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TRIMETHYLSILYL ISOCYANATE

CAS No.
1118-02-1
Chemical Name:
TRIMETHYLSILYL ISOCYANATE
Synonyms
ISOCYANATOTRIMETHYLSILANE;trimethylsilanylisocyanate;DK481;TRIMETHYLSILYL ISOCYANATE;Trimethylisocyanatosilane;isocyanatotrimethyl-silan;Silane,isocyanatotriMethyl-;Trimethylsilyl isocyanate,95%;TRIMETHYLSILYLISOCYANATE ,75%;(Trimethylsilyl)Iscyanate, 95%
CBNumber:
CB7367144
Molecular Formula:
C4H9NOSi
Molecular Weight:
115.21
MDL Number:
MFCD00001993
MOL File:
1118-02-1.mol
Last updated:2023-04-23 13:52:06

TRIMETHYLSILYL ISOCYANATE Properties

Melting point -49°C
Boiling point 90-92 °C(lit.)
Density 0.851 g/mL at 25 °C(lit.)
refractive index n20/D 1.396(lit.)
Flash point -2 °C
storage temp. 2-8°C
solubility Miscible with ethers and o-dichlorobenzene.
form clear liquid
color Colorless to Almost colorless
Specific Gravity 0.867
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
BRN 1744962
CAS DataBase Reference 1118-02-1(CAS DataBase Reference)
EPA Substance Registry System Isocyanatotrimethylsilane (1118-02-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS06,GHS08
Signal word  Danger
Hazard statements  H225-H317-H319-H331-H334-H335
Precautionary statements  P210-P233-P280-P303+P361+P353-P304+P340+P311-P305+P351+P338
Hazard Codes  F,T
Risk Statements  11-23-36/37-42
Safety Statements  23-26-36/37/39-45
RIDADR  UN 2478 3/PG 2
WGK Germany  3
10-19-21
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29319090
NFPA 704
3
3 1

TRIMETHYLSILYL ISOCYANATE price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 252646 Trimethylsilyl Isocyanate 85% 1118-02-1 5g $99.5 2024-03-01 Buy
Sigma-Aldrich 252646 Trimethylsilyl Isocyanate 85% 1118-02-1 25g $154.8 2024-03-01 Buy
TCI Chemical T1106 Trimethylsilyl Isocyanate >95.0%(GC) 1118-02-1 5g $76 2024-03-01 Buy
TCI Chemical T1106 Trimethylsilyl Isocyanate >95.0%(GC) 1118-02-1 25g $198 2024-03-01 Buy
Alfa Aesar A12633 Trimethylsilyl isocyanate 94% 1118-02-1 10g $101 2024-03-01 Buy
Product number Packaging Price Buy
252646 5g $99.5 Buy
252646 25g $154.8 Buy
T1106 5g $76 Buy
T1106 25g $198 Buy
A12633 10g $101 Buy

TRIMETHYLSILYL ISOCYANATE Chemical Properties,Uses,Production

Chemical Properties

Clear colorless liquid

Uses

Trimethylsilyl isocyanate is used in the preparation of 1-unsubstituted 4-(dialkylamino) imidazolin-2-ones. It finds application in the carbamoylation of aromatic hydrocarbons and alcohols. It is also used in the preparation of primary amides from Grignard reagents. Further, it is used in the synthesis of cyclic imides. It is also utilized for the synthesis of trifluoroacetyl isocyanate and cyclic imides. In addition to this, it is employed in the conversion of isocyanates to carbodiimides using cyclopentadienyl Mn(CO)3 catalysis.

Purification Methods

Purify it by repeated fractionation as for the isothiocyanate. [Eaborn J Chem Soc 3077 1950, Beilstein 4 III 1861, 4 IV 4011.]

Global( 134)Suppliers
Supplier Tel Email Country ProdList Advantage
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View Lastest Price from TRIMETHYLSILYL ISOCYANATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Trimethylsilyl)isocyanate 85% pictures 2021-07-02 (Trimethylsilyl)isocyanate 85%
1118-02-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
TRIMETHYLSILYL ISOCYANATE pictures 2020-01-15 TRIMETHYLSILYL ISOCYANATE
1118-02-1
US $1.00 / KG 1KG 99.0% 100kg Career Henan Chemical Co
TRIMETHYLSILYL ISOCYANATE TRIMETHYLSILYL ISOCYANATE, STAB. TRIMETHYLSILYLISOCYANATE ,75% Trimethylsilyl isocyanate,95% TriMethylsilyl isocyanate, 95% 5GR Silane,isocyanatotriMethyl- (TriMethylsilyl)isocyanate 85% isocyanatotrimethyl-silan Isocyanic acid, trimethylsilyl ester Trimethylisocyanatosilane (Trimethylsilyl)Iscyanate, 95% trimethylsilanylisocyanate ISOCYANATOTRIMETHYLSILANE DK481 1118-02-1 CH33SiNCO C4H9NOSi Building Blocks Nitrogen Compounds Isocyanates Si-N Compounds Trimethylsilylazide, etc. Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Organic Building Blocks Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-N Compounds Synthetic Organic Chemistry Trimethylsilylazide, etc.