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Sodium fluorosilicate

Outline Reference quality standards The role and purpose Toxicity Chemical Properties Production method Category Toxicity grading Acute toxicity Data irritation Flammability and hazard characteristics Storage characteristics Fire extinguishing agent Professional standards
Sodium fluorosilicate
Sodium fluorosilicate structure
CAS No.
16893-85-9
Chemical Name:
Sodium fluorosilicate
Synonyms
SSF;safsan;salufer;ent1,501;superprodan;orthoearwigbait;orthoweevilbait;destruxolapplex;ens-zemweevilbait;pscco-opweevilbait
CBNumber:
CB7423572
Molecular Formula:
F6Na2Si
Formula Weight:
188.06
MOL File:
16893-85-9.mol

Sodium fluorosilicate Properties

Melting point:
melts at red heat, decomposing [MER06]
Density 
2.68 g/mL at 25 °C(lit.)
refractive index 
1.310
form 
Crystals
color 
White
Specific Gravity
2.68
Water Solubility 
Slightly soluble in water. Solubility increases with temperature. Insoluble in alcoholSlightly soluble in water. Insoluble in alcohol.
Merck 
14,8624
Stability:
Stable. Incompatible with oxidizing agents, water. Moisture sensitive.
CAS DataBase Reference
16893-85-9(CAS DataBase Reference)
EWG's Food Scores
1-3
FDA UNII
806AV2E065
EPA Substance Registry System
Sodium fluosilicate (16893-85-9)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H301+H311+H331-H301-H311-H331
Precautionary statements  P280h-P301+P310a-P304+P340-P405-P501a-P261-P280-P301+P310-P311
Hazard Codes  T,Xi
Risk Statements  23/24/25
Safety Statements  26-45
RIDADR  UN 2674 6.1/PG 3
WGK Germany  2
RTECS  VV8410000
Hazard Note  Irritant
TSCA  Yes
HazardClass  6.1
PackingGroup  III
Toxicity LD in rabbits (mg F/kg): 76 intragastric; in rats (mg F/kg): 42 s.c. (Muehlberger); LD in guinea pigs (mg/kg): 250 orally, 500 s.c. (Waldbott)

Sodium fluorosilicate price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 250171 Sodium hexafluorosilicate 16893-85-9 500g $52.2 2021-03-22 Buy
Sigma-Aldrich 250171 Sodium hexafluorosilicate 16893-85-9 2kg $109 2021-03-22 Buy
Alfa Aesar 069106 Sodium hexafluorosilicate, 99+% 16893-85-9 2kg $98.3 2020-06-24 Buy
Alfa Aesar 069106 Sodium hexafluorosilicate, 99+% 16893-85-9 500g $41.9 2020-06-24 Buy
Strem Chemicals 93-1147 Sodium hexafluorosilicate, 99% 16893-85-9 100g $24 2021-03-22 Buy

Sodium fluorosilicate Chemical Properties,Uses,Production

Outline

Sodium fluorosilicate appears as white crystal, crystalline powder or colorless hexagonal crystals. It is odorless and tasteless. Its relative density is 2.68; it has moisture absorption capability. It can be dissolved in a solvent such as ethyl ether but insoluble in alcohol. The solubility in acid is greater than that in water. It can be decomposed in alkaline solution, generating sodium fluoride and silica. After searing (300 ℃), it is decomposed into sodium fluoride and silicon tetrafluoride. It is poisonous!
In 25 degrees, the sodium fluorosilicate has its water solubility being 0.78%. Upon production, addition of an excess amount of sodium sulfate or sodium chloride can increase the concentration of sodium ions in the system, thereby increasing the solubility product of fluorine silicate and sodium ions, so that sodium fluoride can be subject to more complete precipitation. Sodium fluorosilicate is the byproduct in the production of calcium phosphate or the production of fluoride salt in aluminum factory. It generally appears as a white crystalline powder with low solubility in water (being 1% or less at room temperature), and the water solubility increases slightly with increasing temperature. The aqueous solution of sodium fluorosilicate is acidic (pH3). This is due to that its hydrolysis product contains hydrofluoric acid. Reduction of the acidicity of the solution facilitates the hydrolysis of sodium fluorosilicate. When pH is lower than 3.5-3.55, the hydrolysis reaction is stabilized. When the pH is equal to 4, the hydrolysis reaction rate is significant. When the pH value is equal to 8-8.5, the sodium fluorosilicate can be completely hydrolyzed to exhibit as silica gel and precipitated out. Therefore, when sodium fluorosilicate is added to the water glass, in addition to hardening effect of precipitation of silicon dioxide gel caused by the neutralization of the sodium hydroxide in the solution of water glass, the sodium fluorosilicate itself is also a source of silica gel.

Reference quality standards

105 ℃ Loss of weight upon drying% 0.17%
Sodium fluorosilicate (based on dry mass) 99.50
Free acid (calculated based on HCL) 0.0075
Water insoluble matter 0.12%
Heavy metals (Pb) content% <0.02
% Fineness (through 250um sieve) 98.00
Appearance white powder

The role and purpose

Sodium fluorosilicate can be used as the insecticide in agriculture, the milky agent of enamel, the corrosion production agent of opal glass, wood preservatives and the raw material for the production of other kinds of fluoride as well as being applied to the smelting of beryllium and aluminum and pharmaceuticals, leather and rubber industry. In the refractory material, it can be used as the coagulant as the water glass binding agent. Since sodium fluorosilicate has a low water solubility, it reaction with the water glass is slow and gradual. This can not only boost the construction but also has a high density and strength of the cured products. It is most commonly used in the inorganic material binding with the water glass.
This information is edited by Xiongfeng Dai from Chemicalbook.

