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Cuprous chloride

Cuprous chloride
Cuprous chloride structure
CAS No.
7758-89-6
Chemical Name:
Cuprous chloride
Synonyms
CuCl;Cu-lyt;Cuproid;Nantokite;chloridmedny;COPPER CHLORIDE;cooper chloride;Chlorocopper(I);CUPROUS CHLORIDE;cuprousdichloride
CBNumber:
CB7341838
Molecular Formula:
ClCu
Formula Weight:
99
MOL File:
7758-89-6.mol

Cuprous chloride Properties

Melting point:
430 °C(lit.)
Boiling point:
1490 °C(lit.)
Density 
1.15 g/mL at 20 °C
vapor pressure 
1.3 mm Hg ( 546 °C)
refractive index 
1.93
Flash point:
1490°C
storage temp. 
Store at +5°C to +30°C.
solubility 
0.06 g/L (25°C)
form 
beads
color 
Slightly greenish-gray
Specific Gravity
4.14
PH
5 (50g/l, H2O, 20℃)(slurry)
Water Solubility 
0.06 g/L (25 ºC)
Sensitive 
Air & Moisture Sensitive
Merck 
14,2660
Solubility Product Constant (Ksp)
pKsp: 6.76
Stability:
Stable. Incompatible with oxidizing agents, potassium, water. Air, light and moisture sensitive.
CAS DataBase Reference
7758-89-6(CAS DataBase Reference)
NIST Chemistry Reference
Cuprous monochloride(7758-89-6)
EPA Substance Registry System
Copper chloride (CuCl)(7758-89-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn,N
Risk Statements  22-50/53-51/53-36/37/38-41-37/38-38
Safety Statements  26-61-60-22-39
RIDADR  UN 3082 9/PG 3
WGK Germany  2
RTECS  GL6990000
1-8-10
TSCA  Yes
HS Code  2827 39 85
HazardClass  8
PackingGroup  III
Toxicity LD50 orally in Rabbit: 336 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P330 Rinse mouth.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P501 Dispose of contents/container to..…

Cuprous chloride price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 212946 Copper(I) chloride reagent grade, 97% 7758-89-6 25g $46.5 2018-11-13 Buy
Sigma-Aldrich 212946 Copper(I) chloride reagent grade, 97% 7758-89-6 2kg $189 2018-11-13 Buy
Alfa Aesar 011871 Copper(I) chloride, 97% 7758-89-6 2kg $113 2018-11-16 Buy
Alfa Aesar 011871 Copper(I) chloride, 97% 7758-89-6 100g $22.2 2018-11-16 Buy
Strem Chemicals 29-0360 Copper(I) chloride (99.99%-Cu) PURATREM 7758-89-6 10g $56 2018-11-13 Buy

Cuprous chloride Chemical Properties,Uses,Production

Chemical Properties

white or pale grey powder

Chemical Properties

Copper chloride is a brownish-yellow powder.

Uses

As catalyst for organic reactions; catalyst, decolorizer and desulfuring agent in petroleum industry; in denitration of cellulose; as condensing agent for soaps, fats and oils; in gas analysis to absorb carbon monoxide.

Uses

Shows unique character as an initiator of radical reactions such as the hydrostannation of α,β-unsaturated ketones.1

Uses

It is used for absorption of carbon monoxide in gas analysis.

Uses

Copper chloride is also known as cupric chloride, this substance was made by treating copper carbonate with hydrochloric acid. The greenish blue crystals are soluble in water, alcohol, and ether. This halide was added to printing-out and silver bromide emulsions for increased contrast.

Definition

ChEBI: An inorganic chloride of copper in which the metal is in the +1 oxidation state.

First aid

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.

Shipping

UN2802 Copper chloride, Hazard class: 8; Labels: 8-Corrosive material.

Purification Methods

Wash the solid with ethanol and diethyl ether, then dry it and store it in a vacuum desiccator [.sterl.f Acta Chem Scand 4 375 1950]. Alternatively, to an aqueous solution of CuCl2.2H2O is added, with stirring, an aqueous solution of anhydrous sodium sulfite. The colourless product is dried at 80o for 30minutes and stored under N2. Cu2Cl2 can be purified by zone-refining [Hall et al. J Chem Soc, Faraday Trans 1 79 343 1983]. [Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1005 1965.]

Incompatibilities

Contact with strong acids forms monovalent copper salts and toxic hydrogen chloride gas. Forms shock-sensitive and explosive compounds with potassium, sodium, sodium hypobromite, nitromethane, acetylene. Keep away from moisture and alkali metals. Attacks metals in the presence of moisture. Reacts with moist air to form cupric chloride dihydrate. May attack some metals, paints, and coatings. May be able to ignite combustible materials.

Cuprous chloride Preparation Products And Raw materials

Raw materials

Preparation Products


Cuprous chloride Suppliers

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Cuprous chloride Spectrum


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