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TELLURIC ACID

CAS No.
7803-68-1
Chemical Name:
TELLURIC ACID
Synonyms
telluric;tellurate;TELLURIC ACID;Tellurium Acid;telluric(vi)acid;orthotelluricaci;Telluric acid 98%;orthotelluricacid;TELLURATE HYDROGEN;telluriumhydroxide
CBNumber:
CB7673964
Molecular Formula:
H6O6Te
Molecular Weight:
229.64404
MDL Number:
MFCD00011609
MOL File:
7803-68-1.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:36

TELLURIC ACID Properties

Melting point 136°C
Boiling point 0℃
Density 3.068; d 3.163
solubility H2O: 0.1 g/mL, clear, colorless
pka 7.7(at 25℃)
form white monoclinic crystals
color White to Almost white
Water Solubility g H2TeO6/100g H2O: 16.2 (0°C), 41.6 (20°C), 155 (100°C) [LAN05]; tends to polymerize; soluble dilute HNO3 [MER06]
λmax 275nm(H2O)(lit.)
Merck 14,9120
Solubility Product Constant (Ksp) pKsp: 53.52
EWG's Food Scores 1
FDA UNII WE1KZR49WU
EPA Substance Registry System Telluric acid (H6TeO6) (7803-68-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H332
Precautionary statements  P261-P271-P304+P340+P312
Hazard Codes  Xn
Risk Statements  20
Safety Statements  22-36/37/39-38
RIDADR  UN 3284 6.1/PG 3
WGK Germany  3
RTECS  WY2350000
8
HS Code  2811.19.6190
HazardClass  6.1(a)
PackingGroup  II

TELLURIC ACID price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 308463 Telluric acid 98% 7803-68-1 25g $198 2024-03-01 Buy
Sigma-Aldrich 308463 Telluric acid 98% 7803-68-1 100g $330 2024-03-01 Buy
TCI Chemical T3253 Telluric Acid >99.0%(T) 7803-68-1 25g $87 2024-03-01 Buy
Sigma-Aldrich 86375 Telluric acid purum, ≥99.0% (T) 7803-68-1 25g $217 2024-03-01 Buy
Sigma-Aldrich 86375 Telluric acid purum, ≥99.0% (T) 7803-68-1 100g $670 2024-03-01 Buy
Product number Packaging Price Buy
308463 25g $198 Buy
308463 100g $330 Buy
T3253 25g $87 Buy
86375 25g $217 Buy
86375 100g $670 Buy

TELLURIC ACID Chemical Properties,Uses,Production

Description

Telluric acid, H6TeO6, is obtained in the form of its salts when tellurium is fused with potassium nitrate plus carbonate, or by the oxidizing action of chlorine on a tellurite in alkaline solution. The free acid may be obtained by decomposing the barium salt with sulfuric acid and concentrating the solution.
where tellurium is in an octahedral coordination. Telluric acid, Te(OH)6, has the CAS number of 7803-68- 1 and a molecular weight of 229.6425 g/mol. It is a white, monoclinic crystal with a density of 3.07 g/cm3. Its melting point is 136°C and its solubility in water is 50.1 g/100 ml.
It is also formed when tellurium dioxide is oxidized by hydrogen peroxide in caustic solution (A. Gutbier, Zest. Anorg. Chem., 1904, 40, p. 260), and perhaps best of all by oxidizing tellurium with a mixture of nitric and chromic acids. It crystallizes as prisms, which lose their water of hydration at 160°C. The tellurates of the alkaline earth metals are more or less soluble in water, those of the other metals being very sparingly or almost insoluble in water. Some tellurates exist in two forms, a colorless form soluble in water and acids, and a yellow form insoluble in water and acids.

Chemical Properties

White, heavy crystals. Soluble in hot water and alkalies; slightly soluble in cold water.

Physical properties

White crystals; dimorphic solid; exists in both cubic and monoclinic crystalline forms; density 3.07g/cm3; melts at 136°C; tends to polymerize (similar to stannic acid); forms polymetatelluric acid (H2TeO4)n on strong heating; soluble in water, about 33g/100 mL at 30°C; the solubility decreases as the molecule polymerizes and becomes colloidal; a very weak dibasic acid, pKa1 7.68 and pKa2 11.0 at 18°C; soluble in dilute nitric acid and alkalies.

Uses

Chemical reagent.

Preparation

Telluric acid can be prepared by reducing barium tellurate with sulfuric acid: BaTeO4 + H2SO4 + 2H2O → H6TeO6 + BaSO4 Also, telluric acid can be prepared by oxidation of tellurium or tellurium dioxide with a strong oxidizing agent such as hydrogen peroxide, sodium peroxide, chromic acid, or potassium permanganate in nitric acid. Molecular equations for overall reactions are shown below: Te + 3H2O2 → H6TeO6 TeO2 + H2O2 + 2H2O → H6TeO6 Te + 2CrO3 + 3H2O → H6TeO6 + Cr2O3
At cold temperatures at about 1°C, telluric acid crystallizes as tetrahydrate.

Definition

ChEBI: Orthotelluric acid is a tellurium oxoacid. It is a conjugate acid of an orthotellurate(1-).

General Description

Telluric acids exist in both cubic and monoclinic crystalline forms.1 It may be prepared by treating tellurium and tellurous acid with strong oxidants.

Hazard

As for tellurium.

Safety Profile

Poison by ingestion and intravenous routes. When heated to decomposition it emits toxic fumes of Te. See also TELLURIUM COMPOUNDS.

Purification Methods

Crystallise it once from nitric acid, then repeatedly from hot water (0.4mL/g). [Fehér in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I pp 451-453 1963.]

TELLURIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from TELLURIC ACID manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Telluric acid pictures 2023-07-10 Telluric acid
7803-68-1
US $117.00-110.00 / kg 1kg 99.9% 100kg Jiangsu Boquan Biotechnology Co., Ltd.
Telluric acid pictures 2023-01-31 Telluric acid
7803-68-1
US $100.00 / kg 1kg 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
orthotelluric acid pictures 2020-01-10 orthotelluric acid
7803-68-1
US $1.00 / KG 1KG 98% HPLC 10 tons/month Career Henan Chemical Co
  • Telluric acid pictures
  • Telluric acid
    7803-68-1
  • US $117.00-110.00 / kg
  • 99.9%
  • Jiangsu Boquan Biotechnology Co., Ltd.
  • Telluric acid pictures
  • Telluric acid
    7803-68-1
  • US $100.00 / kg
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd

TELLURIC ACID Spectrum

tellurate telluric telluric(vi)acid telluricacid(h6teo6) telluriumhydroxide TELLURATE HYDROGEN TELLURIC ACID Hydrogen tellurate(VI) Trihydrated telluric oxide Telluric acid 98% Telluric acid puruM, >=99.0% (T) Tellurium hexahydroxide orthotelluricacid TELLURIC ACID ISO 9001:2015 REACH telluric acid, telluric(VI) acid Tellurium Acid Telluric acid, 99%+ orthotelluricaci 7803-68-1 H6TeO6 TeOH6 Acids Electronic Chemicals Micro/Nanoelectronics