CYCLOOCTENE
- CAS No.
- 931-87-3
- Chemical Name:
- CYCLOOCTENE
- Synonyms
- (Z)-cyclooctene;CYCLOOCTENE;1-Cyclooctene;(Z)-Cycloocten;(1Z)-Cyclooctene;Cyclooctene ,95%;Cyclooctene, (Z)-;(Z)-1-Cyclooctene;Cyclooctene, (1Z)-;cis-Cyclooctene,94%
- CBNumber:
- CB7340240
- Molecular Formula:
- C8H14
- Molecular Weight:
- 110.2
- MDL Number:
- MFCD00001753
- MOL File:
- 931-87-3.mol
- MSDS File:
- SDS
| Melting point | −16 °C(lit.) |
|---|---|
| Boiling point | 32-34 °C12 mm Hg(lit.) |
| Density | 0.848 g/mL at 20 °C(lit.) |
| vapor pressure | 9.9hPa at 20℃ |
| refractive index |
n |
| Flash point | 77 °F |
| storage temp. | Flammables area |
| solubility | H2O: insoluble |
| form | Liquid |
| color | Clear colorless to light brown |
| Viscosity | 2.22mm2/s |
| Water Solubility | Miscible with alcohol and ether. Immiscible with water. |
| Sensitive | Air Sensitive |
| BRN | 1280166 |
| LogP | 5 at 25℃ |
| CAS DataBase Reference | 931-87-3(CAS DataBase Reference) |
| FDA UNII | AE340T3540 |
| EPA Substance Registry System | Cyclooctene, (1Z)- (931-87-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H304-H401-H411-H226 | |||||||||
| Precautionary statements | P210-P280a-P301+P310a-P303+P361+P353-P405-P501a | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 10-65 | |||||||||
| Safety Statements | 29-33 | |||||||||
| RIDADR | UN 3295 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29021990 | |||||||||
| NFPA 704 |
|
CYCLOOCTENE price More Price(12)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 125482 | cis-Cyclooctene contains 100-200 ppm Irganox 1076 FD as antioxidant, 95% | 931-87-3 | 25ml | $55.9 | 2024-03-01 | Buy |
| Alfa Aesar | A13477 | cis-Cyclooctene, 95%, stab. | 931-87-3 | 50ml | $35.65 | 2024-03-01 | Buy |
| Alfa Aesar | A13477 | cis-Cyclooctene, 95%, stab. | 931-87-3 | 100ml | $42.65 | 2024-03-01 | Buy |
| Alfa Aesar | A13477 | cis-Cyclooctene, 95%, stab. | 931-87-3 | 250ml | $76.65 | 2024-03-01 | Buy |
| Alfa Aesar | A13477 | cis-Cyclooctene, 95%, stab. | 931-87-3 | 500ml | $156 | 2024-03-01 | Buy |
CYCLOOCTENE Chemical Properties,Uses,Production
Chemical Properties
clear colourless to light brown liquid
Uses
cis-Cyclooctene is used as a displaced ligand in chlorobis(cyclooctene)rhodium dimer and chlorobis(cyclooctene)iridium dimer in organometallic chemistry. It acts as a monomer used in synthetic chemistry. It is used to prepare 1-chloro-4-(trichloromethyl) cyclooctane by reaction with carbon tetrachloride using dichlorotris(triphenylphosphine) ruthenium(II) as a catalyst. Further, it is used to study the alkenes chemisorbed on silicon(100) by scanning tunneling microscopy.
Synthesis Reference(s)
Journal of the American Chemical Society, 102, p. 2693, 1980 DOI: 10.1021/ja00528a029
The Journal of Organic Chemistry, 40, p. 2555, 1975 DOI: 10.1021/jo00905a040
Tetrahedron Letters, 14, p. 2667, 1973
General Description
cis-Cyclooctene undergoes addition reaction with carbon tetrachloride catalyzed by dichlorotris(triphenylphosphine) ruthenium(II) to yield 1-chloro-4-(trichloromethyl) cyclooctane (1,4-adduct). It undergoes epoxidation catalyzed by molybdenum oxide nanoparticles incorporated in a mesoporous silica shell coated on dense silica-coated magnetite nanoparticles.
Purification Methods
The cis-isomer is freed from the trans-isomer by fractional distillation through a spinning-band column, followed by preparative gas chromatography on a Dowex 710-Chromosorb W GLC column. It is passed through a short alumina column immediately before use [Collman et al. J Am Chem Soc 108 2588 1986]. It has also been distilled in a dry N2 glove box from powdered fused NaOH through a Vigreux column (p 11), then passed through activated neutral alumina before use [Wong et al. J Am Chem Soc 109 4328 1987]. Alternatively it can be purified via the AgNO3 salt. This salt is obtained from crude cyclooctene (40 mL) by shaking at 70-80o with 50% w/w AgNO3 (2 x 15 mL) to remove cyclooctadienes (aqueous layer). Extraction is repeated at 40o (4 x 20 mL, of 50% AgNO3). Three layers are formed each time. The middle layer contains the AgNO3 adduct of cyclooctene which crystallises on cooling the layer to room temperature. The adduct (complex 2:1) is highly soluble in MeOH (at least 1g/mL) from which it crystallises in large flat needles when cooled at 0o. It is dried under slight vacuum for 1 week in the presence of CaCl2 and paraffin wax soaked in cyclooctene. It has m 51o and loses hydrocarbon on exposure to air. cis-Cyclooctene can be recovered by steam distillation of the salt, collected, dried (CaCl2) and distilled in vacuum. [Braude et al. J Chem Soc 4711 1957, AgNO3: Jones J Chem Soc 1808 1954, Cope & Estes J Am Chem Soc 72 1128 1950, Beilstein 5 I 35, 5 IV 263.] FLAMMABLE LIQUID.
CYCLOOCTENE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7845 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-18789408387 | 1057@dideu.com | China | 3537 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 15093356674; | laboratory@coreychem.com | China | 30255 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9320 | 58 |
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 9116 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43348 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33349 | 58 |
| Aladdin Scientific | +1-833-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
View Lastest Price from CYCLOOCTENE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-12-26 | CYCLOOCTENE
931-87-3
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2020-01-08 | cis-Cyclooctene, stabilized
931-87-3
|
US $1.00 / KG | 1KG | 99% | 20T | Shaanxi Dideu Medichem Co. Ltd |
-
- CYCLOOCTENE
931-87-3
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- cis-Cyclooctene, stabilized
931-87-3
- US $1.00 / KG
- 99%
- Shaanxi Dideu Medichem Co. Ltd
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