Toxicity

This product is toxic with stimulation effect on the respiratory organ. People of mistakenly oral poisoning will get severe symptoms of damage to the gastrointestinal tract with the lethal dose being 0.4~4g. During the working of the operator, they should wear the necessary protective equipment to prevent poisoning. Production equipment should be sealed and the workshop should be well ventilated.

Chemical Properties

It appears as colorless hexagonal crystals. It is odorless and tasteless. It has hygroscopicity. It can be dissolved in a solvent such as ethyl ether but insoluble in alcohol with its solubility in acid is being greater than in the water.

Production method

Calcium superphosphate byproduct method: use sulfuric acid and ground phosphate rock for production of superphosphate or fluorine-containing waste gas during extraction of phosphate with water absorbing silicon tetrafluoride to make it into fluorosilicate. When the concentration of fluorine acid solution reaches 8% to 10%, stand static for clarification and remove the impurities with the clarified fluorine silicate solution being added of sodium chloride (being excess of about 25%) for reaction of sodium fluorosilicate. Further go through centrifugation isolation, washing, air drying at a temperature below 300 ℃ and then pulverize to obtain the finished product of sodium fluorosilicate.
H2SiF6 + 2NaCl → Na2SiF6 + 2HCl

Category

Toxic substances.

Toxicity grading

Highly toxic.

Acute toxicity

Oral-mouse LD50: 70 mg/kg.

Data irritation

Skin-rabbit 500 mg Mild; Eyes-rabbit 100 mg/4 seconds Severe.

Flammability and hazard characteristics

It is non-combustible with fire releasing toxic fluoride and sodium oxide, silica smoke; when it is reacted with acid, it can generate toxic hydrogen fluoride.

Storage characteristics

Treasury: ventilation, low-temperature and drying; store it separately from food and acid.

Fire extinguishing agent

plenty of water.

Professional standards

TWA 2.5 mg (fluorine)/cubic meter.

Chemical Properties

white powder

Chemical Properties

Sodium hexafluorosilicate is a white crystalline solid.

Uses

In enamels for china and porcelain; manufacture of opal glass; as insecticide, rodenticide; mothproofing of woolens. Fluoridating agent for drinking water. Intermediate in production of synthetic cryolite.

General Description

Fine, white, odorless, powdered solid. Toxic by ingestion, inhalation and skin absorption. Used as a rodenticide.

Air & Water Reactions

Water soluble.

Reactivity Profile

Sodium fluorosilicate has weak oxidizing or reducing powers. Redox reactions can however still occur. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive.

Hazard

Toxic by ingestion and inhalation, strong irritant to tissue.

Health Hazard

Inhalation of dust may irritate nose and throat. Ingestion causes symptoms similar to fluoride poisoning; compound is highly toxic; initial symptoms include nausea, cramps, vomiting, diarrhea, and dehydration; in severe cases, convulsions, shock, and cyanosis are followed by death in 2-4 hr. Contact with eyes causes irritation. Contact with skin causes rash, redness, and burning, sometimes followed by ulcer formation.

Fire Hazard

Behavior in Fire: Decomposes at red heat

Industrial uses

Sodium fluorosilicate (Na2SiF6) is a white, isomorphous powder. Solubility in water is similar to that of NaF. In acid pH, solubility improves.
Commercially, Na2SiF6 is produced by treatment of fluorosilic acid with sodium chloride, as shown in the following reaction: H2SiF6 + 2NaCl = Na2SiF6 + 2HCl

Safety Profile

Poison by ingestion and subcutaneous routes. A skin and severe eye irritant. An insecticide. When heated to decomposition it emits very toxic fumes of Fand Na2O.

Potential Exposure

Sodium hexafluorosilicate is as a rodenticide; as an intermediate in production of synthetic cyrolite; as an insecticide in delousing and in mothproofing of woolens.

Shipping

UN2674/Sodium fluorosilicate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Crystallise it from hot water (40mL/g) by cooling.

Incompatibilities

Reacts with acids to produce hydrogen fluoride, a highly corrosive and poisonous gas.

Sodium fluorosilicate Preparation Products And Raw materials

Raw materials

Preparation Products


Sodium fluorosilicate Suppliers

Global( 270)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
ATK CHEMICAL COMPANY LIMITED
+86 21 5161 9050/ 5187 7795
+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 26762 60
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679
86-0551-65418697 info@tnjchem.com China 3000 55
Win-Win Chemical CO., Limited
0086-577-64498589
0086-577-56994596 sales@win-winchemical.com CHINA 998 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5930 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6369 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Wuhan Chemwish Technology Co., Ltd
027-67849912
sales@chemwish.com CHINA 10829 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58
career henan chemical co
13203830695 0086-371-86658258
0086-371-86658258 factory@coreychem.com CHINA 29864 58

View Lastest Price from Sodium fluorosilicate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-11-08 Sodium fluorosilicate
16893-85-9
US $10.00 / KG 1KG 99% 20 TONS Wuhan wingroup Pharmaceutical Co., Ltd
2021-04-09 sodium silicofluoride
16893-85-9
US $1.00 / PCS 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
2020-05-19 Sodium Silicofluoride
16893-85-9
US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd

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