw materials

6-Methyl-3-pyridinecarbonyl azide Carbamic acid, (6-methyl-3-pyridinyl)-, ethyl ester (9CI) 2-methylpyridinium chloride 3-Bromo-2-methylpyridine ETHYL 6-METHYLPYRIDINE-3-CARBOXYLATE

3-Pyridinecarboxylicacid,6-methyl-,hydrazide(9CI) 5-CYANO-2-METHYLPYRIDINE 6-METHYLNICOTINAMIDE

1of2

Preparation Products

5-Bromo-2-hydroxymethylpyridine 5-BROMO-2-METHYLPYRIDINE N-OXIDE 4-AMINO-5-BROMO-2-METHYLPYRIDINE 5-Bromopyridine-2-carbaldehyde 6-Methylpyridine-3-boronic Acid

3-Bromo-2-cyano-6-methylpyridine 2-Methyl-5-vinylpyridine

1of2

5-Bromo-2-methylpyridine Suppliers

Global( 533)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Terma Medicare India Pvt.,Ltd	+8613916485955	shivshanghai@yahoo.com	India	132	58
Hebei Guanlang Biotechnology Co,.LTD	+8619930503252	daisy@crovellbio.com	China	5964	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7845	58
Frapp's ChemicalNFTZ Co., Ltd.	+86 (576) 8169-6106	sales@frappschem.com	China	885	50
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32480	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Zhejiang ZETian Fine Chemicals Co. LTD	18957127338	stella@zetchem.com	China	2141	58

Supplier	Advantage
Terma Medicare India Pvt.,Ltd	58
Hebei Guanlang Biotechnology Co,.LTD	58
Henan Fengda Chemical Co., Ltd	58
Frapp's ChemicalNFTZ Co., Ltd.	50
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Zhejiang ZETian Fine Chemicals Co. LTD	58

View Lastest Price from 5-Bromo-2-methylpyridine manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-08	5-Bromo-2-methylpyridine 3430-13-5	US $5.00-0.10 / KG	1KG	98%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-06-28	5-Bromo-2-methylpyridine 3430-13-5	US $9.00 / KG	1KG	99.9	1 ton	Hebei Guanlang Biotechnology Co,.LTD
2023-04-14	5-Bromo-2-methylpyridine 3430-13-5	US $10.00 / KG	1KG	99%	10 mt	Hebei Guanlang Biotechnology Co., Ltd.

5-Bromo-2-methylpyridine
3430-13-5
US $5.00-0.10 / KG
98%
Henan Fengda Chemical Co., Ltd

5-Bromo-2-methylpyridine
3430-13-5
US $9.00 / KG
99.9
Hebei Guanlang Biotechnology Co,.LTD

5-Bromo-2-methylpyridine
3430-13-5
US $10.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

5-Bromo-2-methylpyridine Spectrum

5-Bromo-2-methylpyridine(3430-13-5)¹HNMR

3430-13-5(5-Bromo-2-methylpyridine)Related Search:

5-Bromo-2-hydroxymethylpyridine 5-Bromo-2-methoxypyridine 5-BROMO-2-(METHYLTHIO)PYRIMIDINE 2-AMINO-3,5-DIBROMO-6-METHYLPYRIDINE 2,6-Dimethyl-3,5-dibromopyridine

5-Bromo-2-methylpyridine 3-Bromo-2,6-dimethylpyridine Methyl 6-bromonicotinate 5-bromo-2-pyridinecarboxylic acid ethyl ester 5-Bromo-2-pyridinecarbonitrile

6-AMINO-5-BROMO-2-PICOLINE 5-BROMO-2-METHYLPYRIDINE N-OXIDE 3,5-DIBROMO-2,4,6-TRIMETHYLPYRIDINE 2-CHLORO-3-BROMO-6-PICOLINE 2,5,6-Tribromo-3-methylpyridine

2-FLUORO-3-BROMO-6-PICOLINE 2,3-DIBROMO-6-PICOLINE 3-AMINO-2-BROMO-5-PICOLINE

1of4

5-broMo-1-Methylpyridine 5--2- MethylpyridinebroMide 2 - Methyl - 5 - broMide pyridine 2-METHYL-5-BROMOPYRIDINE 5-BROMOPICOLINE 3-BROMO-6-METHYLPYRIDINE 5-BROMO-2-METHYLPYRIDINE 3-BROMO-6-PICOLINE 5-Bromo-2-methylpyridine 98% Pyridine, 5-bromo-2-methyl- 2-METHYL-5-BROMOPYRIDINE 98.5%(MIN) 2-Methyl-5-bromopyrid 5-bormo-2-methylpyridine 5-Bromo-2-picoline,99% 2-Picoline, 5-bromo- (6CI,7CI,8CI) 5-Bromo-2-methylpyridine ,99% 5-BROMO-2-METHYLPYRIDINE (5-BROMO-2-PICOLINE) 5-BROMO-2-PICOLINE5-BROMO-2-METHYLPYRIDINE 5-BroMo-2-picoline, 99% 1GR 5-Bromo-2-methylpyridine > 5-Bromo-2-methylpyridine ISO 9001：2015 REACH 5-BROMO-2-PICOLINE 3430-13-5 3430-18-5 340-13-5 1074-98-7 Building Blocks Heterocyclic Building Blocks Bromopyridines Halopyridines Pyridines Halogenated Heterocycles Pyridines derivates Bromopyridines Halopyridines Pyridine series blocks Bromides Pyridines Pyridine Pyridines, Pyrimidines, Purines and Pteredines alkyl bromide Building Blocks C6 Chemical Synthesis Halogenated Heterocycles Heterocyclic Building Blocks 3430-13-5