ChemicalBook >> CAS DataBase List >>Bromodiphenylmethane

Bromodiphenylmethane

CAS No.
776-74-9
Chemical Name:
Bromodiphenylmethane
Synonyms
(bromomethylene)Dibenzene;BENZHYDRYL BROMIDE;1-Benzyl-2-broMobenzene;DIPHENYLBROMOMETHANE;CL048;Bromodiphenyl;pha-BromodiphenyL;Bromodiphenylmethan;BROMODIPHENYLMETHANE;DIPHENYLMETHYL BROMIDE
CBNumber:
CB7481460
Molecular Formula:
C13H11Br
Molecular Weight:
247.13
MDL Number:
MFCD00000134
MOL File:
776-74-9.mol
Last updated:2024-04-02 10:23:00

Bromodiphenylmethane Properties

Melting point 35-39 °C(lit.)
Boiling point 184 °C20 mm Hg(lit.)
Density 0,9 g/cm3
refractive index 1.6290 (estimate)
Flash point >230 °F
storage temp. Store below +30°C.
solubility 0.45g/l
form powder to lump to clear liquid
color White to cream to yellow to orange to brown crystals or fused solid
PH 2 (H2O, 20℃)(saturated aqueous solution)
Water Solubility Insoluble
Sensitive Moisture Sensitive
BRN 638544
CAS DataBase Reference 776-74-9(CAS DataBase Reference)
FDA UNII LS6ZRZ2QNN
NIST Chemistry Reference Benzene, 1,1'-(bromomethylene)bis-(776-74-9)
EPA Substance Registry System Benzene, 1,1'-(bromomethylene)bis- (776-74-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H318-H314
Precautionary statements  P280-P305+P351+P338-P310-P309-P260-P264-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501
Hazard Codes  C
Risk Statements  34-37
Safety Statements  26-36/37/39-45
RIDADR  UN 1770 8/PG 2
WGK Germany  3
RTECS  PA5350000
19-21
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29036990
NFPA 704
1
3 0

Bromodiphenylmethane price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B0586 α-Bromodiphenylmethane 776-74-9 25G $40 2024-03-01 Buy
TCI Chemical B0586 α-Bromodiphenylmethane 776-74-9 100G $101 2024-03-01 Buy
Alfa Aesar L02211 Benzhydryl bromide, 90+% 776-74-9 25g $26.65 2024-03-01 Buy
Alfa Aesar L02211 Benzhydryl bromide, 90+% 776-74-9 100g $59.65 2024-03-01 Buy
TCI Chemical B0586 α-Bromodiphenylmethane 776-74-9 500G $353 2024-03-01 Buy
Product number Packaging Price Buy
B0586 25G $40 Buy
B0586 100G $101 Buy
L02211 25g $26.65 Buy
L02211 100g $59.65 Buy
B0586 500G $353 Buy

Bromodiphenylmethane Chemical Properties,Uses,Production

Uses

Benzhydryl Bromide is used as a reagent in the synthesis of O-(triazolyl)methyl carbamates as a novel and potent class of fatty acid amide hydrolase (FAAH) inhibitors.

Chemical Properties

ORANGE-RED TO ORANGE-BROWN LOW MELTING SOLID

Uses

Benzhydryl bromide is a halogenated building block. Benzhydryl group was preferred to the commoner benzyl to protect 2-nitrophenol in the Bartoli (vinyl Grignard) synthesis of 7-hydroxyindole. Protection was by reaction with the phenol in the presence of potassium carbonate in acetone; deprotection of the indole was by hydrogenolysis.

General Description

Bromodiphenylmethane is a white crystalline solid. Melting point 113°F. A lachrymator. In the presence of moisture corrosive to tissue and most metals.

Air & Water Reactions

Insoluble in cold water. Decomposed by hot water to give corrosive hydrobromic acid.

Reactivity Profile

Halogenated aliphatic compounds are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Safety Profile

A corrosive, irritating liquid, When heated to decomposition it emits toxic fumes of Br-. See also

91-01-0
631-61-8
954-67-6
776-74-9
Synthesis of Bromodiphenylmethane from Benzhydrol and Ammonium acetate
Global( 275)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7786 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Zhejiang ZETian Fine Chemicals Co. LTD
18957127338 stella@zetchem.com China 2141 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715 admin@nexconn.com China 10248 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 6992 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58

Related articles

  • Bromodiphenylmethane-Application
  • Bromodiphenylmethane is a halogenated building block. Benzhydryl group was preferred to the commoner benzyl to protect 2-nitro....
  • Dec 27,2019

View Lastest Price from Bromodiphenylmethane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bromodiphenylmethane pictures 2023-12-26 Bromodiphenylmethane
776-74-9
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Bromodiphenylmethane  pictures 2023-03-21 Bromodiphenylmethane
776-74-9
US $1.33-569.00 / Kg 1Kg 99% 100000 Shaanxi Dideu Medichem Co. Ltd
Bromodiphenylmethane pictures 2023-01-17 Bromodiphenylmethane
776-74-9
US $25.00 / kg 1kg 99% 5000 tons Hebei Duling International Trade Co. LTD
ALPHA-BROMODIPHENYLMETHANE 1,1’-(bromomethylene)bis-benzen 1,1’(Bromomethylene)bisbenzene Methane, bromodiphenyl- DIPHENYLMETHYL BROMIDE BROMODIPHENYLMETHANE [Bromo(phenyl)methyl]benzene 9,10-Dihydro-4H-Benzo[4,5] Cyclohepta[1,2-B] Thiophene Benzhydryl bromide, (Bromodiphenylmathane Bromodiphenylmethane~Diphenylmethyl bromide N,N-Di(butyl)amino-3-chloropropane BROMODIPHENYLMETHANE CRYSTALLINE BenzhydrylBromide,>97% 9,10-DIHYDRO-4H-BENZO[4,5]CYCLOHEPTA[1,2-B]THIOPHENE(BROMODIPHENYLMETHANE) Benzhydryl bromide, Diphenylbromomethane Bromodiphenylmethane,95% Bromodiphenylmethane,90% Bromodiphenyl Benzene, 1,1-(bromomethylene)bis- BroModiphenylMethane, 90% 100GR Benzhydryl broMide, 90+% Benzhydryl Bromide Diphenylbromomethane Diphenylmethyl Bromide BROMODIPHENYLMETHANE FOR SYNTHESIS alpha-BroModiphenylMethane , 97.0%(GC&T B**Bromodiphenylmethane CL048 alpha-Bromodiphenylmethane > pha-BromodiphenyL Bromodiphenylmethane ISO 9001:2015 REACH Bromodiphenylmethane pure, 98% α-Bromodiphenylmethane BENZHYDRYL BROMIDE Extra Pure DIPHENYLBROMOMETHANE BENZHYDRYL BROMIDE (bromomethylene)Dibenzene 1-Benzyl-2-broMobenzene Bromodiphenylmethan Armodafinil Impurity 2 776-74-9 76-74-9 766-74-9 C6H52CHBr BENZYL HALIDE Organic Building Blocks Halogenated Hydrocarbons Aryl C13 to C37+ Building Blocks Pharmaceutical Intermediates