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E-PHENYLETHENYLBORONIC ACID

CAS No.
6783-05-7
Chemical Name:
E-PHENYLETHENYLBORONIC ACID
Synonyms
STYRYLBORONIC ACID;TRANS-2-PHENYLVINYLBORONIC ACID;RARECHEM AH PB 0201;(E)-Styreneboronic acid;Phenylethenylboronicacid;trans-^b-Styrylboronic acid;TRANS-B-STYRENEBORONIC ACID;E-PHENYLETHENYLBORONIC ACID;TRANS-β-STYRENEBORONIC ACID;TRANS-PHENYLVINYLBORONIC ACID
CBNumber:
CB7685002
Molecular Formula:
C8H9BO2
Molecular Weight:
147.97
MDL Number:
MFCD00963621
MOL File:
6783-05-7.mol
MSDS File:
SDS
Last updated:2023-04-27 16:27:43

E-PHENYLETHENYLBORONIC ACID Properties

Melting point 146-156 °C(lit.)
Boiling point 315.9±35.0 °C(Predicted)
Density 1.130±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Store in freezer, under -20°C
form Powder and/or Chunks
pka 9.38±0.43(Predicted)
color Light yellow to beige
CAS DataBase Reference 6783-05-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26
WGK Germany  3
HazardClass  IRRITANT
HS Code  29310099
NFPA 704
0
2 0

E-PHENYLETHENYLBORONIC ACID price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 473790 trans-2-Phenylvinylboronic acid 97% 6783-05-7 5g $261 2024-03-01 Buy
Sigma-Aldrich 473790 trans-2-Phenylvinylboronic acid 97% 6783-05-7 25g $435 2024-03-01 Buy
Alfa Aesar H53227 trans-beta-Styrylboronic acid 97% 6783-05-7 1g $68.65 2024-03-01 Buy
Alfa Aesar H53227 trans-beta-Styrylboronic acid 97% 6783-05-7 5g $261 2024-03-01 Buy
TRC P338328 [(E)-2-Phenylvinyl]boronicAcid 6783-05-7 50mg $60 2021-12-16 Buy
Product number Packaging Price Buy
473790 5g $261 Buy
473790 25g $435 Buy
H53227 1g $68.65 Buy
H53227 5g $261 Buy
P338328 50mg $60 Buy

E-PHENYLETHENYLBORONIC ACID Chemical Properties,Uses,Production

Chemical Properties

Brown granular powder

Uses

Reagent used for

  • Palladium (Pd)-catalyzed Suzuki-Miyaura coupling reactions
  • Rhodium (Rh)-catalyzed intramolecular amination of aryl azides
  • Diastereoselective synthesis via Pd-catalyzed Heck-Suzuki cascade reaction
  • Copper (Cu)-mediated cyanation
  • Rhodium (Rh)-catalyzed asymmetric addition
  • Diastereoselective synthesis via iridium (Ir)-catalyzed addition
  • Palladium (Pd)-catalyzed cascade cyclization

Reagent used in Preparation of
  • Optically active unsaturated amino acids by diastereoselective Petasis borono-Mannich reaction
  • Amino alcohol dienes via Petasis 3-component reaction using Ru-catalyzed ring-closing metathesis and isomerization

Uses

E-Phenylethenylboronic acid is a reagent used for• ;Palladium (Pd)-catalyzed Suzuki-Miyaura coupling reactions
1 Rhodium (Rh)-catalyzed intramolecular amination of aryl azides
2 Diastereoselective synthesis via Pd-catalyzed Heck-Suzuki cascade reaction
3 Copper (Cu)-mediated cyanation
4 Rhodium (Rh)-catalyzed asymmetric addition
5 Diastereoselective synthesis via iridium (Ir)-catalyzed addition
6 Palladium (Pd)-catalyzed cascade cyclization
7 Reagent used in Preparation of • ;Optically active unsaturated amino acids by diastereoselective Petasis borono-Mannich reactio

Uses

trans-beta-Styrylboronic acid as reagent is used for palladium (Pd)-catalyzed Suzuki-Miyaura coupling reactions, diastereoselective synthesis via Pd-catalyzed Heck-Suzuki cascade reaction and rhodium (Rh)-catalyzed intramolecular amination of aryl azides. It is also used as reagent in preparation of optically active unsaturated amino acids by diastereoselective Petasis borono-Mannich reaction and amino alcohol dienes via Petasis 3-component reaction using Ru-catalyzed ring-closing metathesis and isomerization.

588-72-7
6783-05-7
Synthesis of E-PHENYLETHENYLBORONIC ACID from [(Z)-2-bromoethenyl]benzene
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E-PHENYLETHENYLBORONIC ACID Spectrum

trans-^b-Styrylboronic acid trans-beta-Styrylboronic acid RARECHEM AH PB 0201 TRANS-BETA-STYRENEBORONIC ACID TRANS-B-STYRENEBORONIC ACID TRANS-PHENYLETHENYLBORONIC ACID TRANS-PHENYLVINYLBORONIC ACID E-PHENYLETHENYLBORONIC ACID Phenylethenylboronicacid trans-beta-Styreneboronic acid,95% trans-Phenylethenylboronic acid ,97% trans-beta-Styreneboronic acid, 95% 2.5GR (E)-2-phenyl-Etheneboronic acid (E)-Styreneboronic acid trans-(2-Phenylethenyl)boronic acid Styrylboronic acid, May contain varying amounts of anhydride, 97% [trans-2-Phenylvinyl]boronic acid, [(E)-2-Phenylethenyl]boronic acid, trans-Styrylboronic acid trans-2-Phenylvinylboronic acid 97% [(E)-2-Phenylvinyl]boronic acid 95% Boronic acid, B-[(1E)-2-phenylethenyl]- TRANS-β-STYRENEBORONIC ACID methyl N-[(E)-(1-hydroxy-4-oxidoquinoxalin-4-ium-2-ylidene)methyl]iminocarbamate STYRYLBORONIC ACID TRANS-2-PHENYLVINYLBORONIC ACID 6783-05-7 6783-5-7 1783607 1783-60-7 C6H5CHCHBOH2 Boronic Acids Boronic Acids and Derivatives Alkenyl Organometallic Reagents Boronic Acids blocks BoronicAcids Alkenyl Boronic Acids Boronic Acids and Derivatives Chemical Synthesis Organometallic Reagents Alkenyl Boronic Acids Boronic Acids and Derivatives