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Cobalt(II) fluoride

Preparation
Cobalt(II) fluoride
Cobalt(II) fluoride structure
CAS No.
10026-17-2
Chemical Name:
Cobalt(II) fluoride
Synonyms
COBALT FLUORIDE;Cobalt(Ⅱ)fluorde;Cobalt(Ⅱ)fluoride;COBALT DIFLUORIDE;COBALTOUS FLUORIDE;COBALT(II) FLUORIDE;cobaltfluoride(cof2);COBALT FLUORIDE PINK;Cobalt(II) difluoride;Cobalt(II) fluoride,99%
CBNumber:
CB7681660
Molecular Formula:
CoF2
Formula Weight:
96.93
MOL File:
10026-17-2.mol

Cobalt(II) fluoride Properties

Melting point:
1200 °C
Boiling point:
1400 °C
Density 
4.46 g/mL at 25 °C
form 
powder
color 
Pink
Specific Gravity
4.46
Water Solubility 
Soluble in water, alcohol and acetone.
Sensitive 
Hygroscopic
Merck 
14,2440
Stability:
hygroscopic
CAS DataBase Reference
10026-17-2(CAS DataBase Reference)
EPA Substance Registry System
Cobalt fluoride (CoF2)(10026-17-2)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,C
Risk Statements  25-34
Safety Statements  26-36/37/39-45-50A-28A
RIDADR  UN 2923 8/PG 3
WGK Germany  3
RTECS  GG0770000
21
Hazard Note  Toxic
TSCA  Yes
HazardClass  6.1
PackingGroup  III
Hazardous Substances Data 10026-17-2(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Cobalt(II) fluoride price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 236128 Cobalt(II) fluoride powder 10026-17-2 25g $96.2 2018-11-13 Buy
Alfa Aesar 013074 Cobalt(II) fluoride, anhydrous, 98% 10026-17-2 100g $190 2018-11-16 Buy
Alfa Aesar 013074 Cobalt(II) fluoride, anhydrous, 98% 10026-17-2 25g $66.6 2018-11-16 Buy
Strem Chemicals 93-2738 Cobalt(II) fluoride, anhydrous, 99% 10026-17-2 50g $130 2018-11-13 Buy
Strem Chemicals 93-2738 Cobalt(II) fluoride, anhydrous, 99% 10026-17-2 10g $37 2018-11-13 Buy

Cobalt(II) fluoride Chemical Properties,Uses,Production

Preparation

Cobalt(II) fluoride is prepared by heating anhydrous cobalt(II) chloride or oxide in a stream of hydrogen fluoride:
CoCl2 + 2HF → CoF2 + 2HCl
CoO + 2HF → CoF2 + 2H2O
Also, cobalt(II) fluoride can be prepared as a tetrahydrate, CoF2•4H2O by dissolving cobalt(II) hydroxide in hydrofluoric acid. The tetrahydrate is then dehydrated to anhydrous fluoride. Elemental fluorine combines with cobalt at 450°C forming mixtures of cobalt(II)–and cobalt(III) fluorides.

Chemical Properties

Rose-red crystals or powder. Soluble in cold water and hydrofluoric acid. Decomposes in hot water. Ammine complexes can be prepared from the hydrate.

Uses

Catalyst for organic reactions.

General Description

Violet to red solid. Sinks and mixes slowly with water.

Reactivity Profile

Cobalt(II) fluoride is a toxic, light brown crystalline material, when exposed to water Cobalt(II) fluoride forms highly corrosive hydrofluoric acid. When heated to decomposition Cobalt(II) fluoride emits toxic fumes of metallic cobalt and fluorides [Lewis, 3rd ed., 1993, p. 344].

Hazard

Highly toxic.

Health Hazard

INHALATION: Inhalation of dust may cause pulmonary symptoms. EYES: Irritation. SKIN: Skin rashes, dermatitis. INGESTION: Nausea and vomiting caused by local irritation.
LD50 oral (rat): 150 mg/kg

Safety Profile

Poison by ingestion. When heated to decomposition it emits toxic fumes of Co and F-.

Cobalt(II) fluoride Preparation Products And Raw materials

Raw materials

Preparation Products


Cobalt(II) fluoride Suppliers

Global( 65)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20243 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40395 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30291 84
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44187 61
Nanjing Chemlin Chemical Co., Ltd 025-83697070
+86-25-83453306 sales@chemlin.com.cn China 19998 64
Thermo Fisher Scientific 800-810-5118
+86-10-84193589 cnchemical@thermofisher.com China 17559 75
Beijing HuaMeiHuLiBiological Chemical 010-56205725;010-86181995
010-65763397 waley188@sohu.com China 12388 58
9ding chemical ( Shanghai) Limited 4009209199
86-021-52271987 sales@9dingchem.com China 22651 55
Sigma-Aldrich 021-61415566 800-819-3336(Tel) 400-620-3333(Mobile)
021-61415567 orderCN@sial.com China 28593 80

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